Search results for "010401 analytical chemistry"
showing 10 items of 1284 documents
Determination of pharmaceutical residues in wastewater using high performance liquid chromatography coupled to quadrupole-Orbitrap mass spectrometry
2016
Abstract A multi-class method for the determination of 24 emerging pharmaceutical residues has been developed and validated. The method is based on solid-phase extraction of wastewater samples using Strata-X cartridges followed by high performance liquid chromatography coupled to hybrid quadrupole − Orbitrap high resolution mass spectrometry (HPLC-Q-Orbitrap-HRMS). A single-laboratory validation procedure showed satisfactory analytical performance. The analysis of 21 samples collected at the wastewater treatment plant in Riga revealed the occurrence of 20 compounds of different therapeutic classes. The highest concentration was found for the central nervous system stimulator caffeine − up t…
Effect of environmental humidity and coating on aroma transfer through treated papers
2012
Abstract Coupled transfers of aroma compounds and water vapour were investigated by varying the relative humidity gradient of storage (50% or 90%) of two paper packaging at 25 °C. These papers differed in their coating surface: both were identically impregnated then supercalendered, and only one was twice coated on both sides with a synthetic barrier substance. Permeability and solubility coefficients were determined. The coating treatment was more effective to decrease the permeabilities of water vapour and ethyl ester than the effect of RH. On the contrary, the RH modified the water content of the treated papers and affected more strongly their permeability and solubility to cis-3-hexenol…
Brain Biophysics: Perception, Consciousness, Creativity. Brain Computer Interface (BCI)
2018
The paper presents connections between perception, awareness, and creativity from the biophysical point of view. Attention was drawn to human senses’ limitations and their influence on cognition. The role of interfaces connecting brain with computer and particular role of Brain Computer Interface (BCI) are indicated which the authors believe will be the next stage of human brain supporting technology evolution. It will enable the growth of perception, awareness, and creativity, and consequently lead to social development.
Green extraction techniques in green analytical chemistry
2019
Abstract Green analytical chemistry concept, involving the development of analytical methodologies with an environmental concern, encourages the use of direct analysis to avoid any sample treatment that involves energy and reagent consumption and generation of wastes. However, the determination of target analytes at trace concentration levels or in complex matrices frequently requires previous extraction, pre-concentration, or clean-up steps offering thus, additional possibilities for greening classical methods. So, a green evaluation of alternative extraction techniques to currently used ones for the extraction of solid, liquid, and gaseous samples has been carried out in this study. Moreo…
Analysis and Evaluation of Adaptive RSSI-based Ranging in Outdoor Wireless Sensor Networks
2019
Estimating inter-node distances based on received radio signal strength (RSSI) is the foundation of RSSI-based outdoor localization in wireless sensor networks (WSNs). However, the accuracy of RSSI-based ranging depends on environmental and weather conditions. Therefore, it is important that RSSI-based ranging adapts to prevailing conditions to improve its range and location accuracy. This paper analyzes and evaluates RSSI-based ranging and adaptive techniques in outdoor WSNs to improve the range quality. The findings highlight the effects of path loss exponent (PLE) estimation error and temperature change on RSSI-based ranging. Consequently, we analyze techniques for mitigating these detri…
Indoor localization using time difference of arrival with UWB signals and unsynchronized devices
2020
Abstract Indoor location using radio frequency (RF) signals has been traditionally focused mainly on RSSI and fingerprint techniques, because methods based on time of arrival (ToA) or time difference of arrival (TDoA) were not suitable for measuring short distances. However, the release of the IEEE 802.15.4a standard, the emergence of commercial ultra wide band (UWB) transceivers that are compliant to this norm and the integration of high frequency oscillators have permitted the design of more accurate indoor localization systems using the RF signal transmission time. In this paper, we propose an indoor localization system based on TDoA for UWB. The method implements an only one way transmi…
Performance of frame transmissions and event-triggered sleeping in duty-cycled WSNs with error-prone wireless links
2018
Abstract Two types of packet transmission schemes are prevalent in duty-cycled wireless sensor networks, i.e., single packet transmission and aggregated packet transmission which integrates multiple packets in one frame. While most existing models are developed based on an error-free channel assumption, this paper evaluates the performance of both transmission schemes under error-prone channel conditions. We develop a four-dimensional discrete-time Markov chain model to investigate the impact of channel impairments on the performance of frame transmissions. Together with tracking the number of packets in the queue, number of retransmissions and number of active nodes, the fourth dimension o…
Modeling RISC-V Processor in IP-XACT
2018
IP-XACT is the most used standard in IP (Intellectual Property) integration. It is intended as a language neutral golden reference, from which RTL and HW dependent SW is automatically generated. Despite its wide popularity in the industry, there are practically no public and open design examples for any part of the design flow from IP-XACT to synthesis. One reason is the difficulty of creating IP-XACT models for existing RTL projects. In this paper, we address the issues by modeling the PULPino RISC-V microprocessor that is written in SystemVerilog (SV) and the project distributed over several repositories. We propose how to solve the mismatching concepts between SV project and IP-XACT, and…
Angle and Height Estimation Technique for Aerial Vehicles using mmWave FMCW Radar
2021
In this article, we present a novel angle and height estimation technique for aerial vehicles using mmWave frequency modulated continuous wave (FMCW) Radar. In the proposed method, Radar’s antennas are oriented vertically to measure the elevation angle of arrival of the aerial vehicle from ground station. Height of the aerial vehicle and horizontal distance of the aerial vehicle from Radar station on ground are estimated using the measured radial range and the elevation angle of arrival.
Challenges in the determination of engineered nanomaterials in foods
2016
Detection, characterization, and quantification of engineering nanomaterials (ENMs) in foods is still a pending issue that needs to be tackle to protect consumers and to fix some related aspects (e.g. labelling or control). The global challenge for the analytical sciences is that ENMs are a new sort of analytes, involving both chemical (composition, mass and number concentration) and physical information (e.g. size, shape, aggregation). In this critical review, we evaluate and compare the procedures involved in the analytical methods and studies developed thus far for the identification and quantification of ENMs in food. We discuss advantages and limitation as well as prospects. We pointed…