Search results for "010401 analytical chemistry"
showing 10 items of 1284 documents
Current Trends on the Acquisition, Virtual Representation, and Interaction of Cultural Heritage
2020
Cultural heritage (CH) tells us about our roots, and therefore, constitutes a rich value for the society. Its conservation, dissemination, and understanding are of utmost importance. In order to preserve CH for the upcoming generations, it needs to be documented, a process that nowadays is done digitally. Current trends involve a set of technologies (cameras, scanners, etc.) for the shape and radiometric acquisition of assets. Also, intangible CH can be digitally documented in a variety of forms. Having such assets virtualized, a proper dissemination channel is of relevance, and recently, new technologies that make use of interaction paradigms have emerged. Among them, in this chapter, the …
A Wireless Acoustic Array System for Binaural Loudness Evaluation in Cities
2017
Networks of acoustic sensors are being deployed in smart cities to continuously monitor noise levels. In this paper, a novel acoustic sensor device is designed for binaural loudness evaluation, in a standalone platform. The audio is acquired from an array of microphones and a binaural signal is synthesized by a direction-of-arrival algorithm and a head-related transfer function. Hardware setup and software algorithms are presented and the results are discussed. Finally, the tests conducted in an early deployment show the feasibility of using the device to carry out large temporal and spatial sampling for the evaluation of binaural loudness.
Reconstruction of undergraduate analytical chemistry laboratory course
2016
The Analytical chemistry laboratory course at the Department of Chemistry at the University of Jyväskylä was reconstructed due to problems in the traditional arrangement, structure and contents of the course. The purposes of the reform were: to increase student-centered activity, co-operation and inquiry-based learning; to strengthen the connections to real-life; to develop students’ critical-thinking skills; and to decrease the number of drop-outs during the course. The reconstructed course includes independent laboratory work tasks and a research project. The results of the projects are presented in a course seminar. All of the laboratory experiments are done in groups of 8-10 students un…
Warehouse threats and loss prevention management in case of fire
2016
Abstract Warehouses play an important role when it comes to the reception, delivery and storage of various types of goods. Due to the complex scenarios that may occur, as well as the heterogeneous nature of goods, warehouses bear a higher risk of accidents. Regardless if we’re taking about removing hassle or standardizing operations we speak the same language: insuring efficiency and increased efficiency leads to smart cost maintenances. In the article hear by we will observe the behavior of different warehouse materials in the case of trigger fired. Starting from the results obtained during the low scale tests and completing the premises with the large scale experiment (warehouse scale), w…
Exploring FPGA‐Based Lock‐In Techniques for Brain Monitoring Applications
2017
Functional near‐infrared spectroscopy (fNIRS) systems for e‐health applications usually suffer from poor signal detection, mainly due to a low end‐to‐end signal‐to‐noise ratio of the electronics chain. Lock‐in amplifiers (LIA) historically represent a powerful technique helping to improve performance in such circumstances. In this work a digital LIA system, based on a Zynq® field programmable gate array (FPGA) has been designed and implemented, in an attempt to explore if this technique might improve fNIRS system performance. More broadly, FPGA‐based solution flexibility has been investigated, with particular emphasis applied to digital filter parameters, needed in the digital LIA, and its …
Assessment of air passive sampling uptakes for volatile organic compounds using VERAM devices
2017
Abstract A calibration chamber has been designed and employed for the simple and easy determination of uptake sampling rate (RS) of volatile organic compounds (VOCs) from air using passive samplers. A flow of clean air was continuously spiked, at a constant VOC concentration, by the microinjection of a standard solution by means of a T-type tube. The developed system allowed the complete evaporation at room temperature of the standard solution in acetone and the air concentration of VOCs was easily controlled by the regulation of the clean air flow, the standard solution concentration and its flow. Active sampling was employed for monitoring the true concentration of the evaluated compounds…
Impact of historical mining assessed in soils by kinetic extraction and lead isotopic ratios.
2014
12 pages; International audience; The aim of this study is to estimate the long-term behaviour of trace metals, in two soils differently impacted by past mining. Topsoils from two 1 km(2) zones in the forested Morvan massif (France) were sampled to assess the spatial distribution of Cd, Cu, Pb and Zn. The first zone had been contaminated by historical mining. As expected, it exhibits higher trace-metal levels and greater spatial heterogeneity than the second non-contaminated zone, supposed to represent the local background. One soil profile from each zone was investigated in detail to estimate metal behaviour, and hence, bioavailability. Kinetic extractions were performed using EDTA on thre…
Determination of pharmaceutical residues and assessment of their removal efficiency at the Daugavgriva municipal wastewater treatment plant in Riga, …
2017
Pharmaceutical products (PPs) belong to emerging contaminants that may accumulate along with other chemical pollutants in wastewaters (WWs) entering industrial and/or urban wastewater treatment plants (WWTPs). In the present study, the technique of ultra-high-performance liquid chromatography coupled to Orbitrap high-resolution mass spectrometry (Orbitrap-HRMS) was applied for the analysis of 24 multi-class PPs in WW samples collected at different technological stages of Daugavgriva WWTP located in Riga, Latvia. Caffeine and acetaminophen levels in the range of 7,570–11,403 ng/L and 810–1,883 ng/L, respectively, were the predominant compounds among 19 PPs determined in the WW. The results i…
Measurement of pollution levels of N-nitroso compounds of health concern in water using ultra-performance liquid chromatography–tandem mass spectrome…
2017
International audience; This paper reports the development of a highly sensitive analytical method combining solid-phase extraction (SPE) with ultra-high performance liquid chromatography coupled with tandem mass spectrometry (UHPLC–MS/MS), for the monitoring of ultra-trace levels of N-nitrosamines in water samples. Under optimized analytical conditions, chromatographic separation was performed in 3 min, in isocratic mode, using an Acquity UHPLC C18 column and a mobile phase consisting of acetonitrile, water, and formic acid (60:40:0.1, v/v/v) at a flow rate of 0.4 mL min−1. Electrospray ionization tandem interface was employed prior to mass spectrometric detection. Good linearity (R2 ≥ 0.9…
Development and optimization of gas chromatography coupled to high resolution mass spectrometry based method for the sensitive determination of Dechl…
2017
An analytical method has been developed for the trace determination of 10 dechlorane-related compounds (DRCs) in food products by gas chromatography - high resolution mass spectrometry (GC-HRMS). The highest sensitivity of this instrumental analysis method was achieved by selection of the GC column type, optimization of the heated zones within the instrument, and adjusting the electron impact energy. The efficiency of solid phase extraction as clean-up procedure was also optimized. Two different types of cartridges - neutral silica gel and Florisil®, as well as seven organic solvents or their mixtures - n-hexane, cyclohexane, acetone, toluene, n-hexane/ethyl acetate, n-hexane/acetone, and n…