Search results for "0204 chemical engineering"
showing 10 items of 273 documents
Adaptive control of a drilling system with unknown time-delay and disturbance
2016
In this paper, we address adaptive predictor feedback design for a simplified drilling system in the presence of disturbance and time-delay. The main objective is to stabilize the bottomhole pressure at a critical depth at a desired set-point directly. The stabilization of the dynamic system and the asymptotic tracking are demonstrated by the proposed adaptive control, where the adaptation employs Lyapunov update law design with normalization. The proposed method is evaluated using a high fidelity drilling simulator and cases from a North Sea drilling operation are simulated. The results show that the proposed predictor controller is effective to stabilize the bottom hole pressure within th…
Gas-liquid mass transfer rates in unbaffled tanks stirred by PBT: scale-up effects and pumping direction
2018
Abstract Unbaffled stirred tanks are increasingly recognized as a viable alternative to common baffled tanks for a range of applications such as biochemical, food or pharmaceutical processes where the presence of baffles is undesirable for some reason. In this work, the mass transfer performance of unbaffled stirred tanks with pitched blade turbine, operating either in up-pumping or down-pumping mode, was investigated. The influence of impeller size and liquid viscosity were also investigated. The mass transfer intensity was measured by means of the Simplified Dynamic Pressure. Method The measurements concerned both coalescent and non-coalescent (viscous) batches. Results confirm that incre…
Electrodialysis with asymmetrically profiled membranes: Influence of profiles geometry on desalination performance and limiting current phenomena
2021
Abstract Electrodialysis (ED) has recently gained much attention in the wide field of desalination and water treatment. However, energy consumption and capital costs may impair the process competitiveness. In this regard, limiting current density (LCD) and current efficiency (η) are key performance parameters for optimized ED systems. In this work, an experimental campaign was carried out characterizing the performance of ED stacks when adopting asymmetrically profiled membranes. Current–voltage curves were recorded under different operating conditions mimicking the operation of brackish water or seawater desalination units. Results showed that there was a preferable direction of the electr…
Obtaining of the Modified NH4NO3 Granules with 3-D Nanoporous Structure: Impact of Humidifier Type on the Granule’s Structure
2018
The article deals with the study of the porous ammonium nitrate granules’ (PAN) nanoporous structure of surface and surface layers. The research results, presented in the article, show that the suggested way to generate PAN allows to provide the granule porous structure without destruction of core and disposal of air from the granules. Analysis of experiments results has shown that various types of humidifiers can form various kinds of pores after drying – “mechanical” pores and “modification” pores. Various types of humidifiers have significant effect on the ratio of values of “mechanical” and “modification” pores. The obtained results allow to select the optimal humidifier composition, wh…
Thermal kinetics for the energy valorisation of polylactide/sisal biocomposites
2018
[EN] The thermal stability and decomposition kinetics of PLA/sisal biocomposites was discussed to evaluate the suitability of their use in energy recovery processes such as pyrolysis and combustion. The influence of the addition of sisal up to 30%wt, the presence of coupling agent, and the atmosphere of operation, i.e. inert or oxidative was discussed by means of multi-rate linear non-isothermal thermogravimetric experiments. All biocomposites showed a mean high heating value of 15 MJ/kg indicating their suitability for energy recovery processes. The thermal requirements of PLA/sisal decomposition were assessed in terms of onset decomposition temperature and apparent activation energy. A mi…
Hydrothermal liquefaction of wood using a modified multistage shrinking-core model
2020
Abstract Wood liquefaction in hot compressed water is modeled using the hydrolysis of Cellulose, Hemicellulose, and Lignin. These three components are reacted under catalyst-free subcritical conditions in a temperature range from 553 K to 640 K, and the heating rate ranges from 2 K/min to 6 K/min. Using a simplified reaction scheme, water-soluble products 1 (WSP), Biocrude, char, and gas are generated through intermediates with each wood component. A modified multistage shrinking core model is employed to simulate biomass particle degradation. The reaction and kinetic regime of the hydrothermal liquefaction 2 (HTL) process are treated separately for each wood component. Although the lack of…
A study of densified biochar as carbon source in the silicon and ferrosilicon production
2019
Abstract Biochar pellets were investigated as renewable reducing agents in substitution of coal and coke in the silicon and ferrosilicon production, where a high reactivity, good mechanical properties and low feedstock costs are appreciated. The usage of pyrolysis oil as binder was investigated as way to improve the quality of the pellets. Norway spruce biochar produced at 500, 800 and 1100 °C, was pelletized blended with pyrolysis oil and lignosulphonate. A second heat treatment was carried out at the same temperatures to evaluate the interaction between biochar and pyrolysis oil and to imitate the thermal stability of the pellets when used in a furnace. Density, tensile strength and mecha…
Air gasification of wood chips, wood pellets and grass pellets in a bubbling fluidized bed reactor
2021
Abstract Gasification is an attractive method for biomass-to-energy conversion and fluidized bed design is one of the best options for large scale operation. A bubbling fluidized bed reactor was used to analyze the effects of biomass type, equivalence ratio (ER) and temperature for product gas compositions. Wood chips, wood pellets and grass pellets were gasified between 650 °C and 800 °C temperature. The ER was varied between 0.08 and 0.16. Gasification of grass pellets was difficult at 800 °C due to agglomeration and the gas composition was poor compared to wood. The reactor performances improved over the temperature and 650 °C was not sufficient to achieve a reasonable carbon conversion.…
The Design and the Process Technology of a Rotational Mold
2019
The present paper highlights a series of introduction aspects of the rotational system for slush plastic casting, which are the characteristic elements of this fabrication technology and which consistsof the rotational molding. Also, the structure of a rotational mold and the methods used to obtain themold, are presented. The purpose of this research is to describe the parametric design of a rotationalmold and its fabrication process. The research method used to accomplish this purpose consist of the CAD – Modelling specific software utilized to carry out the parametric design of the rotational mold. After the parametric design it was adopted the manufacturing technology of the mold, using …