6533b854fe1ef96bd12ae910

RESEARCH PRODUCT

A study of densified biochar as carbon source in the silicon and ferrosilicon production

Gerrit Ralf SurupHenrik Kofoed NielsenLorenzo RivaTherese Videm Buø

subject

Materials science020209 energyPellets02 engineering and technologyRaw materialIndustrial and Manufacturing Engineeringchemistry.chemical_compoundFerrosilicon020401 chemical engineeringPyrolysis oilBiochar0202 electrical engineering electronic engineering information engineeringCoal0204 chemical engineeringElectrical and Electronic EngineeringCivil and Structural Engineeringbusiness.industryMechanical Engineeringdigestive oral and skin physiologyMetallurgyBuilding and ConstructionCokeVDP::Teknologi: 500::Materialteknologi: 520::Annen materialteknologi: 529PollutionGeneral EnergychemistrybusinessPyrolysis

description

Abstract Biochar pellets were investigated as renewable reducing agents in substitution of coal and coke in the silicon and ferrosilicon production, where a high reactivity, good mechanical properties and low feedstock costs are appreciated. The usage of pyrolysis oil as binder was investigated as way to improve the quality of the pellets. Norway spruce biochar produced at 500, 800 and 1100 °C, was pelletized blended with pyrolysis oil and lignosulphonate. A second heat treatment was carried out at the same temperatures to evaluate the interaction between biochar and pyrolysis oil and to imitate the thermal stability of the pellets when used in a furnace. Density, tensile strength and mechanical durability were analyzed before and after the second heat treatment. The CO2 reactivity was investigated under non-steady conditions. It was observed that the pellet quality is affected by the pyrolysis temperature, showing a relevant difference in properties between 500 °C and 800 °C. The combination of lignosulphonate and pyrolysis oil improved considerably the density and mechanical durability of the pellets. By the second heat treatment, the quality of the pellets was bettered significantly. Densification seems to reduce CO2 reactivity; however, pellets showed a still high reactivity.

yearjournalcountryeditionlanguage
2019-08-01
http://hdl.handle.net/11250/2637238