Search results for "16."
showing 10 items of 7809 documents
Enantiomeric Resolution of Asymmetric-Carbon-Free Binuclear Double-Stranded Cobalt(III) Helicates and Their Application as Catalysts in Asymmetric Re…
2018
A series of double-stranded binuclear helicates [Co2(H1)2]4+, [Co2(H2)2]4+, and [Co2(H3)2]4+, derived from monodeprotonated bis-pyridyl hydrazine-based ligands of H21, H22, and H23 with one, two, and three -CH2 spacers, were obtained. These asymmetric-carbon-free racemic helicates were separated into their ΔΔ and ΛΛ enantiomers. The resolved helicates were examined for the first time as enantioselective catalysts in asymmetric benzoylation and nitroaldol reactions.
Structural and metallo selectivity in the assembly of [2 × 2] grid-type metallosupramolecular species: Mechanisms and kinetic control
2011
An unsymmetrical bis(tridentate) ligand LH in which one binding site can be readily deprotonated forms a kinetically inert [Co(III)L(2)](+) complex which can be used as a "corner" species for the "Coupe du Roi" assembly of trans,trans-[Co(2)M(2)L(4)](6+) metallogrids (M = Fe(II), Co(II), Cu(II), Zn(II)). In the mixed Co(III)/Co(II) species, the oxidation states appear to be localised. In solution, the ligand LH forms octacationic, homometallic [2 × 2] grids with the individual labile metal ions Fe(II), Co(II), Cu(II), Zn(II), seemingly as mixtures of all possible isomers arising from the unsymmetrical nature of the ligand. In the solid state, however, [Zn(4)L(4)](CF(3)SO(3))(8)·4CH(3)CN cry…
Deep XMM-Newton Observations Reveal the Origin of Recombining Plasma in the Supernova Remnant W44
2019
Recent X-ray studies revealed over-ionized recombining plasmas (RPs) in a dozen mixed-morphology (MM) supernova remnants (SNRs). However, the physical process of the over-ionization has not been fully understood yet. Here we report on spatially resolved spectroscopy of X-ray emission from W44, one of the over-ionized MM-SNRs, using XMM-Newton data from deep observations, aiming to clarify the physical origin of the over-ionization. We find that combination of low electron temperature and low recombination timescale is achieved in the region interacting with dense molecular clouds. Moreover, a clear anti-correlation between the electron temperature and the recombining timescale is obtained f…
Simulated European stalagmite record and its relation to a quasi-decadal climate mode
2013
Abstract. A synthetic stalagmite record for the Bunker cave is constructed using a combined climate-stalagmite modeling approach. The power spectrum of the simulated speleothem calcite δ18O record has a pronounced peak at quasi-decadal time scale. Interestingly, mixing processes in the soil and karst above the cave represent a natural low-pass filter of the speleothem climate archive. We identify a quasi-decadal mode characterized by a "tripole pattern" of sea surface temperature affecting stalagmite δ18O values. This pattern, which is well-known in literature as the quasi-decadal mode in the North Atlantic, propagates eastwards and affects western European temperature surrounding the cave.…
THEMIS: A Parameter Estimation Framework for the Event Horizon Telescope
2020
This is an open access article.-- Full list of authors: Broderick, Avery E.; Gold, Roman; Karami, Mansour; Preciado-López, Jorge A.; Tiede, Paul; Pu, Hung-Yi; Akiyama, Kazunori; Alberdi, Antxon; Alef, Walter; Asada, Keiichi; Azulay, Rebecca; Baczko, Anne-Kathrin; Baloković, Mislav; Barrett, John; Bintley, Dan; Blackburn, Lindy; Boland, Wilfred; Bouman, Katherine L.; Bower, Geoffrey C.; Bremer, Michael; Brinkerink, Christiaan D.; Brissenden, Roger; Britzen, Silke; Broguiere, Dominique; Bronzwaer, Thomas; Byun, Do-Young; Carlstrom, John E.; Chael, Andrew; Chatterjee, Shami; Chatterjee, Koushik; Chen, Ming-Tang; Chen, Yongjun; Cho, Ilje; Conway, John E.; Cordes, James M.; Crew, Geoffrey B.; Cu…
Seismic sources and stress transfer interaction among axial normal faults and external thrust fronts in the Northern Apennines (Italy): A working hyp…
2016
In this study we analyse the main potential seismic sources in some axial and frontal sectors of the Northern Apennines, in Italy. This region was hit by a peculiar series of earthquakes that started in 1916 on the external thrust fronts near Rimini. Later, in 1917-1921, seismicity (up to Mw approximate to 6.5) shifted into the axial zone and clearly migrated north-westward, along the belt of active normal faults. The collection of fault-slip data focused on the active normal faults potentially involved in this earthquake series. The acquired data allowed us to better characterize the geometry and kinematics of the faults. In a few instances, the installation of local seismic networks durin…
Holocene land-cover reconstructions for studies on land cover-climate feedbacks
2010
The major objectives of this paper are: (1) to review the pros and cons of the scenarios of past anthropogenic land cover change (ALCC) developed during the last ten years, (2) to discuss issues related to pollen-based reconstruction of the past land-cover and introduce a new method, REVEALS (Regional Estimates of VEgetation Abundance from Large Sites), to infer long-term records of past land-cover from pollen data, (3) to present a new project (LANDCLIM: LAND cover – CLIMate interactions in NW Europe during the Holocene) currently underway, and show preliminary results of REVEALS reconstructions of the regional land-cover in the Czech Republic for five selected time windows of the Holocene…
Effects of dating errors on nonparametric trend analyses of speleothem time series
2012
A fundamental problem in paleoclimatology is to take fully into account the various error sources when examining proxy records with quantitative methods of statistical time series analysis. Records from dated climate archives such as speleothems add extra uncertainty from the age determination to the other sources that consist in measurement and proxy errors. This paper examines three stalagmite time series of oxygen isotopic composition (δ18O) from two caves in western Germany, the series AH-1 from the Atta Cave and the series Bu1 and Bu4 from the Bunker Cave. These records carry regional information about past changes in winter precipitation and temperature. U/Th and radiocarbon dat…
Black shale deposition during Toarcian super-greenhouse driven by sea level
2013
Abstract. One of the most elusive aspects of the Toarcian oceanic anoxic event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the end of the overarching positive trend in the carbon isotopes that characterises the T-OAE. In the present study, we have attempted to establish a sequence stratigraphic framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a…
Effect of the Ordovician paleogeography on the (in)stability of the climate.
2014
The Ordovician Period (485–443 Ma) is characterized by abundant evidence for continental-sized ice sheets. Modeling studies published so far require a sharp CO2 drawdown to initiate this glaciation. They mostly used non-dynamic slab mixed-layer ocean models. Here, we use a general circulation model with coupled components for ocean, atmosphere, and sea ice to examine the response of Ordovician climate to changes in CO2 and paleogeography. We conduct experiments for a wide range of CO2 (from 16 to 2 times the preindustrial atmospheric CO2 level (PAL)) and for two continental configurations (at 470 and at 450 Ma) mimicking the Middle and the Late Ordovician conditions. We find that the temper…