Search results for "40"
showing 10 items of 17345 documents
Equivalence of viscosity and weak solutions for the normalized $p(x)$-Laplacian
2018
We show that viscosity solutions to the normalized $p(x)$-Laplace equation coincide with distributional weak solutions to the strong $p(x)$-Laplace equation when $p$ is Lipschitz and $\inf p>1$. This yields $C^{1,\alpha}$ regularity for the viscosity solutions of the normalized $p(x)$-Laplace equation. As an additional application, we prove a Rad\'o-type removability theorem.
Estimating the safety performance function for urban unsignalized four-legged one-way intersections in Palermo, Italy
2014
Abstract Starting from consideration that urban intersections are sites with promise for safety and operational improvements, the paper describes the steps taken to develop a crash predictive model for estimating the safety performance of urban unsignalized intersections located in Palermo, Italy. The focus is on unsignalized four-legged one-way intersections widespread in Italian downtowns. The sample considered in the study consist of 92 intersections in Palermo, Italy. For the study were collected crashes occurred in the sites during the years 2006-2012, geometric design and functional characteristics and traffic flow. Results showed that data were overdispersed and NB1 distributed. In o…
Monitoring Commercial Starter Culture Development in Presence of Red Grape Pomace Powder to Produce Polyphenol-Enriched Fresh Ovine Cheeses at Indust…
2021
Red grape Nero d’Avola cultivar grape pomace powder (GPP) was applied during fresh ovine cheese production in order to increase polyphenol content. Before cheeses were produced, the bacteria of a freeze-dried commercial starter culture were isolated and tested in vitro against GPP. Two dominant strains, both resistant to GPP, were identified. Thestarter culture was inoculated in pasteurized ewe’s milk and the curd was divided into two bulks, one added with 1% (w/w) GPP and another one GPP-free. GPP did not influence the starter culture development, since lactic acid bacteria (LAB) counts were 109 CFU/g in both cheeses at 30 d. To exclude the interference of indigenous LAB, the pasteurized m…
An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide
2016
The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings. peerReviewed
1,1prime-Binaphthyl-2-methylpyridinium-based peroxophosphotungstate salts: synthesis, characterization, and their use as oxidation catalysts
2009
A series of 1,1′-binaphthyl-2-methylammonium and pyridinium salts 6, 7, and 8 was synthesized through the coupling reaction of 2-(bromomethyl)-1,1′-binaphthalene (5) with the dendritic tetraallyl pyridinedicarbinol dendron 2 as well as triethylamine and 4-tert-butylpyridine. Tetraallyl pyridinedicarbinol dendron 2 was prepared by allylation of commercially available diethyl pyridine-3,5-dicarboxylate (1). The allylation of 2 with allyltrimethylsilane in the presence of boron trifluoride was unsuccessful, as tetraallyl pyridinedicarbinol trifluoroboron adduct 3 was obtained instead of expected hexaallylpyridine compound 4. The catalytic hydrogenation of allyl groups of the ammonium salt of 2…
DFT Prediction of Enhanced Reducibility of Monoclinic Zirconia upon Rhodium Deposition.
2018
Oxides are an important class of materials and are widely used, for example, as supports in heterogeneous catalysis. In a number of industrial catalytic processes, oxide supports actively participate in chemical transformations by releasing lattice oxygen anions. While this is intuitively understood for reducible oxides, the reducibility of irreducible oxides may be modified via nanoengineering or upon inclusion of foreign species. Our calculations predict that the ability of irreducible monoclinic zirconia to release oxygen improves substantially upon deposition of rhodium. Through a comprehensive screening of Rh/ZrO2 with different size of the rhodium species, we find that a Rh adatom and…
Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi-Lability.
2021
We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E–H bonds at one or both of the tin centres through dissociation of the hemi-labile N–Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr ( n = 1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron-withdrawing properties of the –Sn(Ar)H– backbone units generated via oxidative addition. peerReviewed
Oxygen uptake, acid-base balance and hormonal responses in maximal 300 - 400 m running in child, adolescent and adult athletes
2013
Vilmi, Nikke (2013). Oxygen uptake, acid-base balance and hormonal responses in maximal 300 - 400 m running in child, adolescent and adult athletes. Department of Biology of Physical Activity, University of Jyväskylä, Master's thesis, Science of Sport Coaching and Fitness Testing, 55 pp. The 400 m sprint demands both aerobic and anaerobic energy systems. During the race the acid-base balance of the body is disturbed and that has effects on the oxygen uptake. The purpose of this study was to investigate the oxygen uptake and acid-base balance during and after the maximal anaerobic running test in child (300 m), adolescent (350 m) and adult (400 m) athletes. Furthermore, the aim was also to d…
$\Lambda_c^{\pm}$ production in pp collisions with a new fragmentation function
2020
Physical review / D D 101(11), 114021 (2020). doi:10.1103/PhysRevD.101.114021
Investigations of Anisotropic Flow Using Multiparticle Azimuthal Correlations in pp, p-Pb, Xe-Xe, and Pb-Pb Collisions at the LHC
2019
Measurements of anisotropic flow coefficients ($v_n$) and their cross-correlations using two- and multi-particle cumulant methods are reported in collisions of pp at $\sqrt{s} = 13$ TeV, p-Pb at $\sqrt{s_{_{\rm NN}}} = 5.02$ TeV, Xe-Xe at $\sqrt{s_{_{\rm NN}}} = 5.44$ TeV, and Pb-Pb at $\sqrt{s_{_{\rm NN}}} = 5.02$ TeV recorded with the ALICE detector. The multiplicity dependence of $v_n$ is studied in a very wide range from 20 to 3000 particles produced in the mid-rapidity region $|��|<0.8$ for the transverse momentum range $0.2 < p_{\rm T} < 3.0$ GeV/$c$. An ordering of the coefficients $v_2 > v_3 > v_4$ is found in pp and p-Pb collisions, similar to that seen in large coll…