6533b82bfe1ef96bd128e2f9

RESEARCH PRODUCT

An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide

Evgeny BulatovTatiana G. ChulkovaAnastasiia AfanasenkoFedor M. DolgushinMatti Haukka

subject

oxidation010405 organic chemistryoxime ligandsMetals and Alloyschemistry.chemical_elementoxidative chlorination010402 general chemistryOxime01 natural sciencesMedicinal chemistry0104 chemical sciencesCatalysisInorganic ChemistryElectrophilic substitutionchemistry.chemical_compoundchemistryElectrophileMaterials ChemistryChlorineOrganic chemistryAcetaldoximeBenzeneOrganometallic chemistryplatinum complexes

description

The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings. peerReviewed

yearjournalcountryeditionlanguage
2016-03-01Transition Metal Chemistry
https://doi.org/10.1007/s11243-016-0034-7