Search results for "43"
showing 10 items of 1438 documents
Er3+-doped GeGaSbS glasses for mid-IR fibre laser application: Synthesis and rare earth spectroscopy
2008
International audience; With an infrared transparency extended to 10 µm, low multiphonon relaxation rates and suitable rare earth solubility, sulphide glasses in the Ge-Ga-Sb-S system allow radiative emission from rare earth ions in the mid-IR range. The Er3+ ion, widely studied in glass fibres for optical amplification at 1.5 µm, presents an interesting transition for mid-IR applications around 4.5 µm (4I9/2→ 4I11/2). Thus, the aim of this work is to evaluate the Er3+-doped Ge20Ga5Sb10S65 glass as a potential fibre laser source operating in the 3-5 µm mid-IR spectral region. For that purpose, absorption and emission spectra were recorded from visible to mid-IR and the radiative lifetimes o…
Optical and Vibrational Spectra of CsCl-Enriched GeS2-Ga2S3 Glasses
2016
Optical and FTIR spectroscopy was employed to study the properties of 80GeS2-20Ga2S3-CsCl chalcohalide glasses with CsCl additives in a temperature range of 77–293 K. It is shown that CsCl content results in the shift of fundamental absorption edge in the visible region. Vibrational bands in FTIR spectra of (80GeS2-20Ga2S3)100 − х (СsCl) x (x = 5, 10, and 15) are identified near 2500 cm−1, 3700 cm−1,, around 1580 cm−1, and a feature at 1100 cm−1. Low energy shifts of vibrational frequencies in glasses with a higher amount of CsCl can be caused by possible thermal expansion of the lattice and nanovoid agglomeration formed by CsCl additives in the inner structure of the Ge-Ga-S glass.
On-surface synthesis on a bulk insulator surface
2018
On-surface synthesis has rapidly emerged as a most promising approach to prepare functional molecular structures directly on a support surface. Compared to solution synthesis, performing chemical reactions on a surface offers several exciting new options: due to the absence of a solvent, reactions can be envisioned that are otherwise not feasible due to the insolubility of the reaction product. Perhaps even more important, the confinement to a two-dimensional surface might enable reaction pathways that are not accessible otherwise. Consequently, on-surface synthesis has attracted great attention in the last decade, with an impressive number of classical reactions transferred to a surface as…
Laser beam scattering effects in non-absorbent inhomogenous polymers
2007
Ilie, Mariana Kneip, Jean-Christophe Mattei, Simone Nichici, Alexandru Roze, Claude Girasole, Thierry; In this paper a numerical model for laser beam scattering in the semi-transparent polymers is presented, using a Monte Carlo algorithm and the Mie theory. The algorithm correctly accounts for the independent multiply-scattered light. We describe the algorithm, present a number of important parameters that account in the welding process, and explicitly show how the algorithm can be used to estimate the laser beam intensity both inside the semi-transparent component and at the welding interface and the beam widening. For the model validation an experimental bench test has been realized and s…
Low loss microstructured chalcogenide fibers for large non linear effects at 1995 nm
2010
International audience; Microstructured optical fibers (MOFs) are traditionally prepared using the stack and draw technique. In order to avoid the interfaces problems observed in chalcogenide glasses, we have developed a new casting method to prepare the chalcogenide preform. This method allows to reach optical losses around 0.4 dB/m at 1.55 µm and less than 0.05 dB/m in the mid IR. Various As(38)Se(62) chalcogenide microstructured fibers have been prepared in order to combine large non linear index of these glasses with the mode control offered by MOF structures. Small core fibers have been drawn to enhance the non linearities. In one of these, three Stokes order have been generated by Ram…
Fourth-order cascaded Raman shift in AsSe chalcogenide suspended-core fiber pumped at 2 μm
2011
International audience; Cascaded Raman wavelength shifting up to the fourth order ranging from 2092 to 2450nm is demonstrated using a nanosecond pump at 1995nm in a low-loss As38Se62 suspended-core microstructured fiber. These four Stokes shifts are obtained with a low peak power of 11W, and only 3W are required to obtain three shifts. The Raman gain coefficient for the fiber is estimated to (1.6 +-0.5)x 10e−11 m/W at 1995nm. The positions and the amplitudes of the Raman peaks are well reproduced by the numerical simulations of the nonlinear propagation.
Theory of parabolic pulse propagation in nonlinear dispersion decreasing optical fiber amplifiers
2008
Optical fibers ; Nonlinear optics ; Optical fiber amplifiers ; Optical amplifier ; Optical solitons ; Electromagnetic wave propagation ; Pulse propagation ;; International audience; We show that pulse spectral broadening in normally dispersive nonlinear fiber amplifiers may be enhanced by introducing a suitable dispersion tapering. We obtain an analytical dispersion profile that permits one to reduce pulse propagation in a varying dispersion fiber to the case of an equivalent fiber with constant parameters.
Vibrations of free and embedded anisotropic elastic spheres:Application to low-frequency Raman scattering of silicon nanoparticles in silica
2004
Vibrational mode frequencies and damping are calculated for an elastic sphere embedded in an infinite, homogeneous, isotropic elastic medium. Anisotropic elasticity of the sphere significantly shifts the frequencies in comparison to simplified calculations that assume isotropy. New low-frequency Raman light scattering data are presented for silicon spheres grown in a ${\mathrm{SiO}}_{2}$ glass matrix. Principal features of the Raman spectrum are not correctly described by a simple model of the nanoparticle as a free, isotropic sphere, but require both matrix effects and the anisotropy of the silicon to be taken into account. Libration, not vibration, is the dominant mechanism.
Parabolic pulse generation with active or passive dispersion decreasing optical fibers
2007
International audience; We experimentally demonstrate the possibility to generate parabolic pulses via a single dispersion decreasing optical fiber with normal dispersion. We numerically and experimentally investigate the influence of the dispersion profile, and we show that a hybrid configuration combining dispersion decrease and gain has several benefits on the parabolic generated pulses.
PANI-Based Wearable Electrochemical Sensor for pH Sweat Monitoring
2021
Nowadays, we are assisting in the exceptional growth in research relating to the development of wearable devices for sweat analysis. Sweat is a biofluid that contains useful health information and allows a non-invasive, continuous and comfortable collection. For this reason, it is an excellent biofluid for the detection of different analytes. In this work, electrochemical sensors based on polyaniline thin films deposited on the flexible substrate polyethylene terephthalate coated with indium tin oxide were studied. Polyaniline thin films were abstained by the potentiostatic deposition technique, applying a potential of +2 V vs. SCE for 90 s. To improve the sensor performance, the electronic…