Search results for "44"

showing 10 items of 1507 documents

Antioxidant Bibenzyl Derivatives from Notholaena nivea Desv.

2011

Four new bibenzyl derivatives were isolated, together with other known bibenzyls, by bioassay-guided fractionation of a CHCl3-MeOH extract of Notholaena nivea Desv. (Pteridaceae) aerial parts. The structures were elucidated by NMR, ESIMS and other spectral analyses. Their antioxidative effects towards superoxide, lipidic peroxidation and the 2,2'- azino-bis-3- ethilbenzothiazoline-6-sulfonic acid (ABTS) radical were assayed. Results showed that the compound 3,12-dihydroxy-5-methoxybibenzyl (6) is the most active compound in the ABTS free-radical scavenging test, while in the coupled oxidation of ȕ-carotene and linoleic acid assay the compound 5,12-dihydroxy-3-methoxydibenzyl-6- carboxylic a…

PteridaceaeSpectrometry Mass Electrospray IonizationMagnetic Resonance SpectroscopyAntioxidantStereochemistrymedicine.medical_treatmentLinoleic acidNatural products active principles oxidative stress.Pharmaceutical ScienceArticleAntioxidantsAnalytical Chemistrylcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistryDrug DiscoverymedicineBibenzylPhysical and Theoretical Chemistrychemistry.chemical_classificationABTSbiologyPlant Extractsbibenzyl derivativesSuperoxideOrganic ChemistryNotholaenabiology.organism_classificationNMR<em>Notholaena nivea</em>; bibenzyl derivatives; NMR; antioxidants activityEnzymechemistryBiochemistryChemistry (miscellaneous)PteridaceaeMolecular MedicineNotholaena niveaantioxidants activityMolecules
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Aza- and Azo-Stilbenes: Bio-Isosteric Analogs of Resveratrol

2020

Several series of natural polyphenols are described for their biological and therapeutic potential. Natural stilbenoid polyphenols, such as trans-resveratrol, pterostilbene and piceatannol are well-known for their numerous biological activities. However, their moderate bio-availabilities, especially for trans-resveratrol, prompted numerous research groups to investigate innovative and relevant synthetic resveratrol derivatives. This review is focused on isosteric resveratrol analogs aza-stilbenes and azo-stilbenes in which the C=C bond between both aromatic rings was replaced with C=N or N=N bonds, respectively. In each series, synthetic ways will be displayed, and structural sights will be…

PterostilbeneResearch groupsPharmaceutical ScienceReviewResveratrolStilbenoidAntioxidantsAnalytical Chemistrylcsh:QD241-44103 medical and health scienceschemistry.chemical_compound0302 clinical medicinelcsh:Organic chemistryDrug DiscoveryStilbenesPhysical and Theoretical Chemistryazo-stilbene030304 developmental biologyPiceatannol0303 health sciencesAza CompoundsMolecular Structurestructure-activity relationshipOrganic Chemistryfood and beveragesStereoisomerismbio-isosterismtrans-resveratrolCombinatorial chemistryaza-stilbenechemistryChemistry (miscellaneous)PolyphenolResveratrol030220 oncology & carcinogenesisMolecular MedicineAzo CompoundsMolecules
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Phytochemical Studies on Ptilostemon greuteri Raimondo & Domina (Compositae)

2012

Ptilostemon greuteri Raimondo & Domina is described as a new species and its growth is limited to the area of the province of Trapani. Essential oils of aerial parts of P. greuteri were analized by gas chromatography-mass spectrometry (GC-MS). The analysis of acetonic extract of aerial parts led to identification of triterpenes components: α-amyrin, β-amyrin, α-amyrin acetate, β-amyrin acetate, lupeol, lupeol acetate and taraxasterol. CC and preparative TLC of acetonic extracts has yielded lignan lactone and a sesquiterpene lactone that have been isolated previously from other Ptilostemon species.

Ptilostemon greuterilcsh:Chemistrylcsh:QD241-441Compositaepentacyclic triterpeneslcsh:QD1-999lcsh:Organic chemistryESSENTIAL OIL AERIAL PARTS NMRlcsh:Botanysesquiterpene lactonelignan lactoneessential oillcsh:QK1-989
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Endeudamiento municipal en la región de Lleida a finales del siglo XVII

2018

Este articulo quiere analizar la evolución del endeudamiento de los municipios de la región económica de Lleida a finales del siglo XVII para poner de relieve no solo el enorme peso que este tuvo sobre los municipios catalanes de los siglos modernos, sino también el efecto que causó la expansión económica de los años previos a la guerra de Sucesión sobre esta deuda. Durante los años estudiados hemos podido observar una mejora evidente sobre el nivel de endeudamiento comunal, pero también la persistencia de problemas crónicos en las finanzas municipales. In this paper is analyzed the municipal debt evolution of the Lleida region during the late seventeenth century. It highlights the importan…

Public debtDeuda públicaUNESCO::HISTORIAEconomic crisisMunicipal financesiglo XVIIRecuperación económicaEconomic recovery0210-9093 553 Estudis: Revista de historia moderna 500918 2018 44 6623955 Endeudamiento municipal en la región de Lleida a finales del siglo XVII Ramon MolinsGabriel 173 196Finanzas municipalesRevista de historia moderna 500918 2018 44 6623955 Endeudamiento municipal en la región de Lleida a finales del siglo XVII Ramon Molins [0210-9093 553 Estudis]:HISTORIA [UNESCO]Crisis económicaSeventeenth century
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Contribution of bronchial biopsies in the evaluation of pathogenesis and progression of COPD.

2016

This review summarizes and discusses the lung pathology of COPD patients emphasising on inflammatory cell phenotypes and mechanisms which prevail in different clinical conditions. In bronchial biopsies a series of events takes place during the progression of the disease from mild to severe. T-lymphocytes, particularly CD8+ cells and macrophages are the prevalent inflammatory cells in the lungs of healthy smokers and patients with mild/moderate COPD. This T-cell activation seems to be sustained by CD4+, CD8+ cells and macrophages expressing transcription factors and Tc1 cytokines such as NF-kB, STAT4 and IFNγ. In contrast, severe disease is characterized by lymphocytes producing greater amo…

Pulmonary and Respiratory MedicinePathologymedicine.medical_specialtyinflammatory cellsBiopsylcsh:MedicineContext (language use)BronchiPathogenesischemistry.chemical_compoundPulmonary Disease Chronic ObstructivemedicineCOPDHumansSTAT4COPDbiologybusiness.industryNitrotyrosineCD44lcsh:Rmedicine.diseasebronchial biopsiesNeutrophiliarespiratory tract diseaseschemistryIntegrin alpha MImmunologybiology.proteinmedicine.symptomCardiology and Cardiovascular MedicinebusinessMonaldi archives for chest disease = Archivio Monaldi per le malattie del torace
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Unique continuation property and Poincar�� inequality for higher order fractional Laplacians with applications in inverse problems

2020

We prove a unique continuation property for the fractional Laplacian $(-\Delta)^s$ when $s \in (-n/2,\infty)\setminus \mathbb{Z}$. In addition, we study Poincar\'e-type inequalities for the operator $(-\Delta)^s$ when $s\geq 0$. We apply the results to show that one can uniquely recover, up to a gauge, electric and magnetic potentials from the Dirichlet-to-Neumann map associated to the higher order fractional magnetic Schr\"odinger equation. We also study the higher order fractional Schr\"odinger equation with singular electric potential. In both cases, we obtain a Runge approximation property for the equation. Furthermore, we prove a uniqueness result for a partial data problem of the $d$-…

Pure mathematicsControl and Optimizationfractional Schrödinger equationApproximation propertyPoincaré inequalityRadon transform.01 natural sciencesinversio-ongelmatSchrödinger equationsymbols.namesakefractional Poincaré inequalityOperator (computer programming)Mathematics - Analysis of PDEsFOS: MathematicsDiscrete Mathematics and CombinatoricsUniquenesskvanttimekaniikka0101 mathematicsepäyhtälötMathematicsosittaisdifferentiaaliyhtälötPlane (geometry)inverse problemsComputer Science::Information Retrieval010102 general mathematicsOrder (ring theory)Gauge (firearms)Mathematics::Spectral Theoryunique continuationFunctional Analysis (math.FA)010101 applied mathematicsMathematics - Functional AnalysisModeling and Simulationsymbolsfractional LaplacianAnalysis35R30 46F12 44A12Analysis of PDEs (math.AP)
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Fourier analysis of periodic Radon transforms

2019

We study reconstruction of an unknown function from its $d$-plane Radon transform on the flat $n$-torus when $1 \leq d \leq n-1$. We prove new reconstruction formulas and stability results with respect to weighted Bessel potential norms. We solve the associated Tikhonov minimization problem on $H^s$ Sobolev spaces using the properties of the adjoint and normal operators. One of the inversion formulas implies that a compactly supported distribution on the plane with zero average is a weighted sum of its X-ray data.

Pure mathematicsGeneral MathematicsBessel potential01 natural sciencesTikhonov regularizationsymbols.namesakeFOS: Mathematics0101 mathematicsperiodic distributionsMathematicsRadon transformRadon transformApplied Mathematics44A12 42B05 46F12 45Q05010102 general mathematicsZero (complex analysis)Function (mathematics)Fourier analysisFunctional Analysis (math.FA)010101 applied mathematicsSobolev spaceregularizationMathematics - Functional AnalysisDistribution (mathematics)Fourier analysissymbolsAnalysis
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Selective versions of chain condition-type properties

2015

We study selective and game-theoretic versions of properties like the ccc, weak Lindel\"ofness and separability, giving various characterizations of them and exploring connections between these properties and some classical cardinal invariants of the continuum.

Pure mathematicsRothberger spaceGeneral MathematicsMathematics::General TopologyType (model theory)01 natural sciencesChain (algebraic topology)FOS: Mathematicstopological games0101 mathematicsMathematics - General TopologyMathematicsDiscrete mathematicsContinuum (topology)010102 general mathematicsGeneral Topology (math.GN)TEORIA DOS JOGOSMathematics - Logic16. Peace & justice010101 applied mathematicsMathematics::LogicPrimary: 54A25 03E17 91A44 Secondary: 54D35 54D10selection principlescardinal inequalitiesLogic (math.LO)Chain conditionsActa Mathematica Hungarica
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Pharmaceutical potential of synthetic and natural pyrrolomycins

2015

The emergence of antibiotic resistance is currently considered one of the most important global health problem. The continuous onset of multidrug-resistant Gram-positive and Gram-negative bacterial strains limits the clinical efficacy of most of the marketed antibiotics. Therefore, there is an urgent need for new antibiotics. Pyrrolomycins are a class of biologically active compounds that exhibit a broad spectrum of biological activities, including antibacterial, antifungal, anthelmintic, antiproliferative, insecticidal, and acaricidal activities. In this review we focus on the antibacterial activity and antibiofilm activity of pyrrolomycins against Gram-positive and Gram-negative pathogens…

Pyoluteorinantibiotic resistancemedicine.drug_classAntibioticsPharmaceutical ScienceMicrobial Sensitivity TestsReviewPharmacologyAntibiofilm agentpyrrolomycinSettore BIO/19 - Microbiologia GeneraleAnalytical Chemistrylcsh:QD241-441Antibiotic resistancelcsh:Organic chemistryDrug DiscoveryDrug Resistance BacterialMedicineAnimalsHumansPyrrolesClinical efficacyPhysical and Theoretical ChemistrypyrrolomycinspentabromopseudilinLow toxicityBacteriabusiness.industryOrganic ChemistryBiological activityBacterial Infectionsantibiofilm agentsAntimicrobialSettore CHIM/08 - Chimica FarmaceuticaAnti-Bacterial AgentsChemistry (miscellaneous)BiofilmsPentabromopseudilinMolecular MedicinebusinessAntibacterial activity
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Conformational and Tautomeric Control by Supramolecular Approach in Ureido-N-iso-propyl,N’-4-(3-pyridin-2-one)pyrimidine

2019

Ureido-N-iso-propyl,N&rsquo

PyrimidineStereochemistryMolecular ConformationSupramolecular chemistryPharmaceutical ScienceArticleCatalysisAnalytical Chemistrylcsh:QD241-441chemistry.chemical_compoundIsomerismlcsh:Organic chemistryDrug DiscoveryPyridineUreaMoleculeMoietyPhysical and Theoretical ChemistryMolecular switchvetysidoksetintermolecular interactionsOrganic ChemistryTemperaturemolekyylithydrogen bondingTautomermolecular switchKineticstautomerismPyrimidineschemistryChemistry (miscellaneous)Proton NMRQuantum TheoryThermodynamicsMolecular MedicineProtonstautomeria
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