Search results for "49"

showing 10 items of 1208 documents

CCDC 1575262: Experimental Crystal Structure Determination

2018

Related Article: Yan-Long Ma, Hua Ke, Arto Valkonen, Kari Rissanen, Wei Jiang|2018|Angew.Chem.,Int.Ed.|57|709|doi:10.1002/anie.201711077

Space GroupCrystallography[3]-(11'-(decane-110-diyl)bis(14-diazabicyclo[2.2.2]octan-1-ium))-bis(10163642-tetrabutoxy-132839505456-hexaoxatridecacyclo[43.7.1.1351.12327.12529.027.0611.01520.01924.03237.03355.04146.04953]hexapentaconta-246810151719212329(55)30323436414345(53)4648-icosaene)-rotaxane bis(hexafluorophosphate) 12-dichloroethane acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1417790: Experimental Crystal Structure Determination

2015

Related Article: Guobao Huang, Zhenfeng He, Chen-Xi Cai, Fangfang Pan, Dingqiao Yang, Kari Rissanen, Wei Jiang|2015|Chem.Commun.|51|15490|doi:10.1039/C5CC06768E

Space GroupCrystallographyanti-10183846-Tetra-n-butoxy-30545860-tetraoxa-13154143-tetra-azatridecacyclo[47.7.1.1355.12529.12731.027.0611.01722.02126.03439.03559.04550.05357]hexaconta-246810171921232531(59)323436384547495153(57)-icosaene-1442-dione acetonitrile chloroform 14-dioxane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1555957: Experimental Crystal Structure Determination

2017

Related Article: Disha Mungalpara, Arto Valkonen, Kari Rissanen, Stefan Kubik|2017|Chemical Science|8|6005|doi:10.1039/C7SC02700A

Space GroupCrystallographybis(tetra-n-butylammonium) dihydrogen diphosphate 6183042-tetramethyl-345815161720272829323940414449515355-icosa-azanonacyclo[43.3.1.125.1913.11417.12125.12629.13337.13841]hexapentaconta-1(49)2(56)39(55)101214(54)1521(53)222426(52)2733(51)343638(50)394547-icosaene-7193143-tetrone dimethyl sulfoxide unknown solvate hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1553488: Experimental Crystal Structure Determination

2018

Related Article: Djamille Azazna, Marine Lafosse, Julie Rivollier, Jialan Wang, Imen Ben Cheikh, Michel Meyer, Pierre Thury, Jean-Pierre Dognon, Gaspard Huber, Marie-Pierre Heck|2018|Chem.-Eur.J.|24|10793|doi:10.1002/chem.201801468

Space GroupCrystallographytetra-n-butylammonium 5713152123293137394547-dodecakis(prop-2-en-1-yl)-1357911131517192123252729313335373941434547-tetracosaazatridecacyclo[41.5.1.139.11117.11925.12733.13541.048.01216.02024.02832.03640.04448]tetrapentacontane-61422303846495051525354-dodecone chloride unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Brief an Garlieb H. Merkel

1798

Ms. 930a, Nr. 13, Bl. 35r-[36v] August Hennings. Brief an Garlieb H. Merkel, Ploen, den 20. Dece[mber] 1798 Autora rokraksts / Autograph, vācu val. / Deutsch [3] lpp. / S. Attēlu numuri / Bildnummern: 930a-013-1, 930a-013-2, 930a-013-3 Hennings, der dänische Amtmann in Plön und Bekannte des dänischen Ministers Schimmelmann, schreibt in seiner Funktion als Herausgeber der Zeitschrift „Genius der Zeit“ an Merkel. Er kündigt an, einen Aufsatz zu drucken, in dem Merkel Partei für seinen Schriftstellerkollegen Johann(es) Falk ergreift, worum ihn dieser in einem anderen Brief gebeten hat (vgl. Ms. 930a-012). Merkels Aufsatz soll in der Februarausgabe 1799 erscheinen. Der Aufsatz sowie der hier üb…

SpätaufklärungGoija Francisko Hosē (1746-1828)BriefgeheimnisLiteraturMerķelis Garlībs Helvigs (1769-1850)Gabriel Friedrich August (1783-1869)sarakstes noslēpumsagrīnā romantikaSanzio Raffaello (1483-1520)muižas saimniecībaklīnika BerlīnēstrīdsFrühromantikGutswirtschaftMerkel Garlieb Helvig (1769-1850):HUMANITIES and RELIGION [Research Subject Categories]Hennings August (1746-1826)CharitéApgaismības laikmetsvēlīnā apgaismībaliteratūraZeitschrift „Genius der Zeit“Goya Francisco (1746-1828)Falk Johann(es) Daniel (1768-1826)FehdeStreitBiester Johann Erich (1749-1816)Aufklärung
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Peraldi, Michel. 2018. Marrakech, ou le souk des possibles. Du moment colonial à l’ère néolibérale. Paris: La Découverte

2019

Rezension

Stadtentwicklunglcsh:Language and LiteratureMarrakechlcsh:PC1-5498Stadtsoziologielcsh:Romanic languageslcsh:PGeneral MedicineNeoliberalisierung1912 bis heuteapropos [Perspektiven auf die Romania]
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Sharp dimension free quantitative estimates for the Gaussian isoperimetric inequality

2017

We provide a full quantitative version of the Gaussian isoperimetric inequality: the difference between the Gaussian perimeter of a given set and a half-space with the same mass controls the gap between the norms of the corresponding barycenters. In particular, it controls the Gaussian measure of the symmetric difference between the set and the half-space oriented so to have the barycenter in the same direction of the set. Our estimate is independent of the dimension, sharp on the decay rate with respect to the gap and with optimal dependence on the mass.

Statistics and ProbabilityGaussianGaussian isoperimetric inequality01 natural sciencesPerimeterSet (abstract data type)symbols.namesakeMathematics - Analysis of PDEsDimension (vector space)quantitative isoperimetric inequalityFOS: MathematicsMathematics::Metric Geometry0101 mathematicsSymmetric differenceGaussian isoperimetric inequalityQuantitative estimatesMathematics010102 general mathematicsMathematical analysisProbability (math.PR)49Q20Gaussian measure010101 applied mathematicssymbolsHigh Energy Physics::Experiment60E15Statistics Probability and UncertaintyMathematics - ProbabilityAnalysis of PDEs (math.AP)
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Extremal polynomials in stratified groups

2018

We introduce a family of extremal polynomials associated with the prolongation of a stratified nilpotent Lie algebra. These polynomials are related to a new algebraic characterization of abnormal subriemannian geodesics in stratified nilpotent Lie groups. They satisfy a set of remarkable structure relations that are used to integrate the adjoint equations.

Statistics and Probabilityextremal polynomialsMathematics - Differential GeometryPure mathematicsGeodesicStructure (category theory)Group Theory (math.GR)Characterization (mathematics)algebra01 natural sciencesdifferentiaaligeometriaMathematics - Analysis of PDEsMathematics - Metric Geometry53C17FOS: Mathematics0101 mathematicsAlgebraic numberMathematics - Differential Geometry; Mathematics - Differential Geometry; Mathematics - Analysis of PDEs; Mathematics - Group Theory; Mathematics - Metric Geometry; Mathematics - Optimization and Control; 53C17; 49K30; 17B70Mathematics - Optimization and ControlMathematics010102 general mathematicsStatisticsta111polynomitProlongation53C17 49K30 17B70Lie groupMetric Geometry (math.MG)abnormal extremals010101 applied mathematicsNilpotent Lie algebraNilpotentsub-Riemannian geometryabnormal extremals extremal polynomials Carnot groups sub-Riemannian geometryAbnormal extremals; Carnot groups; Extremal polynomials; Sub-Riemannian geometry; Analysis; Statistics and Probability; Geometry and Topology; Statistics Probability and UncertaintyDifferential Geometry (math.DG)Optimization and Control (math.OC)Carnot groups17B70Probability and UncertaintyGeometry and TopologyStatistics Probability and UncertaintyMathematics - Group TheoryAnalysisAnalysis of PDEs (math.AP)Mathematics - Differential Geometry; Mathematics - Differential Geometry; Mathematics - Analysis of PDEs; Mathematics - Group Theory; Mathematics - Metric Geometry; Mathematics - Optimization and Control; 53C17 49K30 17B7049K30
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Studies on DNA interaction of organotin(IV) complexes of meso-tetra(4-sulfonatophenyl)porphine that show cellular activity.

2016

PubMedID: 27393277 The interaction of the diorgano- and triorganotin(IV) derivatives of meso-tetra-(4-sulfonatophenyl)porphine (Me2Sn)2TPPS, (Bu2Sn)2TPPS, (Me3Sn)4TPPS and (Bu3Sn)4TPPS to natural DNA was analysed (together with free meso-tetra-(4-sulfonatophenyl)porphine (TPPS4 -) for comparison purposes). Particular attention was paid to (Bu3Sn)4TPPS, a species that shows significant cellular action. Preliminary tests were done on the solution properties of the organotin(IV) compounds (pKA and possible self-aggregation). Spectrophotometric and spectrofluorometric experiments showed that all the investigated organotin(IV) derivatives strongly interact with DNA, the binding energy depending …

Steric effectsCellular activityOrganometallic compounds External binding Negative porphyrins Aggregation ViscosityNegative porphyrinsPorphyrinsStereochemistryBinding energyDna interactionOrganometallic compounds010402 general chemistry01 natural sciencesMedicinal chemistryBiochemistryInorganic Chemistrychemistry.chemical_compoundAggregationmetal complexequilibrium constantDNA conformation changescomplex formationOrganotin CompoundsHumansDNA bindingEquilibrium constantGroup 2 organometallic chemistrybiology010405 organic chemistryViscosityDNAbiology.organism_classificationExternal binding0104 chemical sciencesAggregation External binding Negative porphyrins Organometallic compounds Viscosity Biochemistry Inorganic Chemistry metal complex equilibrium constant DNA conformation changes DNA binding complex formationchemistrySettore CHIM/03 - Chimica Generale E InorganicaA549 CellsTetraNucleic Acid ConformationDNAJournal of inorganic biochemistry
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Subdifferential and conjugate calculus of integral functions with and without qualification conditions

2023

We characterize the subdifferential and the Fenchel conjugate of convex integral functions by means of respectively the approximate subdifferential and the conjugate of the associated convex normal integrands. The results are stated in Suslin locally convex spaces, and do not require continuity-type qualification conditions on the functions, nor special topological or algebraic structures on the index set. Consequently, when confined to separable Banach spaces, the characterizations of such a subdifferential are obtained using only the exact subdifferential of the given integrand but at nearby points. We also provide some simplifications of our formulas when additional continuity conditions…

Subdifferentialsconvex normal integrandsConvex normal integrandsSuslin spacessub-differentialsSuslin spaces. Mathematics Subject Classi…cation (2010): 26B0526J25[MATH.MATH-OC] Mathematics [math]/Optimization and Control [math.OC]49H05Integral functions and functionals
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