Search results for "505"
showing 10 items of 574 documents
Hexakis(diethylacetamide)iron(II) hexahalorhenate(IV) ionic salts: X-ray structures and magnetic properties
2015
Two novel Fe<sup>II</sup>-Re<sup>IV</sup> compounds of general formula [Fe<sup>II</sup>(DEA)<inf>6</inf>][Re<sup>IV</sup>X<inf>6</inf>] where DEA = diethylacetamide and X = Cl (1) and Br (2) have been prepared and magnetostructurally characterised. Complexes 1 and 2 are isomorphic ionic salts that crystallise in the trigonal crystal system with space group R(-3). The rhenium(IV) ion in 1 and 2 is six-coordinate with six chloro (1) or bromo (2) ligands building a regular octahedral chromophore. The Fe<sup>II</sup> ion is also six-coordinate, and bonded to six oxygen atoms from six DEA molecules. [Fe<sup>…
HF radar for wind waves measurements in the Malta-Sicily Channel
2018
Abstract The CALYPSO HF radar network is a permanent and fully operational observing system currently composed of four CODAR SeaSonde stations. The system is providing real-time hourly maps of sea surface currents and waves data in the Malta-Sicily Channel. The present work aims to compare significant wave height measurements by HF Radar to wave data from numerical models and satellite altimeter. This is the first time that this set of wave data are analysed since the four HF radars were installed between 2012 and 2015. Results suggest that CODAR HF Radar wave data are a reliable source of wave information even in the case of extreme events, providing an avenue to improve and complete the o…
The UKC3 regional coupled environmental prediction system
2019
Abstract. This paper describes an updated configuration of the regional coupled research system, termed UKC3, developed and evaluated under the UK Environmental Prediction collaboration. This represents a further step towards a vision of simulating the numerous interactions and feedbacks between different physical and biogeochemical components of the environment across sky, sea and land using more integrated regional coupled prediction systems at km-scale resolution. The UKC3 coupled system incorporates models of the atmosphere (Met Office Unified Model), land surface with river routing (JULES), shelf-sea ocean (NEMO) and ocean surface waves (WAVEWATCH III), coupled together using OASIS3-MC…
The making of the New European Wind Atlas - Part 1: Model sensitivity
2020
This is the first of two papers that document the creation of the New European Wind Atlas (NEWA). It describes the sensitivity analysis and evaluation procedures that formed the basis for choosing the final setup of the mesoscale model simulations of the wind atlas. The suitable combination of model setup and parameterizations, bound by practical constraints, was found for simulating the climatology of the wind field at turbine-relevant heights with the Weather Research and Forecasting (WRF) model. Initial WRF model sensitivity experiments compared the wind climate generated by using two commonly used planetary boundary layer schemes and were carried out over several regions in Europe. They…
A Geometry-Based Underwater Acoustic Channel Model Allowing for Sloped Ocean Bottom Conditions
2017
This paper proposes a new geometry-based channel model for shallow-water ocean environments, in which the ocean bottom can slope gently down/up. The need for developing such an underwater acoustic (UWA) channel model is driven by the fact that the standard assumption of a flat ocean bottom does not hold in many realistic scenarios. Starting from a geometrical model, we develop a stochastic channel model for wideband single-input single-output vehicle-to-vehicle UWA channels using the ray theory assuming smooth ocean surface and bottom. We investigate the effect of the ocean-bottom slope angle on the distribution of the channel envelope, instantaneous channel capacity, temporal autocorrelati…
A Nonisovelocity Geometry-Based Underwater Acoustic Channel Model
2018
This paper proposes a new geometry-based shallow underwater acoustic (UWA) channel model allowing for nonisovelocity ocean conditions. The fact that the isovelocity assumption does not hold in many real-world scenarios motivates the need for developing channel models for nonisovelocity UWA propagation environments. Starting from a geometrical model, we develop a stochastic channel model for a single-input single-output (SISO) vehicle-to-vehicle UWA channel assuming that the ocean surface and bottom are rough and that the speed of sound varies with depth. The effect of the nonisovelocity condition has been assessed regarding its influence on the temporal autocorrelation function, the frequen…
Performance analysis of Alamouti-coded OFDM systems over spatio-temporally correlated underwater acoustic channels
2017
In this paper, we analyze the performance of Alamouti-coded orthogonal frequency division multiplexing (OFDM) systems over time-varying underwater acoustic (UWA) channels. A realistic UWA channel model has been considered, which can be correlated in either time or space or simultaneously in both domains. An exact analytical expression for the bit error probability (BEP) is necessary to analyze accurately the performance of Alamouti-coded OFDM systems over the spatio-temporally correlated UWA channel model. Hence, by using this UWA channel model, an expression has been derived for the BEP of Alamouti-coded OFDM systems assuming that the receiver knows perfectly the channel state information.…
Antioxidant Phenolic Compounds in Salvia officinalis L. and Salvia sclarea L.
2018
Abstract The differences in the chemical composition of the phenolic compounds of Salvia officinalis versus Salvia sclarea growing in different habitats, were studied. First, the optimal solvent - methanol - for ultrasonic extraction of phenolic compounds from these plants was chosen experimentally. Total phenolic content and 1,1-diphenyl-2-picrylhydrazyl (DPPH) assays were determined spectrophotometrically. Total phenolic content was in the range of 63.9 to 134.4 mg GAE/g of plant depending on the studied species. The highest antiradical activity was displayed by the methanol fractions of S. sclarea varieties (83 and 67%). HPLC-DAD analysis of extracts was done in order to identify the pre…
Co-Designing Social Simulation Models For Policy Advise: Lessons Learned From the INFSO-SKIN Study
2019
This paper describes a participatory approach to co-designing social simulation models with policymakers using a case study of modeling European Commission policy. Managing the collaboration of a wide range of individuals or organizations is challenging but increasingly important as policy making becomes more complex. A framework for a co-design process based on a participatory approach is proposed. The framework suggests that the collaborative design should go through the following phases: Identifying user questions, data provision, model discussion for validation, visualization of results and discussing scope and limitations with stakeholders. Key findings are that the co-design process r…
Studying illegal online trades in plants: market characteristics, organisational and behavioural aspects, and policing challenges
2020
AbstractIllegal commerce in plants and their derivatives threatens and destroys numerous species and important natural resources, and may cause phytosanitary and health problems. This illegal trade, which has been boosted by the commercialisation of the Internet, has been relatively overlooked in criminological research. Furthermore, the policing of illegal plant markets remains limited and poorly resourced, with law enforcement agencies lacking awareness and technical capacity in investigation and prosecution services. Based on semi-structured interviews with law enforcement officers and other relevant experts, this study, developed in the context of the ESRC-funded project “FloraGuard: Ta…