Search results for "ADD"

Water in stereoselective organocatalytic reactions

2009

In this review, recent advances in asymmetric organocatalytic reactions carried out with variable amounts of water, from substoichiometric to a large excess (reaction medium), are discussed. We also summarize several proposed mechanisms for the different possibilities of the action of water both in the increased activity of the catalyst and in the asymmetric induction. Finally, the application of this catalytic methodology to the enantioselective synthesis of valuable compounds through enamine or iminium catalysis is presented.

Ortho -Functionalized Aryltetrazines by Direct Palladium-Catalyzed C−H Halogenation: Application to Fast Electrophilic Fluorination Reactions

2016

International audience; A general catalyzed direct C-H functionalization of s-tetrazines is reported. Under mild reaction conditions, N-directed ortho-C-H activation of tetrazines allows the introduction of various functional groups, thus forming carbon-heteroatom bonds: C-X (X=I, Br, Cl) and C-O. Based on this methodology, we developed electrophilic mono- and poly-ortho-fluorination of tetrazines. Microwave irradiation was optimized to afford fluorinated s-aryltetrazines, with satisfactory selectivity, within only ten minutes. This work provides an efficient and practical entry for further accessing highly substituted tetrazine derivatives (iodo, bromo, chloro, fluoro, and acetate precurso…

High Entropy Alloys for Energy Conversion and Storage: A Review of Grain Boundary Wetting Phenomena

2022

This research was funded by the Russian Ministry of Science and Higher Education (contract no. 075-15-2021-945 grant no. 13.2251.21.0013). Support from the University of the Basque Country (project GIU19/019) and from the Basque Government (project IT1714-22) is also acknowledged.

Differential effects of workaholism and work engagement on the interference between life and work domains

2018

This study analyzed the differences between workaholism and work engagement in relation to their influence on work–life interference. Workaholism is an addiction to work, characterized by obsessive attitude towards job, whereas work engagement concerns a positive pattern of thoughts and feelings about one’s job; these two constructs thus represent pathological and healthy forms of heavy work investment, respectively. As a consequence, it was expected that workaholism and work engagement would have different effects on perceived interference between work and life domains. We assessed levels of workaholism, work engagement, work-to-life interference, and life-to-work interference in a sample …

XPS structural data and correlation with Mossbauer spectra for Tin-organic compounds: adducts of RnSnCl4-n with 1,2-bis(diphenylphosphino)ethane

1982

Abstract Core level X-ray photoelectron spectra of 1:1 adducts of SnCl4 and RSnCl3 with DPE {[RnSnCl4−n} · DPE (n = 1, R = Me, Bun, Octn, Phn; n = 2, R = Ph; DPE = 1,2-bis(diphenylphosphino)ethane], have been measured in solid phase. The Sn3d 5 2 binding energies, corrected for the Madelung potential at the metal atom, are well correlated with both partial atomic charge on tin, accounting for relaxation upon ionization, and 119Sn Mossbauer isomer shifts. The results are discussed in terms of these molecular parameters.

Puuttuvuuden mallintaminen FINRISKI-tutkimuksessa

2017

Puuttuva tieto on ongelma terveystutkimuksissa, koska tutkimukseen osallistujat ja ei-osallistujat usein eroavat toisistaan. Puuttuvuuden mallintaminen on tärkeää, jotta tuloksia pystyttäisiin korjaamaan ja jatkossa ottamaan mallinnettu puuttuvuus paremmin huomioon tutkimusta suunnitellessa. Myös Kansallinen FINRISKI-tutkimus kärsii puuttuvuudesta, sillä tutkimuksen osallistumisprosentti on laskenut jatkuvasti. Tutkimus on Terveyden ja hyvinvoinnin laitoksen väestötutkimussarja, jonka tavoitteena on seurata kansantauteja ja niiden riskitekijöitä Suomessa sekä tarkkailla suomalaisten terveydentilaa. Tässä työssä pyritään mallintamaan Kansallisen FINRISKI-tutkimuksen puuttuvuus tarkastelemall…

Bladder tumours in children: An interesting case report of TCC with a partial inverted growth pattern.

2014

Bladder urothelial carcinoma is typically a disease of older individuals and rarely occurs below the age of 40 years. There is debate and uncertainty in the literature regarding the clinicopathologic and prognostic characteristics of bladder urothelial neoplasms in younger patients compared with older patients, although no consistent age criteria have been used to define "younger" age group categories. We report on a 16 years old girl with transitional cell carcinoma of the bladder with a partial inverted growth pattern who presented with gross hematuria. Ultrasonography revealed a papillary lesion in the bladder; cystoscopic evaluation showed a 15 mm papillary lesion with a thick stalk loc…

Verzeichnis d. Rigaer-Aerzte

1931

Book reviews: P. Cheyne, A. Hamilton, M. Paddison (eds.). Philosophy of Rhythm: Aesthetics, Music, Poetics. New York: Oxford University Press, 2019

2021

Autobiographical texts written by learners of Catalan as an Additional Language: From formative needs to reflection in the teaching of narrative genr…

2022

In this article we analyse autobiographical narrative texts written by university students studying Catalan as an Additional Language at a CEFR (2020) B1 level. The goal is to analyse the formative needs related to the writing of this genre in order to foster metadiscursive reflection in the classroom that will allow students to improve their written output. To this end, we analyzed a corpus of 39 autobiographies at both the macrotextual level (i.e., rhetorical moves) and the microtextual level (i.e., deictic elements which channel the narrative’s organization). Our results show that the problems that these texts present for students are related to awareness of the elements that define the …