6533b83afe1ef96bd12a7c35

RESEARCH PRODUCT

XPS structural data and correlation with Mossbauer spectra for Tin-organic compounds: adducts of RnSnCl4-n with 1,2-bis(diphenylphosphino)ethane

Claudio FurlaniP. MauersbergerArturo SilvestriGiovanni PolzonettiEleonora RivarolaG. Mattogno

subject

xpBinding energyAnalytical chemistrychemistry.chemical_elementAdductInorganic ChemistryMossbauerchemistry.chemical_compound12-Bis(diphenylphosphino)ethanechemistryX-ray photoelectron spectroscopyIonizationcorrelationAtomMössbauer spectroscopyMaterials ChemistryPhysical chemistryPhysical and Theoretical ChemistryTin

description

Abstract Core level X-ray photoelectron spectra of 1:1 adducts of SnCl4 and RSnCl3 with DPE {[RnSnCl4−n} · DPE (n = 1, R = Me, Bun, Octn, Phn; n = 2, R = Ph; DPE = 1,2-bis(diphenylphosphino)ethane], have been measured in solid phase. The Sn3d 5 2 binding energies, corrected for the Madelung potential at the metal atom, are well correlated with both partial atomic charge on tin, accounting for relaxation upon ionization, and 119Sn Mossbauer isomer shifts. The results are discussed in terms of these molecular parameters.

yearjournalcountryeditionlanguage
1982-01-01
https://hdl.handle.net/11590/123026