Search results for "AOT"
showing 10 items of 347 documents
Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to γ-Cyclodextrin
2015
Dodecaborate anions of the type B12X12(2-) and B12X11Y(2-) (X=H, Cl, Br, I and Y=OH, SH, NH3(+), NR3(+)) form strong (K(a) up to 10(6) L mol(-1), for B12Br12(2-)) inclusion complexes with γ-cyclodextrin (γ-CD). The micromolar affinities reached are the highest known for this native CD. The complexation exhibits highly negative enthalpies (up to -25 kcal mol(-1)) and entropies (TΔS up to -18.4 kcal mol(-1), both for B12I12(2-)), which position these guests at the bottom end of the well-known enthalpy-entropy correlation for CDs. The high driving force can be traced back to a chaotropic effect, according to which chaotropic anions have an intrinsic affinity to hydrophobic cavities in aqueous …
Almost Planar Homoclinic Loops in R3
1996
AbstractIn this paper we study homoclinic loops of vector fields in 3-dimensional space when the two principal eigenvalues are real of opposite sign, which we call almost planar. We are interested to have a theory for higher codimension bifurcations. Almost planar homoclinic loop bifurcations generically occur in two versions “non-twisted” and “twisted” loops. We consider high codimension homoclinic loop bifurcations under generic conditions. The generic condition forces the existence of a 2-dimensional topological invariant ring (non necessarily unique), which is a topological cylinder in the “non-twisted” case and a topological Möbius band in the “twisted” case. If the third eigenvalue is…
Porosities and dimensions of measures
1999
We introduce a concept of porosity for measures and study relations between dimensions and porosities for two classes of measures: measures on $R^n$ which satisfy the doubling condition and strongly porous measures on $R$.
On the number of solutions of a Duffing equation
1991
The exact number of solutions of a Duffing equation with small forcing term and homogeneous Neumann boundary conditions is given. Several bifurcation diagrams are shown.
A Hardware and Secure Pseudorandom Generator for Constrained Devices
2018
Hardware security for an Internet of Things or cyber physical system drives the need for ubiquitous cryptography to different sensing infrastructures in these fields. In particular, generating strong cryptographic keys on such resource-constrained device depends on a lightweight and cryptographically secure random number generator. In this research work, we have introduced a new hardware chaos-based pseudorandom number generator, which is mainly based on the deletion of an Hamilton cycle within the $N$ -cube (or on the vectorial negation), plus one single permutation. We have rigorously proven the chaotic behavior and cryptographically secure property of the whole proposal: the mid-term eff…
A new method for optimal synthesis of wavelet-based neural networks suitable for identification purposes
1999
Abstract This paper deals with a new method for optimal synthesis of Wavelet-Based Neural Networks (WBNN) suitable for identification purposes. The method uses a genetic algorithm (GA) combined with a steepest descent technique and least square techniques for both optimal selection of the structure of the WBNN and its training. The method is applied for designing a predictor for a chaotic temporal series
Estimation of Granger causality through Artificial Neural Networks: applications to physiological systems and chaotic electronic oscillators
2021
One of the most challenging problems in the study of complex dynamical systems is to find the statistical interdependencies among the system components. Granger causality (GC) represents one of the most employed approaches, based on modeling the system dynamics with a linear vector autoregressive (VAR) model and on evaluating the information flow between two processes in terms of prediction error variances. In its most advanced setting, GC analysis is performed through a state-space (SS) representation of the VAR model that allows to compute both conditional and unconditional forms of GC by solving only one regression problem. While this problem is typically solved through Ordinary Least Sq…
“Beyond Weather Regimes”: Descriptors Monitoring Atmospheric Centers of Action. A case study for Aotearoa New Zealand
2021
AbstractThis paper introduces a set of descriptors applied to weather regimes, that allow for a detailed monitoring of the location and intensity of their atmospheric centers of action (e.g. troughs and ridges) and the gradients between them, when applicable. Descriptors are designed to document the effect of climate variability and change in modulating the character of daily weather regimes, rather than merely their occurrence statistics.As a case study, the methodology is applied to Aotearoa New Zealand (ANZ), using ERA5 ensemble reanalysis data for the period 1979-2019. Here, we analyze teleconnections between the regimes and their descriptors, and large-scale climate variability. Result…
Role of the reagents consumption in the chaotic dynamics of the Belousov-Zhabotitinsky oscillator in closed unstirred reactors
2010
Chemical oscillations generated by the Belousov–Zhabotinsky reaction in batch unstirred reactors, show a characteristic chaotic transient in their dynamical regime, which is generally found between two periodic regions. Chemical chaos starts and finishes by following a direct and an inverse Ruelle–Takens–Newhouse scenario, respectively. In previous works we showed, both experimentally and theoretically, that the complex oscillations are generated by the coupling among the nonlinear kinetics and the transport phenomena, the latter due to concentration and density gradients. In particular, convection was found to play a fundamental role. In this paper, we develop a reaction–diffusion–convecti…