Search results for "ASTER"
showing 10 items of 2223 documents
Oxygen-assisted hydroxymatairesinol dehydrogenation: a selective secondary-alcohol oxidation over a gold catalyst.
2013
Selective dehydrogenation of the biomass-derived lignan hydroxymatairesinol (HMR) to oxomatairesinol (oxoMAT) was studied over an Au/Al(2)O(3) catalyst. The reaction was carried out in a semi-batch glass reactor at 343 K under two different gas atmospheres, namely produced through synthetic air or nitrogen. The studied reaction is, in fact, an example of secondary-alcohol oxidation over an Au catalyst. Thus, the investigated reaction mechanism of HMR oxidative dehydrogenation is useful for the fundamental understanding of other secondary-alcohol dehydrogenation over Au surfaces. To investigate the elementary catalytic steps ruling both oxygen-free- and oxygen-assisted dehydrogenation of HMR…
Calculation of the rate constants for hydrogen abstraction reactions by Hydroperoxyl radical from Methanol, and the investigation of stability of CH3…
2020
Abstract Master equation (ME) with Lennard-Jones potential utilized to simulate the collision between CH3OH and HO2 radical in the presence of bath gas. The reaction mechanism explored through the lowest doublet potential energy surface at CCSD(T)/aug-cc-pVTZ//B3LYP/aug-cc-pVTZ level of theory that is barrierless and forms shallow energized intermediate at the entrance channel. The investigation of the fractional population showed that lifetime of CH3OH.HO2 intermediate (INT*) is fairly short due to its shallow depth, and at the low temperature, most reaction takes place by re-dissociation back to reactants and also when the pressure is high enough, the INT* is thermalized and comes into eq…
Synthesis of optically pure alkynols
1993
Abstract (R,S)-1-alkylprop-2-yn-1-ols have been separated by a 2-step procedure, esterification with N-p-tosyl-(L)-phenylalanine (or valine), recrystallisation of the diastereomeric esters from ethanol/hexane and saponification of the optically pure esters.
In developing Drosophila neurones the production of γ-amino butyric acid is tightly regulated downstream of glutamate decarboxylase translation and c…
2003
The presented work pioneers the embryonic Drosophila CNS for studies of the developmental regulation and function of gamma-amino butyric acid (GABA). We describe for the first time the developmental pattern of GABA in Drosophila and address underlying regulatory mechanisms. Surprisingly, and in contrast to vertebrates, detectable levels of GABA occur late during Drosophila neurogenesis, after essential neuronal proliferation and growth have taken place and synaptogenesis has been initiated. This timeline is almost unchanged when the GABA synthetase glutamate decarboxylase (GAD) is strongly misexpressed throughout the nervous system suggesting a tight post-translational regulation of GABA ex…
Insurance mechanisms for tropical cyclones and droughts in Pacific Small Island Developing States
2016
One group of locations significantly affected by climate-related losses and damage is the Small Island Developing States (SIDS). One mechanism aiming to reduce such adverse impacts is insurance, with a wide variety of products and models available. Insurance for climate-related hazards affecting Pacific SIDS has not been investigated in detail. This article contributes to filling this gap by exploring how insurance mechanisms might be implemented in the Pacific SIDS for tropical cyclones and droughts. The study examines opportunities and constraints or limitations of some existing insurance mechanisms and programmes as applied to the Pacific SIDS. Eight insurance mechanisms are compared and…
Mapping and structure of DMXL1, a human homologue of the DmX gene from Drosophila melanogaster coding for a WD repeat protein.
2000
The DmX gene was recently isolated from the X chromosome of Drosophila melanogaster. TBLASTN searches of the dbEST databases revealed sequences with a high level of similarity to DmX in a variety of different species, including insects, nematodes, and mammals showing that DmX is an evolutionarily highly conserved gene. Here we describe the cloning of the cDNA and the chromosomal localization of one of the human homologues of DmX, Dmx-like 1 (DMXL1). The human DMXL1 gene codes for a large mRNA of 11 kb with an open reading frame of 3027 amino acids. The putative protein belongs to the superfamily of WD repeat proteins, which have mostly regulatory functions. The DMXL1 protein contains an exc…
Research in disaster settings: a systematic qualitative review of ethical guidelines
2016
Background Conducting research during or in the aftermath of disasters poses many specific practical and ethical challenges. This is particularly the case with research involving human subjects. The extraordinary circumstances of research conducted in disaster settings require appropriate regulations to ensure the protection of human participants. The goal of this study is to systematically and qualitatively review the existing ethical guidelines for disaster research by using the constant comparative method (CCM). Methods We performed a systematic qualitative review of disaster research ethics guidelines to collect and compare existing regulations. Guidelines were identified by a three-tie…
Finte Pietre. Architettura dell'apparire e conservazione dei valori culturali
2012
Il volume presenta gli esiti di una ricerca incentrata sulla conoscenza delle finiture architettoniche di pietra artificiale, con particolare attenzione agli intonaci brevettati nel 1901 dai fratelli Li Vigni. Le attività di studio sono condotte attraverso la ricognizione dei documenti conservati presso l’Archivio Centrale dello Stato a Roma, e compiono una rigorosa selezione e analisi dei brevetti con l’obiettivo di tracciare il percorso evolutivo dei metodi d’intonacatura ed evidenziare i legami che s’instaurano tra le ricerche in corso nei diversi paesi. Nel XIX secolo i ricercatori di molte nazionalità avviano una selezione critica delle ricette tramandate dal passato e perfezionano pro…
THE ROLE OF THERMOGRAPHY IN THE NON-DESTRUCTIVE EVALUATION OF HISTORICAL ARCHITECTURAL SURFACES. Some observation about the method and its purpose
2014
Infrared-Thermography (IRT) has become a supporting tool for the investigation of historical structures and facades. Using the non-destructive testing method for the detection can give a profound knowledge about the current status of the object and the state of decay, about different kinds of discontinuities at historical facades, of construction details and of thermal bridges in the facades. Different case studies of thermographic surveys on some Sicilian monuments are presented and discussed to illustrate how the method can offer applicable information about the investigated objects and demonstrate its reasonable integration into conservation projects.
Indagine termografica del prospetto di palazzo Di Lorenzo a Palermo
2010
La relazione riporta gli esiti di una indagine termografica svolta sulle superfici esterne del palazzo DiLorenzo a Palermo, su incarico di committenti privati che hanno la tutela del bene architettonico. L'indagine diagnostica è finalizzata ad individuare i distacchi dell'intonaco LiVigni con lavorazione superfociale a "finta pietra", in vista del conseguente intervento di restauro. The report contains the results of a thermographic survey carried out on the external surfaces of the Di Lorenzo palace in Palermo, on behalf of private clients who have the protection of the architectural heritage. The diagnostic analysis is aimed at identifying the detachment of Li Vigni artificial stone plast…