Search results for "ASYM"
showing 10 items of 2151 documents
The kinematics of water masers in the stellar molecular outflow source, IRAS 19134+2131
2004
Using the Very Large Array (VLA) and the Very Long Baseline Array (VLBA), we have observed water maser emission in the proto-planetary nebula candidate IRAS 19134+2131, in which the water maser spectrum has two groups of emission features separated in radial velocity by ∼100 km s^−1. The blue-shifted and red-shifted clusters of maser features are clearly separated spatially by ∼150 mas, indicative of a fast collimated flow. However, not all of the maser features are aligned along the axis of the flow, as is seen in the similar high-velocity water maser source, W43A. Comparing the VLA and VLBA maps of the water maser source, we find 4 maser features that were active for 2 years. Using only V…
Mössbauer study of the solid state configuration of triorganotin derivatives with intramolecular coordination
1980
Triorganotin bromides with intramolecular nitrogen-to-tin coordination (I-VIII, Fig. 1) have been structurally investigated by Mossbauer and infrared spectroscopy. Mossbauer-Zeeman spectra have been measured for I and VIII in order to obtain the sign of the nuclear quadrupole splitting ΔE and the value of the asymmetry parameter η. Point-charge model values of ΔE and η have been calculated for environments of tin atoms in I-VIII which are plausible in view of the results of previous investigations. From trends of experimental ΔE in the series, and from the agreement between experimental and calculated Mossbauer parameters it is concluded that the compounds I-VIII all have trigonal bipyramid…
Allylpalladium( II ) Complexes with Aminophosphane Ligands: Solution Behaviour and X‐ray Structure of cis ‐[Pd(η 3 ‐CH 2 CHCHPh){Ph 2 PCH 2 CHPhNH(2,…
2004
A new β-aminophosphane L2 [Ph2PCH2CH(Ph)NH(2,6-C6H3iPr2)], bearing an asymmetric carbon atom and a vicinal prochiral nitrogen centre and (η3-allyl)palladium complexes of general formula [Pd(η3-C3H4R){η2-Ph2PCH2CH(Ph)NHAr}][PF6] (1−6) (R = H, Me or Ph and Ar = Ph or 2,6-C6H3iPr2) have been synthesised. NMR spectroscopic studies and a crystal structure analysis of complex 6 (R = Ph, Ar = 2,6-C6H3iPr2) confirmed the highly diastereoselective coordination of the nitrogen atom. Because of the allyl fluxionality and the presence of asymmetric centres, all the complexes exist in solution as mixtures of up to four diastereomers. For the monosubstituted allyl complexes [Pd(η3-C3H4R){Ph2PCH2CH(Ph)NHA…
Modular P-Chirogenic Aminophosphane-Phosphinite Ligands for Rh-Catalyzed Asymmetric Hydrogenation: A New Model for Prediction of Enantioselectivity
2007
An original series of P-chirogenic aminophosphane-phosphinite (AMPP) ligands has been synthesized from (+)- or(–)-ephedrine in 23 to 61 % overall yields by a versatile three-step methodology. The AMPP ligands, bearing either one or two P-chirogenic centers, were used in the form of rhodium complexes for the catalyzed hydrogenation of α-acetamidocinnamate as a test reaction. Notably, even with AMPP ligands all derived from (+)-ephedrine, variation of the substituent on a P-center allowed the phenylalanine derivatives to be obtained in either (S) or (R) absolute configurations, with ee values ranging from 99 % (S) to 88 % (R). The asymmetric induction was analyzed with the aid of X-ray struct…
"Table 2" of "Flavour Separation of Helicity Distributions from Deep Inelastic Muon-Deuteron Scattering"
2010
Charged pion and kaon semi-inclusive asymmetries as functions of X.
Flavour Separation of Helicity Distributions from Deep Inelastic Muon-Deuteron Scattering
2009
We present a LO evaluation of helicity densities of valence, \Delta u_v+\Delta d_v, non-strange sea, \Delta\bar{u}+\Delta\bar{d}, and strange quarks, \Delta s (assumed to be equal to \Delta\bar{s}). They have been obtained from the inclusive asymmetry A_{3,d} and the semi-inclusive asymmetries A^{\pi+}_{1,d}, A^{\pi-}_{1,d}, A^{K+}_{1,d}, A^{K-}_{1,d} measured in polarised deep inelastic muon-deuteron scattering. The full deuteron statistics of COMPASS (years 2002-2004 and 2006) has been used. The data cover the range Q^2 > 1 (GeV/c)^2 and 0.004<x<0.3. Both non-strange densities are found to be in a good agreement with previous measurements. The distribution of \Delta s(x) is compatible wit…
FIRST MEASUREMENT OF THE STRANGE QUARK ASYMMETRY AT THE Z(0) PEAK
1995
A measurement of the strange quark forward-backward asymmetry at the Z0 peak was performed using 718,000 multihadronic Z0 decays collected by the DELPHI detector at LEP in 1992. The s-quark was tagged by the presence of high momentum charged kaons identified by the Ring Imaging Cherenkov detector and by Λ0;s decaying into pπ-. The s-quark purity obtained was estimated for the two hadrons to be 43%. The average s-quark asymmetry was found to be 0.131±0.035 (stat.) ±0.013 (syst.). The forward-backward asymmetry was measured for unresolved d-and s-quarks, tagged by the detection of a high energy neutron or neutral kaon in the Hadron Calorimeter. The combined d-and s-quark purity was 69% and th…
Bundlet Model of Single- Wall Carbon, BC2N and BN Nanotubes, Cones and Horns in Organic Solvents
2013
Bundlet Model of Single- Wall Carbon, BC2N and BN Nanotubes, Cones and Horns in Organic Solvents The existence of Single-wall C-nanocones (SWNCs), especially nanohorns (SWNHs) and BC2N/Boron Nitride (BN) analogues is discussed in organic solvents in cluster form. A theory is developed based on the bundlet model, describing distribution function by size. The phenomena present unified explanation in the model, in which free energy of (BC2N/BN )SWNCs involved in cluster, is combined from two components: volume one proportional to the number of molecules n in cluster and surface one, to n1/2. The model enables describing distribution function of (BC2N/BN )SWNC clusters by size. From geometrical…
Four solutions for fractional p-Laplacian equations with asymmetric reactions
2020
We consider a Dirichlet type problem for a nonlinear, nonlocal equation driven by the degenerate fractional p-Laplacian, whose reaction combines a sublinear term depending on a positive parameter and an asymmetric perturbation (superlinear at positive infinity, at most linear at negative infinity). By means of critical point theory and Morse theory, we prove that, for small enough values of the parameter, such problem admits at least four nontrivial solutions: two positive, one negative, and one nodal. As a tool, we prove a Brezis-Oswald type comparison result.
N1-Functionalized Indole-Phosphane Oxazoline (IndPHOX) Ligands in Asymmetric Allylic Substitution Reactions
2012
N-Functionalized IndPHOX ligands bearing various groups have been synthesized and the effects of the N1-substituent on the reaction rate, yield, and asymmetric induction in a palladium-catalyzed allylic substitution reaction are reported. The presence of an oxygen atom in the ligands, namely an N-MOM or N-THP group, led to enhancement of the enantioselectivity in the allylic amination reaction. In addition, a ligand with a chiral oxazoline ring at C-1 and a phosphane substituent at C-2 provided high enantioselectivity in good yield in an asymmetric allylic alkylation reaction.