Search results for "ATMOSPHERE"
showing 10 items of 673 documents
Emission of bromine and iodine from Mount Etna volcano
2005
[1] Constraining fluxes of volcanic bromine and iodine to the atmosphere is important given the significant role these species play in ozone depletion. However, very few such measurements have been made hitherto, such that global volcanic fluxes are poorly constrained. Here we extend the data set of volcanic Br and I degassing by reporting the first measurements of bromine and iodine emissions from Mount Etna. These data were obtained using filter packs and contemporaneous ultraviolet spectroscopic SO2 flux measurements, resulting in time-averaged emission rates of 0.7 kt yr−1 and 0.01 kt yr−1 for Br and I, respectively, from April to October 2004, from which we estimate global Br and I flu…
BrO formation in volcanic plumes
2006
Volcanoes have only recently been recognized as a potentially major source of reactive bromine species to the atmosphere, following from the detection of bromine monoxide (BrO) in the plume emitted by Soufriere Hills Volcano, Montserrat. However, BrO is not expected to be emitted in significant quantity from magma, presenting a puzzle regarding its formation. We report here new field measurements of the tropospheric plume emitted by Mt. Etna, Italy, which provide the first direct evidence of fast oxidation of halogen species in a volcanic plume, and lead to an explanation of how BrO is generated from magmatic HBr emissions. We show that the timescale of BrO formation (a few minutes after em…
Focused and diffuse effluxes of CO2 from mud volcanoes and mofettes south of Mt. Etna (Italy).
2007
Abstract Several sites with anomalous emissions of carbon dioxide were investigated in the region south of Mt. Etna volcano in order to assess the types of emission (focused and/or diffuse), their surface extension and the total output of CO 2 . Most of the studied emissions are located on the southwest boundary of Mt. Etna, near the town of Paterno. They consist of three mud volcanoes (known as Salinelle), one spring with bubbling gas (Acqua Grassa) and one area of diffuse degassing (Pescheria). Another site (Naftia Lake) with remarkable gas emissions (bubbling gas into a lake as well as adjacent areas of diffuse soil degassing) is located further southwest of Mt. Etna in an area of extinc…
Ozone depletion in tropospheric volcanic plumes
2010
Ground based remote sensing techniques are used to measure volcanic SO2 fluxes in efforts to characterise volcanic activity. As these measurements are made several km from source there is the potential for in-plume chemical transformation of SO2 to sulphate aerosol (conversion rates are dependent on meteorological conditions), complicating interpretation of observed SO2 flux trends. In contrast to anthropogenic plumes, SO2 lifetimes are poorly constrained for tropospheric volcanic plumes, where the few previous loss rate estimates vary widely (from 99% per hour). We report experiments conducted on the boundary layer plume of Masaya volcano, Nicaragua during the dry season. We found that SO2…
Towards a representation of halogen chemistry within volcanic plumes in a chemistry transport model
2014
Volcanoes are a known source of halogens to the atmosphere. HBr volcanic emissions lead rapidly to the formation of BrO within volcanic plumes as shown by recent work based on observations and models. BrO, having a longer residence time in the atmosphere than HBr, is expected to have a significant impact on tropospheric chemistry, at least at the local and regional scales. The objective of this paper is to prepare a framework that will allow 3-D modelling of volcanic halogen emissions in order to determine their fate within the volcanic plume and then in the atmosphere at the regional and global scales. This work is based on a 1-D configuration of the chemistry transport model MOCAGE whose …
Rapid oxidation of mercury (Hg) at volcanic vents: Insights from high temperature thermodynamic models of Mt Etna's emissions
2011
A major uncertainty regarding the environmental impacts of volcanic Hg is the extent to which Hg is deposited locally or transported globally. An important control on dispersion and deposition is the oxidation state of Hg compounds: Hg(0) is an inert, insoluble gas, while Hg(II) occurs as reactive gases or in particles, which deposit rapidly and proximally, near the volcanic vent. Using a new high temperature thermodynamic model, we show that although Hg in Etna's magmatic gases is almost entirely Hg(0) (i.e., gaseous elemental mercury), significant quantities of Hg(II) are likely formed at Etna's vents as gaseous HgCl2, when magmatic gases are cooled and oxidised by atmospheric gases. Thes…
Volcanic CO2 flux measurement at Campi Flegrei by tunable diode laser absorption spectroscopy
2014
Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross-sections of the atmospheric…
Signals and memory in tree-ring width and density data
2015
It has been suggested that maximum latewood density (MXD) should be used instead of tree-ring width (TRW) data to reconstruct post-volcanic cooling effects. A thorough assessment of high frequency signals and potentially differing memory effects in long MXD and TRW chronologies, in response to large volcanic eruptions, is still missing, however. We here present a compilation of MXD and TRW chronologies from 11 sites in the Northern Hemisphere, covering the past 750+ years, and containing significant June–August temperature signals. Basic assessment of the data using Superposed Epoch Analysis reveals a temporally extended response in TRW, by 2–3 years, to large volcanic eruptions, though pos…
The assessment of volcanic gas hazard by means of numerical models: An example from Vulcano Island (Sicily)
1999
Volcanic activity can inject large quantities of gases and aerosols into the atmosphere both during and between eruptions, creating a health risk for the local population. The paper describes how the volcanic gas concentration in the air can be computed by a flow model simulating the wind field over a digital terrain model of the volcano coupled with a Lagrangian particle model that uses the known (measured) gas emission rates to simulate gas dispersion. The coupling provides hazard maps for a number of meteorological conditions, introduced as boundary and initial conditions to the wind flow model, and permits the estimation of the risk both for actual and increased emission rates. An appli…
G-CLASS: geosynchronous radar for water cycle science – orbit selection and system design
2019
The mission geosynchronous – continental land atmosphere sensing system (G-CLASS) is designed to study thediurnal water cycle, using geosynchronous radar. Although the water cycle is vital to human society, processes on timescalesless than a day are very poorly observed from space. G-CLASS, using C-band geosynchronous radar, could transform this. Itsscience objectives address intense storms and high resolution weather prediction, and significant diurnal processes such assnow melt and soil moisture change, with societal impacts including agriculture, water resource management, flooding, andlandslides. Secondary objectives relate to ground motion observations for earthquake, volcano, and subs…