Search results for "ATOMIC SPECTROSCOPY"
showing 10 items of 29 documents
Determination of Mercury in Milk by Cold Vapor Atomic Fluorescence: A Green Analytical Chemistry Laboratory Experiment
2011
Green analytical chemistry principles were introduced to undergraduate students in a laboratory experiment focused on determining the mercury concentration in cow and goat milk. In addition to traditional goals, such as accuracy, precision, sensitivity, and limits of detection in method selection and development, attention was paid to the evaluation of green parameters of the analytical methods. Milk samples were evaluated by cold vapor atomic fluorescence spectrometry (CV-AFS) and the wastes were minimized by co-precipitation with Fe(III).
Production of ionic and atomic beams of alkaline elements
1980
Abstract An on-line mass spectrometer has been developed and used to perform atomic and nuclear spectroscopy on long series of alkali isotopes including nuclei far from stability. The apparatus was on-line either to the ISOLDE mass separator or directly to the PS, proton beam. In the case of atomic spectroscopy, a thermal atomic beam is needed. As ISOLDE delivers 60 keV ions, a high efficiency “ion-to-atom coverter” has been developed. In all cases, an “ionizer” is required to produce 10 keV ions for the ion source of the mass spectrometer. These two special devices are described, their efficiency and the consequent delay times discussed. The different targets which have been developed for …
How Lasers Can Help Probe the Distribution of Nuclear Magnetism
1989
Publisher Summary High-resolution atomic spectroscopy has played an important part in the study of nuclear electric and magnetic structure. Laser spectroscopy has been crucial for the measurement of isotope shifts, which reflect the variations of nuclear charge radii and shapes. High sensitivity and frequency resolution have allowed experiments to be carried out systematically over extensive ranges of stable and radioactive isotopes with lifetime as short as a few milliseconds. While the laser experiments also yield results for nuclear multipole moments, no measurements are obtained of the distribution of nuclear magnetization. Nuclear structure properties can be probed by penetrating elect…
Approach to quantitative spectroscopy of atomic vapor in optical nanocells
2019
We present a method for recovery of narrow homogeneous spectral features out of a broad inhomogeneous overlapped profile based on second-derivative processing of the absorption spectra of alkali metal atomic vapor nanocells. The method is shown to preserve the frequency positions and amplitudes of spectral transitions, thus being applicable for quantitative spectroscopy. The proposed technique was successfully applied and tested for measurements of hyperfine splitting and atomic transition probabilities, development of an atomic frequency reference, determination of isotopic abundance, study of atom-surface interaction, and determination of magnetic-field-induced modification of atomic tran…
How to measure nuclear ground-state properties in simple systems such as 11Li or U91+?
2008
Abstract Atomic spectroscopy yields key information on properties of ground and isomeric states via a determination of the hyperfine structure and isotope shift. In order to deduce precise nuclear moments and charge radii, the electromagnetic fields produced by the electrons at the site of the nucleus must be known with high accuracy. This is presently possible only for simple systems with very few electrons. This contribution describes two scenarios for such experiments: the determination of the charge radius of the neutron-rich isotopes 8,9Li and of the halo nucleus 11Li at the on-line isotope separators at GSI and TRIUMF and the Highly charged Ion TRAP (HITRAP) facility which is under co…
Atomic spectroscopy studies of short-lived isotopes and nuclear isomer separation with the ISOLDE RILIS
2002
The Resonance Ionization Laser Ion Source (RILIS) at the ISOLDE on-line isotope separator is based on the selective excitation of atomic transitions by tunable laser radiation. Ion beams of isotopes of 20 elements have been produced using the RILIS setup. Together with the mass separator and a particle detection system it represents a tool for high-sensitive laser spectroscopy of short-lived isotopes. By applying narrow-bandwidth lasers for the RILIS one can study isotope shifts (IS) and hyperfine structure (HFS) of atomic optical transitions. Such measurements are capable of providing data on nuclear charge radii, spins and magnetic moments of exotic nuclides far from stability. Although t…
Demonstration of sensitivity increase in mercury free-spin-precession magnetometers due to laser-based readout for neutron electric dipole moment sea…
2018
International audience; We report on a laser based $^{199}$Hg co-magnetometer deployed in an experiment searching for a permanent electric dipole moment of the neutron. We demonstrate a more than five times increased signal to-noise-ratio in a direct comparison measurement with its $^{204}$Hg discharge bulb-based predecessor. An improved data model for the extraction of important system parameters such as the degrees of absorption and polarization is derived. Laser- and lamp-based data-sets can be consistently described by the improved model which permits to compare measurements using the two different light sources and to explain the increase in magnetometer performance. The laser-based ma…
Advanced Hardware and Software for the Upgrade of Mirror/Prisma Monochromator SPM-2 (Carl Zeiss Jena) for the Measurements of Basic Spectroscopic Pro…
2021
Today's digital electronics and fast computers allow the efficiently processing of large volumes of spectroscopic information, which means the opportunity to reuse and upgrade monochromator with sophisticated optical and mechanical systems being designed and used in the middle of the last century. Particular interest is towards high-resolution prism monochromator. We used such an approach to computerize manual operations of universal mirror monochromator SPM-2, which has changeable quartz, glass, NaCl and KBr crystal prisms. SPM-2 was produced by VEB Carl Zeiss JENA in the early sixties of the last century (in former GDR), and its advanced features were widely used [1]. The current interest…
Atomic physics studies at the gamma factory at CERN
2020
The Gamma Factory initiative proposes to develop novel research tools at CERN by producing, accelerating and storing highly relativistic, partially stripped ion beams in the SPS and LHC storage rings. By exciting the electronic degrees of freedom of the stored ions with lasers, high-energy narrow-band photon beams will be produced by properly collimating the secondary radiation that is peaked in the direction of ions' propagation. Their intensities, up to $10^{17}$ photons per second, will be several orders of magnitude higher than those of the presently operating light sources in the particularly interesting $\gamma$--ray energy domain reaching up to 400 MeV. This article reviews opportuni…
Scalar Dark Matter in the Radio-Frequency Band: Atomic-Spectroscopy Search Results
2019
Among the prominent candidates for dark matter are bosonic fields with small scalar couplings to the Standard-Model particles. Several techniques are employed to search for such couplings and the current best constraints are derived from tests of gravity or atomic probes. In experiments employing atoms, observables would arise from expected dark-matter-induced oscillations in the fundamental constants of nature. These studies are primarily sensitive to underlying particle masses below $10^{-14}$ eV. We present a method to search for fast oscillations of fundamental constants using atomic spectroscopy in cesium vapor. We demonstrate sensitivity to scalar interactions of dark matter associate…