Search results for "Absolute"
showing 10 items of 518 documents
Struktur-Wirkungs-Beziehungen bei Histaminanaloga, 22. Mitt. Absolute Konfiguration und histaminartige Wirkung der enantiomeren α, Nα-Dimethylhistami…
1980
Es werden die Synthesen der enantiomeren α, Nα-Dimethylhistamine (+)—3 und (−)—3, die Ableitung der absoluten Konfiguration sowie die histaminartige Wirksamkeit der Enantiomere am Ileum (H1) und Atrium (H2) des Meerschweinchens beschrieben. Structure-Activity Relationship of Histamine Analogues. XXII: Absolute Configuration and Histamine-like Activity of the Enantiomeric α, Nα-Dimethylhistamines The synthesis of the enantiomeric α, Nα-Dimethylhistamines (+)—3 and (−)—3, the determination of the absolute configuration and the histamine-like activity of the enantiomers on the guinea-pig ileum (H1) and atrium (H2) are reported.
Struktur-Wirkungs-Beziehungen bei Histaminanaloga, 23. Mitt. Absolute Konfiguration und histaminartige Wirkung der enantiomeren α-Chlormethylhistamin…
1981
Es wird die histaminartige Wirksamkeit der enantiomeren α-Chlormethylhistamine (+)-2a und (−)-2a sowie der Nα-Methyl-α-chlormethylhistamine (+)-2b und (−)-2b am Ileum (H1) und Atrium (H2) des Meerschweinchens beschrieben und die absolute Konfiguration der Enantiomere abgeleitet. Structure-Activity Relationships of Histamine Analogues, XXIII: Absolute Configuration and Histamine-like Activity of the Enantiomeric α-Chloromethylhistamines and Nα-Methyl-α-chloromethylhistamines The histamine-like activities of the enantiomeric α-chloromethylhistamines (+)-2a and (−)-2a and of the Nα-methyl-α-chloromethylhistamines (+)-2b and (−)-2b on the guinea pig ileum (H1) and atrium (H2) are reported. The …
Les sépultures de Truchtersheim "Holderacker" (Bas-Rhin) et les pratiques funéraires du Bronze A1 dans le sud de la plaine du Rhin supérieur
2023
Die Freilegung 2019 eines kleinen frühbronzezeitlichen (2030-1900 v. Chr.) Bestattungsensemblesin Truchtersheim „Holderacker“, etwa 12 km nordwestlich von Straßburg, hat uns bewegt uns mit der gesamten für das Elsassverfügbaren Dokumentation der frühbronzezeitlichen Bestattungssitten zu befassen. Dieser bisher kaum dokumentiertechronologische Horizont wurde kürzlich durch eine Reihe von Funden bereichert, die vorwiegend zwischen 2017 und 2019bei präventivarchäologischen Operationen im Vorfeld der Bauarbeiten der Westumgehung von Straßburg entdeckt wurden.Das bescheidene regionale Corpus mit 20 Gräbern erlaubt nur begrenzte Beobachtungen, es weist jedoch doch mehrere für dieFrühbronzezeit ch…
Els epítets dels artistes baixmedievals al servei dels poders reial i municipal
2021
Aquest article estudia els adjectius que van rebre els artistes que treballaren per al rei i per a les elits ciutadanes en els territoris de parla catalana durant els segles XIV i XV. En particular, se n’hi examinen dos: apte i subtil. Les notícies exhumades per uns altres especialistes fins al moment permeten comprendre’ls en el propi context documental. Ací es compara el seu significat amb uns altres exemples de la literatura baixmedieval de la Corona d’Aragó i es du a terme una aproximació històrica com a paraules que al·ludien a la perícia de l’artista i que van ser escollides amb una finalitat. Participaren i repercutiren, per tant, en la relació històrica de l’artista amb el client, …
Freedom and Necessity in The Winter’s Tale
2014
From the first expository scene, The Winter’s Tale exhibits a concern with necessity, either through the use of the word itself, its derivatives (necessities, necessary), and their synonyms (needful, required) or through the notion of what “must” happen, what “cannot but” happen. The recurrence of such terms conveys a sense that this is a world where no one is free, and every action is dictated by force of circumstance. This is reinforced by the widespread use of the traditional imagery of fate. Yet the characters of the play are reluctant to submit to necessity. Some even fantasize states of absolute freedom, including freedom from the laws of nature. The play itself, notwithstanding the o…
Crystal structure of (1S,3R,8R,9S,10R)-10-bromomethyl-2,2-dichloro-9,10-epoxy-3,7,7-trimethyltricyclo[6.4.0.01,3]dodecane
2015
The title compound, C16H23BrCl2O, was synthesized in three steps from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (cedrus atlantica). The molecule is built up from two fused six- and seven-membered rings, each linked to a three-membered ring. The six-membered ring has a screw-boat conformation, whereas the seven-membered ring displays a twist-boat conformation. The absolute structure was established unambiguously from anomalous dispersion effects.
Crystal structure of (R)-6-fluoro-2-[(S)-oxiran-2-yl]chroman
2015
The title compound, C11H11FO2, is a building block in the synthesis of the active pharmaceutical ingredient DL-nebivolol. The synthesis starting from the enantiomerically pure (R)-6-fluoro-4-oxo-3,4-dihydro-2H-chromene-2-carboxylic acid resulted in a mixture of two stereoisomers, namely (R)-6-fluoro-2-[(S)-oxiran-2-yl]chroman and (R)-6-fluoro-2-[(R)-oxiran-2-yl]chroman. The mixture was separated by column chromatography but only one stereoisomer crystallized. The X-ray structure analysis revealed that the solid consisted of theR,Sisomer. A similar procedure was repeated for (S)-6-fluoro-4-oxo-3,4-dihydro-2H-chromene-2-carboxylic acid and, in this case, theS,Risomer was produced as a crystal…
Crystal structure and absolute configuration of (3aR,3′aR,7aS,7′aS)-2,2,2′,2′-tetramethyl-3a,6,7,7a,3′a,6′,7′,7′a-octahydro-4,4′-bi[1,3-benzodioxolyl…
2017
The absolute configuration,i.e.(3aR,3′aR,7aS,7′aS), of the title compound, C18H26O4, synthesizedviaa palladium-catalyzed homocoupling reaction, was determined on the basis of the synthetic pathway and was confirmed by X-ray diffraction. The homocoupled molecule is formed by two chemically identical moieties built up from two five- and six-membered fused rings. The supramolecular assembly is controlled mainly by C—H...O interactions that lead to the formation of hydrogen-bonded chains of molecules along the [001] direction, while weak dipolar interactions and van der Waals forces hold the chains together in the crystal structure.
Crystal structure and absolute configuration of (4S,5R,6S)-4,5,6-trihydroxy-3-methylcyclohex-2-enone (gabosine H)
2017
The absolute configuration of the title compound, determined as 4S,5R,6S on the basis of the synthetic pathway, was confirmed by single-crystal X-ray diffraction. The molecule is formed by a substituted six-membered cyclohexene ring adopting an envelope conformation and substituted by carbonyl, methyl and hydroxyl groups. The supramolecular structure is mainly built by a combination of O—H⋯O and weaker C—H⋯O hydrogen bonds.
Dissident bodies: bodies in resistance from art and feminism
2017
Resumen A lo largo de este artículo pretendemos mostrar cómo diferentes mujeres artistas han utilizado su cuerpo como un lienzo de expresión. Sus cuerpos disidentes, abiertos y llevados al extremo serán sujeto de representación y de autoafirmación, a través de los cuales empoderarse y resistir frente a las consideradas verdades absolutas patriarcales, según las cuales, las mujeres han sido representadas como objetos de placer para la miradas masculinas. Abstract Throughout this article we intend to show how different women artists have used their body as a canvas of expression. Their dissident bodies, opened and taken to the extreme, will be subject of representation and self-affirmation, t…