Search results for "Absorption"

Adsorption of Rare Earth Elements onto DNA-Functionalized Mesoporous Carbon.

2020

The recovery and separation of rare earth elements (REEs) are of national importance owing to the specific usages, high demand, and low supply of these elements. In this research, we have investigated the adsorption of rare earth elements onto DNA-functionalized mesoporous carbons with a BET surface area of 605 m2/g and a median mesopore width of 48 A. Three types of single-stranded DNA, one with 100 base units of thymine, another with 20 units of thymine, and the third, a 2000 unit long DNA from salmon milt were grafted on the carboxylated mesoporous carbon surface. All of the DNA-functionalized mesoporous carbons demonstrated higher adsorption of REEs compared to pristine mesoporous carbo…

Full multiple scattering analysis of X-ray absorption near edge structure at the Eu L3-edge in EuO

2004

Abstract X-ray absorption near edge structure (XANES) at the Eu L 3 -edge in crystalline EuO is interpreted within full multiple scattering (FMS) formalism. Our theoretical results, based on the ab initio self-consistent (SC) potential calculations, are in good agreement with experimental data. The main features in the experimental signal are reproduced taking into account a cluster of about five coordination shells, centred at the europium atom and having EuO structure. An addition of more distant coordination shells makes features only better resolved. The relatively high intensity of the peak, located just above the Eu L 3 -edge, indicates that 5d states are well localised. Comparative a…

Fast and green: Sustainable rapid-prototyping of microfluidic chips on polylactic acid substrates

2018

This paper reports novel ways to bond bio-based polylactic acid (PLA) substrates for the production of sustainable, single-use, microfluidic components. A laser-based, fast (minutes) fabrication process for multi-layer microfluidic devices in PLA was reported recently but in that report, demonstrator devices were bonded with adhesive tape, which significantly reduced the devices transparency. In this paper, we propose two novel ways to bond PLA substrates, which alleviate the need for adhesives, and enable optimal device transparency.

Some aspects of pulsed laser deposition of Si nanocrystalline films

2009

International audience; Nanocrystalline silicon films were deposited by a picosecond laser ablation on different substrates in vacuum at room temperature. A nanocrystalline structure of the films was evidenced by atomic force microscopy (AFM), optical and Raman spectroscopies. A blue shift of the absorption edge was observed in optical absorption spectra, and a decrease of the optical phonon energy at the Brillouin zone centre was detected by Raman scattering. Early stages of nanocrystalline film formation on mica and HOPG substrates were studied by AFM. Mechanism of nanocrystal growth on substrate is discussed.

On the topographic and energetic surface modifications induced by laser treatment of metallic substrates before plasma spraying

2003

Abstract Laser surface cleaning has been proven as a very suitable technique for the substitution of some surface preparation steps, such as wet cleaning and grit blasting. The mechanisms involved in short pulsed laser ablation include the absorption of the laser light and conversion into heat via collisional processes. Ejection of matter is achieved either by direct vaporization or hydrodynamical sputtering. This article aims at clarifying the laser–matter interaction mechanisms and effects on metallic materials for different surfaces initial roughness and laser beam energy densities. Both topographic and energetic modifications are investigated by SEM observations, roughness characterizat…

EXAFS study of hydrogen intercalation into ReO 3 using the evolutionary algorithm.

2014

In this study we have investigated the influence of hydrogen intercalation on the local atomic structure of rhenium trioxide using a new approach to EXAFS data analysis, based on the evolutionary algorithm (EA). The proposed EA-EXAFS method is an extension of the conventional reverse Monte Carlo approach but is computationally more efficient. It allows one to perform accurate analysis of EXAFS data from distant coordination shells, taking into account both multiple-scattering and disorder (thermal and static) effects. The power of the EA-EXAFS method is first demonstrated on an example of the model system, pure ReO3, and then it is applied to an in situ study of hydrogen bronze HxReO3 upon …

Temperature-dependent EXAFS study of the local structure and lattice dynamics in cubic Y2O3

2016

The local structure and lattice dynamics in cubic Y2O3were studied at the YK-edge by X-ray absorption spectroscopy in the temperature range from 300 to 1273 K. The temperature dependence of the extended X-ray absorption fine structure was successfully interpreted using classical molecular dynamics and a novel reverse Monte Carlo method, coupled with the evolutionary algorithm. The obtained results allowed the temperature dependence of the yttria atomic structure to be followed up to ∼6 Å and to validate two force-field models.

Rapid determination of lead in petrol by atomic absorption spectrometry of emulsified samples

1979

Evidence of competitive inhibition of methotrexate absorption by leucovorin calcium in rat small intestine

1997

Abstract The effect of leucovorin calcium on the intestinal absorption of methotrexate in rat small intestine was investigated using an in situ rat gut technique. First, the kinetic absorption in situ parameters for methotrexate in solution were obtained: V m =21.54 (±2.22) μ M/h; K m =10.51 (±1.08) μ M; k a =0.26 (±0.03) h −1 and AIC=−188.63. The inhibitory effect of leucovorin calcium in methotrexate intestinal absorption has been investigated by perfusing of 10 μ M methotrexate isotonic solutions containing increasing concentrations of leucovorin calcium (10–500 μ M), and the remaining concentrations of both compounds were measured. A competitive inhibition of methotrexate absorption was…

Time-variations of zeroth-order vegetation absorption and scattering at L-band

2021

Abstract Surface soil moisture and vegetation optical depth (VOD), as an indicator of vegetation wet biomass, from passive microwave remote sensing have been increasingly applied in global ecology and climate research. Both soil moisture and VOD are retrieved from satellite brightness temperature measurements assuming a zeroth order radiative transfer model, commonly known as the tau-omega model. In this model the emission of a vegetated surface is dependent on soil moisture, vegetation absorption and vegetation scattering. Vegetation scattering is normally represented by the single scattering albedo, ω, and is commonly assumed to be a time-invariant calibration parameter to achieve high ac…