Search results for "Adiabatic process"
showing 7 items of 237 documents
Ultrafast stimulated Raman parallel adiabatic passage by shaped pulses
2009
We present a general and versatile technique of population transfer based on {\it parallel adiabatic passage} by femtosecond shaped pulses. Their amplitude and phase are specifically designed to optimize the adiabatic passage corresponding to parallel eigenvalues at all times. We show that this technique allows the robust adiabatic population transfer in a Raman system with the total pulse area as low as 3 $\pi$, corresponding to a fluence of one order of magnitude below the conventional stimulated Raman adiabatic passage process. This process of short duration, typically pico- and subpicosecond, is easily implementable with the modern pulse shaper technology and opens the possibility of ul…
Transition dynamics in optical fiber amplifiers operating in the normal dispersion regime
2011
Over the past decade there has been large interest in ultrafast optical fiber amplifiers operating in the normal dispersion regime because of the discovery that, high-energy pulses with a parabolic intensity profile and linear frequency chirp are the asymptotic solution to the system for arbitrary initial conditions [1]. These so-called “similariton” solutions propagate in a self-similar manner, holding certain relations (scaling) between pulse power, duration, and chirp parameter. While the asymptotic similariton features seem now well understood [1], the physics of the transition to this solution from arbitrary initial pulses has not been fully explored yet (most of the previous attempts …
Orientation of Polar Molecules by Laser Induced Adiabatic Passage
2002
International audience; We show that two overlapping linearly polarized laser pulses of frequencies ω and its second harmonic 2ω can strongly orient linear polar molecules, by adiabatic passage along dressed states. The resulting robust orientation can be interpreted as a laser-induced localization in the effective double well potential created by the fields, which induces a preliminary molecular alignment. The direction of the orientation can be selected by the relative phase of the fields.
The Kleiner Feldberg Cloud Experiment 1990. An overview
1994
An overview is given of the Kleiner Feldberg cloud experiment performed from 27 October until 13 November 1990. The experiment was carried out by numerous European research groups as a joint effort within the EUROTRAC-GCE project in order to study the interaction of cloud droplets with atmospheric trace constituents. After a description of the observational site and the measurements which were performed, the general cloud formation mechanisms encountered during the experiment are discussed. Special attention is given here to the process of moist adiabatic lifting. Furthermore, an overview is given regarding the pollutant levels in the gas phase, the particulate and the liquid phase, and som…
On the electron affinity of TCNQ
2004
The electron affinity of 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) has been studied with density functional theory and coupled cluster (CC) procedures. The adiabatic electron affinity of TCNQ calculated with the B3LYP method is about 1 eV higher than the available experimental value. At the CCSD(T) level, the theoretical result is overestimated by more than 0.4 eV. The electron affinity computed for TCNQ is larger than that obtained for tetracyanoethylene at all levels of calculation, exactly the opposite of what is observed experimentally. Accordingly, a call for an additional empirical measurement of such a property is made.
Merging Features from Green's Functions and Time Dependent Density Functional Theory: A Route to the Description of Correlated Materials out of Equil…
2016
We propose a description of nonequilibrium systems via a simple protocol that combines exchange-correlation potentials from density functional theory with self-energies of many-body perturbation theory. The approach, aimed to avoid double counting of interactions, is tested against exact results in Hubbard-type systems, with respect to interaction strength, perturbation speed and inhomogeneity, and system dimensionality and size. In many regimes, we find significant improvement over adiabatic time dependent density functional theory or second Born nonequilibrium Green's function approximations. We briefly discuss the reasons for the residual discrepancies, and directions for future work.
Strictly correlated electrons approach to excitation energies of dissociating molecules
2019
In this work we consider a numerically solvable model of a two-electron diatomic molecule to study a recently proposed approximation based on the density functional theory of so-called strictly correlated electrons (SCE). We map out the full two-particle wave function for a wide range of bond distances and interaction strengths and obtain analytic results for the two-particle states and eigenenergies in various limits of strong and weak interactions, and in the limit of large bond distance. We then study the so-called Hartree-exchange-correlation (Hxc) kernel of time-dependent density functional theory which is a key ingredient in calculating excitation energies. We study an approximation b…