Search results for "Adiabatic process"
showing 10 items of 237 documents
Mutual capture of dipolar molecules at low and very low energies. II. Numerical study.
2011
The low-energy rate coefficients of capture of two identical dipolar polarizable rigid rotors in their lowest nonresonant (j(1) = 0 and j(2) = 0) and resonant (j(1) = 0, 1 and j(2) = 1, 0) states are calculated accurately within the close-coupling (CC) approach. The convergence of the quantum rate coefficients to their quantum-classical counterparts is studied. A comparison of the present accurate numerical with approximate analytical results (Nikitin, E. E.; Troe, J. J. Phys. Chem. A 2010, 114, 9762) indicates a good performance of the previous approach which was based on the interpolation between s-wave fly wheel quantal and all-wave classical adiabatic channel limits. The results obtaine…
Quantum-chemical calculation of Born–Oppenheimer breakdown parameters to rotational constants
2010
The paper describes how Born–Oppenheimer breakdown parameters for the rotational constants of diatomic molecules can be determined via quantum-chemical computations. The deviations from the Born–Oppenheimer equilibrium values are accounted for by considering the adiabatic correction to the equilibrium bond distances, the electronic contribution to the rotational constant via the rotational g tensor, and the so-called Dunham correction, which can be computed directly from a polynomial expansion of the potential curve around the equilibrium distance. Calculations for HCl, SiS, and HF demonstrate the accuracy that can be achieved in the theoretical treatment of the considered Born–Oppenheimer …
Ultimate field-free molecular alignment by combined adiabatic-impulsive field design
2008
We show that a laser pulse designed as an adiabatic ramp followed by a kick allows one to reach a perfect postpulse molecular alignment, free of saturation. The mechanism is based on an optimized distribution of the energy between a weakly efficient but non saturating adiabatic ramp and an efficient but saturating impulsive field. Unprecedent degrees of alignment are predicted using state-of-the-art pulse shaping techniques and non-destructive field intensities. The scheme can be extended to reach high degrees of orientation of polar molecules using designed half-cycle pulses.
Two-laser multiphoton adiabatic passage in the frame of the Floquet theory. Applications to (1+1) and (2+1) STIRAP
1998
We develop an adiabatic two-mode Floquet theory to analyse multiphoton coherent population transfer in N-level systems by two delayed laser pulses, which is a generalization of the three-state stimulated Raman adiabatic passage (STIRAP). The main point is that, under conditions of non-crossing and adiabaticity, the outcome and feasibility of a STIRAP process can be determined by the analysis of two features: (i) the lifting of degeneracy of dressed states at the beginning and at the end of the laser pulses, and (ii) the connectivity of these degeneracy-lifted branches in the quasienergy diagram. Both features can be determined by stationnary perturbation theory in the Floquet representation…
Quantum dynamics by the constrained adiabatic trajectory method
2011
We develop the constrained adiabatic trajectory method (CATM) which allows one to solve the time-dependent Schr\"odinger equation constraining the dynamics to a single Floquet eigenstate, as if it were adiabatic. This constrained Floquet state (CFS) is determined from the Hamiltonian modified by an artificial time-dependent absorbing potential whose forms are derived according to the initial conditions. The main advantage of this technique for practical implementation is that the CFS is easy to determine even for large systems since its corresponding eigenvalue is well isolated from the others through its imaginary part. The properties and limitations of the CATM are explored through simple…
Adiabatic invariants drive rhythmic human motion in variable gravity.
2019
Voluntary human movements are stereotyped. When modeled in the framework of classical mechanics they are expected to minimize cost functions that may include energy, a natural candidate from a physiological point of view also. In time-changing environments, however, energy is no longer conserved---regardless of frictional energy dissipation---and it is therefore not the preferred candidate for any cost function able to describe the subsequent changes in motor strategies. Adiabatic invariants are known to be relevant observables in such systems, although they still need to be investigated in human motor control. We fill this gap and show that the theory of adiabatic invariants provides an ac…
A consistent microscopic theory of collective motion in the framework of an ATDHF approach
1978
Based on merely two assumptions, namely the existence of a collective Hamiltonian and that the collective motion evolves along Slater determinants, we first derive a set of adiabatic time-dependent Hartree-Fock equations (ATDHF) which determine the collective path, the mass and the potential, second give a unique procedure for quantizing the resulting classical collective Hamiltonian, and third explain how to use the collective wavefunctions, which are eigenstates of the quantized Hamiltonian.
Pair creation in electric fields, anomalies, and renormalization of the electric current
2018
We investigate the Schwinger pair production phenomena in spatially homogeneous strong electric fields. We first consider scalar QED in four-dimensions and discuss the potential ambiguity in the adiabatic order assignment for the electromagnetic potential required to fix the renormalization subtractions. We argue that this ambiguity can be solved by invoking the conformal anomaly when both electric and gravitational backgrounds are present. We also extend the adiabatic regularization method for spinor QED in two-dimensions and find consistency with the chiral anomaly. We focus on the issue of the renormalization of the electric current $\langle j^\mu \rangle$ generated by the created pairs.…
Adiabatic regularization for Dirac fields in time-varying electric backgrounds
2020
The adiabatic regularization method was originally proposed by Parker and Fulling to renormalize the energy-momentum tensor of scalar fields in expanding universes. It can be extended to renormalize the electric current induced by quantized scalar fields in a time-varying electric background. This can be done in a way consistent with gravity if the vector potential is considered as a variable of adiabatic order one. Assuming this, we further extend the method to deal with Dirac fields in four spacetime dimensions. This requires a self-consistent ansatz for the adiabatic expansion, in presence of a prescribed time-dependent electric field, which is different from the conventional expansion u…
Adiabatic regularization and particle creation for spin one-half fields
2013
The extension of the adiabatic regularization method to spin-$1/2$ fields requires a self-consistent adiabatic expansion of the field modes. We provide here the details of such expansion, which differs from the WKB ansatz that works well for scalars, to firmly establish the generalization of the adiabatic renormalization scheme to spin-$1/2$ fields. We focus on the computation of particle production in de Sitter spacetime and obtain an analytic expression of the renormalized stress-energy tensor for Dirac fermions.