Search results for "Adiabatic process"
showing 10 items of 237 documents
Photochemistry and Non-adiabatic Photodynamics of the HOSO Radical
2021
6 pags., 2 figs.
Purification of Lindblad dynamics, geometry of mixed states and geometric phases
2015
We propose a nonlinear Schr\"odinger equation in a Hilbert space enlarged with an ancilla such that the partial trace of its solution obeys to the Lindblad equation of an open quantum system. The dynamics involved by this nonlinear Schr\"odinger equation constitutes then a purification of the Lindbladian dynamics. This nonlinear equation is compared with other Schr\"odinger like equations appearing in the theory of open systems. We study the (non adiabatic) geometric phases involved by this purification and show that our theory unifies several definitions of geometric phases for open systems which have been previously proposed. We study the geometry involved by this purification and show th…
Giant barocaloric effects over a wide temperature range in superionic conductor AgI
2017
Current interest in barocaloric effects has been stimulated by the discovery that these pressure-driven thermal changes can be giant near ferroic phase transitions in materials that display magnetic or electrical order. Here we demonstrate giant inverse barocaloric effects in the solid electrolyte AgI, near its superionic phase transition at ~420 K. Over a wide range of temperatures, hydrostatic pressure changes of 2.5 kbar yield large and reversible barocaloric effects, resulting in large values of refrigerant capacity. Moreover, the peak values of isothermal entropy change (60 J K−1 kg−1 or 0.34 J K−1 cm−3) and adiabatic temperature changes (18 K), which we identify for a starting tempera…
Spectral index-flux relation for investigating the origins of steep decay in γ-ray bursts
2020
$\gamma$-ray bursts (GRBs) are short-lived transients releasing a large amount of energy ($10^{51}-10^{53} $ erg) in the keV-MeV energy range. GRBs are thought to originate from internal dissipation of the energy carried by ultra-relativistic jets launched by the remnant of a massive star's death or a compact binary coalescence. While thousands of GRBs have been observed over the last thirty years, we still have an incomplete understanding of where and how the radiation is generated in the jet. Here we show a relation between the spectral index and the flux found by investigating the X-ray tails of bright GRB pulses via time-resolved spectral analysis. This relation is incompatible with the…
Quantum waveguides with magnetic fields
2019
International audience; We study generalised quantum waveguides in the presence of moderate and strong external magnetic fields. Applying recent results on the adiabatic limit of the connection Laplacian we show how to construct and compute effective Hamiltonians that allow, in particular, for a detailed spectral analysis of magnetic waveguide Hamiltonians. We apply our general construction to a number of explicit examples, most of which are not covered by previous results.
Rovibrational controlled-NOT gates using optimized stimulated Raman adiabatic passage techniques and optimal control theory
2009
Implementation of quantum controlled-NOT (CNOT) gates in realistic molecular systems is studied using stimulated Raman adiabatic passage (STIRAP) techniques optimized in the time domain by genetic algorithms or coupled with optimal control theory. In the first case, with an adiabatic solution (a series of STIRAP processes) as starting point, we optimize in the time domain different parameters of the pulses to obtain a high fidelity in two realistic cases under consideration. A two-qubit CNOT gate constructed from different assignments in rovibrational states is considered in diatomic (NaCs) or polyatomic $({\text{SCCl}}_{2})$ molecules. The difficulty of encoding logical states in pure rota…
Strategies for efficient field-free molecular alignment and its control
2008
Strategies using shaped laser fields to produce and control efficient field-free alignment are analyzed and compared. It is in particular shown that the strategy recently proposed using a shaped laser field combining an adiabatic ramp with a kick is superior to the bipulse strategy.
2020
Organisms use photo-receptors to react to light. The first step is usually the absorption of a photon by a prosthetic group embedded inside the photo-receptor, often a conjugated chromophore. The electronic changes in the chromophore induced by photo-absorption can trigger a cascade of structural or chemical transformations that culminate into a response to light. Understanding how these proteins have evolved to mediate their activation process has remained challenging because the required time and spacial resolutions are notoriously difficult to achieve experimentally. Therefore, mechanistic insights into photoreceptor activation have been predominantly obtained with computer simulations. …
Ionization potential of Al6 and Al7 as a function of temperature
1999
The temperature-depence of the ionization potential of Al6 and Al7 clusters is studied by using ab initio molecular dynamics. The threshold regions of theoretical photoionization efficiency curves are obtained from the calculated ionization potential distributions by integration and the determined ionization potentials are compared with the experimental ones. Two important effects, which complicate the determination of ionization potential from photoionization efficiency curves, are observed: the thermal tail effect and the isomerization. Also a link between the adiabatic ionization potential and the threshold of the photoionization efficiency curve is discussed. In the case of Al7, this of…
Removal of Resonances
2001
From the perturbative procedure in the last chapter we have learned that in the proximity of resonances of the unperturbed system, resonant denominators appear in the expression for the adiabatic invariants. We now wish to begin to locally remove such resonances by trying, with the help of a canonical transformation, to go to a coordinate system which rotates with the resonant frequency.