Search results for "AlON"

showing 10 items of 799 documents

CaCl2, Bisoxazoline, and Malonate: A Protocol for an Asymmetric Michael Reaction

2015

A mild protocol for the asymmetric Michael addition of dimethyl malonate to various α,β-unsaturated carbonyl compounds was developed. The salient feature of this methodology is that a cheap and environmentally friendly Lewis acid, CaCl2, was used as a catalyst. An aminoindanol- and pyridine-derived ligand provided in the presence of CaCl2 Michael adducts in moderate to high enantioselectivities. The scope of the reaction was demonstrated.

Bisoxazolineinorganic chemicalsAminoindanol010405 organic chemistryChemistryLigandOrganic ChemistryMalonateCaCl2macromolecular substances010402 general chemistrybehavioral disciplines and activities01 natural sciencesDimethyl malonatehumanities0104 chemical sciencesCatalysisAdductchemistry.chemical_compoundMalonateMichael reactionOrganic chemistryLewis acids and basesta116The Journal of Organic Chemistry
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The effects of alpha-cypermethrin exposure on biochemical and redox parameters in pregnant rats and their newborns

2016

IF 2.388; International audience; Pyrethroid insecticides are extensively used in agriculture and in household activities. During pregnancy, they might affect maternal metabolic status and there after fetal development. In this work, we studied metabolic and redox effects of low dose alpha-cypermethrin exposure in pregnant rats and their offspring. The diet containing alpha cypermethrin at 0.02 mg/kg/day was consumed during the entire gestation. Plasma biochemical parameters as well as liver lipid and oxidative stress markers were determined. Our results showed that alpha-cypermethrin induced an increase in body weight and in plasma glucose and lipid levels, as well as in plasma aspartate a…

Blood Glucose0301 basic medicineLipid-PeroxidationInsecticidesHealth Toxicology and Mutagenesismedicine.disease_causeCypermethrinchemistry.chemical_compoundMice0302 clinical medicinePregnancyMalondialdehydePyrethrinsMaternal-Fetal Exchange[ SDV.MHEP.PHY ] Life Sciences [q-bio]/Human health and pathology/Tissues and Organs [q-bio.TO]Alpha-cypermethrinAlanine TransaminaseGeneral Medicine030224 pathologyGlutathioneLipidsMitochondriaLiverPrenatal Exposure Delayed EffectsGestationAlkaline phosphataseFemaleChlorpyrifosOxidation-Reductionmedicine.medical_specialtyOffspringBlood sugarBiology03 medical and health sciencesProtective RoleOffspringMetabolic DiseasesInternal medicinemedicineNeurotoxicityAnimalsAspartate AminotransferasesRats WistarPesticides[ SDV.BBM ] Life Sciences [q-bio]/Biochemistry Molecular BiologyPregnancyFetusBody Weightmedicine.diseaseRatsOxidative Stress030104 developmental biologyEndocrinologyMetabolismAnimals NewbornchemistryRatAgronomy and Crop ScienceDeltamethrinFenvalerateOxidative stress
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Beneficial Effect of Docosahexanoic Acid and Lutein on Retinal Structural, Metabolic, and Functional Abnormalities in Diabetic Rats

2009

To assess the effect of docosahexanoic acid (DHA) and lutein (both compounds with anti-inflammatory and antioxidant properties) on experimental diabetic retinopathy.Male Wistar rats were studied: non-diabetic controls, untreated diabetic controls, and diabetic rats were treated with DHA and lutein or the combination of DHA + insulin and lutein + insulin for 12 weeks. Oxidative stress and inflammatory markers, apoptosis, and functional tests were studied to confirm biochemical and functional changes in the retina of diabetic rats. Malondialdehyde (MDA), glutathione concentrations (GSH), and glutathione peroxidase activity (GPx) were measured as oxidative stress markers. TUNEL assay and caspa…

Blood GlucoseMaleLuteingenetic structuresmedicine.medical_treatmentApoptosismedicine.disease_causeAntioxidantschemistry.chemical_compoundMalondialdehydeInsulinFluorescent Antibody Technique Indirectchemistry.chemical_classificationCaspase 3NitrotyrosineGlutathione peroxidaseAnti-Inflammatory Agents Non-Steroidalfood and beveragesMalondialdehydeGlutathioneSensory SystemsDrug Therapy Combinationmedicine.medical_specialtyDocosahexaenoic AcidsEnzyme-Linked Immunosorbent AssayBiologyRetinaDiabetes Mellitus ExperimentalCellular and Molecular NeuroscienceDiabetes mellitusInternal medicineElectroretinographyIn Situ Nick-End LabelingmedicineAnimalsRats WistarGlutathione PeroxidaseDiabetic RetinopathyInsulinLuteinGlutathionemedicine.diseaseeye diseasesRatsOxidative StressOphthalmologyEndocrinologychemistryTyrosinesense organsBiomarkersOxidative stressCurrent Eye Research
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Enhanced Oxidative Stress and Other Potential Biomarkers for Retinopathy in Type 2 Diabetics: Beneficial Effects of the Nutraceutic Supplements

2015

We have studied the global risk of retinopathy in a Mediterranean population of type 2 diabetes mellitus (T2DM) patients, according to clinical, biochemical, and lifestyle biomarkers. The effects of the oral supplementation containing antioxidants/omega 3 fatty acids (A/ω3) were also evaluated. Suitable participants were distributed into two main groups: (1) T2DMG (with retinopathy (+DR) or without retinopathy (−DR)) and (2) controls (CG). Participants were randomly assigned (+A/ω3) or not (−A/ω3) to the oral supplementation with a daily pill of Nutrof Omega (R) for 18 months. Data collected including demographics, anthropometrics, characteristics/lifestyle, ophthalmic examination (best cor…

Blood GlucoseMaleoptical coherenceGlycated Hemoglobin Alcsh:MedicineType 2 diabetesmedicine.disease_causeGastroenterologyAntioxidantschemistry.chemical_compoundMalondialdehyde80 and overglycosylatedAged 80 and overeducation.field_of_studyGeneral MedicineDiabetic retinopathyMiddle AgedMalondialdehydetype 2diabetes mellitusFemaleomega-3Tomography Optical CoherenceResearch ArticleRetinopathyAdultmedicine.medical_specialtyArticle Subjecthemoglobin APopulationtomographyfatty acidsGeneral Biochemistry Genetics and Molecular BiologyInternal medicineFatty Acids Omega-3medicineHumanseducationTriglyceridesAgedGlycated HemoglobinDiabetic RetinopathyGeneral Immunology and MicrobiologySettore MED/30 - Malattie Apparato Visivobusiness.industryadult; aged; aged 80 and over; antioxidants; biomarkers; blood glucose; diabetes mellitus type 2; diabetic retinopathy; fatty acids omega-3; female; hemoglobin A glycosylated; humans; male; malondialdehyde; middle aged; oxidative stress; tomography optical coherence; triglycerides; dietary supplementslcsh:RType 2 Diabetes Mellitusmedicine.diseaseOxidative StressEndocrinologyDiabetes Mellitus Type 2chemistryDietary SupplementsHemoglobinbusinessBiomarkersOxidative stressBioMed Research International
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Spectrofluorimetric Quantification of Malondialdehyde for Evaluation of Cyclooxygenase-1/Thromboxane Synthase Inhibition

1999

The in vitro assay developed by Hartmann and Ledergerber (1995) utilizing the spectrofluorimetric quantification of malondialdehyde after reaction with thiobarbituric acid was modified and used for further investigations. The human whole blood was replaced by a platelet suspension of pig blood, and calcium ionophore A23187 was used instead of collagen for inducing the arachidonic acid cascade. The modified assay represents a simple, time and cost saving method for the evaluation of cyclooxygenase-1/thromboxane synthase inhibition. The reproducibility and comparability of results is given. Additional experiments allow classification of selective phospholipase A2, cyclooxygenase-1, and thromb…

Blood PlateletsSwineThiobarbituric acidPharmaceutical ScienceCyclooxygenase pathwaychemistry.chemical_compoundPhospholipase A2MalondialdehydeDrug DiscoveryAnimalsHumansCyclooxygenase InhibitorsDrug InteractionsPlateletEnzyme InhibitorsDose-Response Relationship DrugbiologyImidazolesMembrane ProteinsReproducibility of ResultsThiobarbituratesMalondialdehydeIsoenzymesSpectrometry FluorescencechemistryBiochemistryProstaglandin-Endoperoxide SynthasesCyclooxygenase 1biology.proteinArachidonic acidThromboxane-A SynthaseThromboxane-A synthaseCyclooxygenaseArchiv der Pharmazie
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Kreisās sirds puses izejas trakta obstrukciju intervencionālas vai operatīvas korekcijas 5 gadu griezumā bērniem Latvijā

2019

Aktualitāte. Iedzimtas sirds slimības ir visbiežākā lielo iedzimto malformāciju grupa. Tās skar aptuveni astoņus līdz desmit no 1000 dzīvi dzimušajiem. Vienai ceturtajai daļai no šiem jaundzimušajiem sastop kritisku iedzimtu sirdskaiti. Šiem pacientiem ir nepieciešama transvazāla vai ķirurģiska ārstēšana pirmajā dzīves gadā. Mūsdienu ārstēšanas tehnoloģijas ir ievērojami uzlabojušas paredzamo dzīves ilgumu, līdz ar to ir ļoti palielinājies pacientu skaits ar iedzimtām sirdskaitēm pusaudžu vecumā. Darba mērķis. Noskaidrot sirds kreisās puses obstrukcijas intervencionālas vai ķirurģiskas iejaukšanās biežumu un efektivitāti bērniem Latvijā laika posmā no 2012. līdz 2016. gadam un izvērtēt ārst…

Bērnu kardioloģijaĶirurģiska aortālā vārstuļa korekcijaKreisā kambara izejas trakta obstrukcijaTransvazāla aortālā vārstuļa balonvalvuloplastijaMedicīna
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ACCORDI DI CO-VENDITA (Drag e Tag Along): profili civilistici e prassi applicativa

2012

CO-VENDITATag AlongSettore IUS/01 - Diritto PrivatoDrag
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Pasajes de París / 3: Al paso de la ciudad

2006

CallesPasoVidal-Beneyto JoséEspacio públicoBóvedasPARÍSBurguesíaPublicaciones: Obra periodística: Columnas y artículos de opiniónPaseantesColumnasGaleríasSeguridadVidrioTiendasSiglo XVIIISalones de téCafésCapitalismo comercialSiglo XIXCiudadPASAJESBenjaminTránsitoCondición museográficaAntiguo RégimenConfortHierroCompradores
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Sexing adult Cory's Shearwater by discriminant analysis of body measurements on Linosa Island (Sicilian Channel), Italy

2001

-Males and females of many avian species may show no plumage dimorphism, but often can be sexed by differences in body measurements. Sex determination of many Cory's Shearwaters Calonectris diomedea, was possible by multiplying bill length by bill depth. In this study, discriminant analysis of six measurements (bill length, bill depth, wing, tail, tarsus and mass) was performed on Cory's Shearwaters breeding on Linosa Island (Sicilian Channel), Italy and the efficiency of sex determination was compared with the univariate method. Results show the advantages of the discriminant functions. Bill depth is the best parameter (up to 92% correct classification), followed by mass (84% correct class…

Calonectris diomedeaDiscriminant analysiZoologySexingBiologyLinear discriminant analysisbiology.organism_classificationlanguage.human_languageSexual dimorphismPlumageCory's ShearwaterlanguageCalonectris diomedeaAnimal Science and ZoologyCory's shearwaterSicilianSicily
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Olfactory foraging in temperate waters: sensitivity to dimethylsulphide of shearwaters in the Atlantic Ocean and Mediterranean Sea

2014

AbstractMany procellariiforms use olfactory cues to locate food patches over the seemingly featureless ocean surface. In particular, some of them are able to detect and are attracted by dimethylsulfide (DMS), a volatile compound naturally occurring over worldwide oceans in correspondence with productive feeding areas. However, current knowledge is restricted to sub-Antarctic species, and to only one study realized under natural conditions at sea. Here, for the first time, we investigated the response to DMS in parallel in two different environments in temperate waters, the Atlantic Ocean and the Mediterranean Sea, employing Cory's (Calonectris borealis) and Scopoli's shearwaters (Calonectri…

Calonectris diomedeaPhysiologyOceans and SeasForagingOlfactory cuesSulfidesAquatic ScienceBiologyBirdsMediterranean seaMediterranean SeaTemperate climateAnimalsAtlantic OceanMolecular BiologyEcology Evolution Behavior and SystematicsEcologyWaterFeeding Behaviorbiology.organism_classificationSmellOceanographySettore AGR/11 - Entomologia Generale E ApplicataInsect ScienceOdorantsAnimal Science and ZoologyCuesDMS Foraging Odour cues Olfaction Petrels Procellariiform seabirdsCalonectris borealisRegional differences
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