Search results for "Alloy"
showing 10 items of 2153 documents
Protection against chemical submission: naked-eye detection of γ-hydroxybutyric acid (GHB) in soft drinks and alcoholic beverages
2020
Two new oxazole derivatives, able to detect γ-hydroxybutyric acid (GHB) in soft drinks and alcoholic beverages, by color and fluorescence changes, are reported.
A new selective fluorogenic probe for trivalent cations.
2012
[EN] A new selective chromo-fluorogenic probe for Fe 3+, Cr 3+ and Al 3+ is reported. Detection limits are in the ¿M range and the fluorogenic sensing ability could be observed by the naked eye when illuminated with UV-light. No response is observed with divalent cations. © 2012 The Royal Society of Chemistry.
Strong circularly polarized luminescence of an octahedral chromium(iii) complex
2019
The chiral spin-flip luminophore [Cr(ddpd)2]3+ can be resolved into enantiopure material by chiral HPLC. The corresponding enantiomers show very high luminescence dissymmetry factors of up to ∣glum ∣≈ 0.093 in circularly polarized luminescence (CPL) measurements for the "ruby-like" phosphorescence transition 2E/2T1 → 4A2 in the near-IR region around λ ≈ 775 nm.
Halloysite nanotubes-carbon dots hybrids multifunctional nanocarrier with positive cell target ability as a potential non-viral vector for oral gene …
2019
Abstract Hypothesis The use of non-viral vectors for gene therapy is hindered by their lower transfection efficiency and their lacking of self-track ability. Experiments This study aims to investigate the biological properties of halloysite nanotubes-carbon dots hybrid and its potential use as non-viral vector for oral gene therapy. The morphology and the chemical composition of the halloysite hybrid were investigated by means of high angle annular dark field scanning TEM and electron energy loss spectroscopy techniques, respectively. The cytotoxicity and the antioxidant activity were investigated by standard methods (MTS, DPPH and H2O2, respectively) using human cervical cancer HeLa cells …
Exchange coupling in the correlated electronic states of amorphous GdFe films
2013
The bulk sensitivity of hard x-ray photoelectron spectroscopy in combination with circularly polarized radiation of the P09 beamline at PETRA III enables the investigation of the magnetic properties of capped films. We have determined the temperature dependence of the magnetic circular dichroism in the Fe 2$p$ and in the Gd 3$d$ states in amorphous GdFe films. The magnetic dichroism reflects the stronger temperature dependence of Gd moments compared to Fe moments in agreement with mean-field models. We resolved the exchange split Gd 3${d}_{5/2}$ substates and found a significant temperature dependence of the splitting which is attributed to a temperature dependent part of the exchange energ…
Circular dichroism in angular resolved photoemission from pure and Rb-doped C60 and C22H14 layers on platinum and tungsten
1997
Abstract Polycrystalline C60 and Pentacene films grown on W(110) and Pt(111) have been studied in valence band photoemission using circularly polarised synchrotron radiation from BESSY with special emphasis on circular dichroism in photoemission. For thin films of C60, dichroic asymmetries of about 10% occur independent of the temperature and the substrate hinting that the rotation of the topmost layer is hindered even at room temperature. For Pentacene we found asymmetries up to 50% in the region of the σ-electrons. Moreover, we found for this molecule a dichroic asymmetry in normal emission, that is a forbidden geometry. This hints on adsorption with the molecules perpendicularly oriented…
An energy efficiency analysis of single point incremental forming as an approach for sheet metal based component reuse
2020
Producing materials causes about 25% of all anthropogenic CO2 emissions. Metals play a significant role, steel and aluminum account for 24% and 3% of worldwide material related emissions respectively. Fostering resources efficiency strategies in the field of sheet components could lead to a significant environmental impact reduction. Reshaping could be one of the most efficient strategy to foster material reuse and lower the environmental impact due to material production. Specifically, for aluminum recycling, the overall energy efficiency of conventional route is very low and, more importantly, permanent material losses occur during re-melting because of oxidation. The present paper aims a…
Specific interaction of citrate with bis(fluorophoric) bibrachial lariat aza-crown in comparison with the other components of the Krebs cycle
2006
Clares Garcia, M. Paz, M.Paz.Clares@uv.es ; Garcia-España Monsonis, Enrique, Enrique.Garcia-Es@uv.es ; Soriano Soto, Concepcion, Concepcion.Soriano@uv.es ; Tejero Toquero, Roberto, Roberto.Tejero@uv.es
Magnesium alloys laser (Nd:YAG) cladding and alloying with side injection of aluminium powder
2003
International audience; The development of the high purity magnesium alloys (such as WE43) incites the designers to reconsider them, and the car industry appears, these days, the most interested to use this kind of alloy. However, due to their ignitability and tendency to oxidation, magnesium alloys require surface treatments. A series of experiments was carried out in order to improve the corrosion resistance of two types of magnesium alloys, WE43 and ZE41. In most cases, the substrate surface was treated before laser interaction. Side injection of aluminium powder under a 3 kW cw Nd:YAG laser was employed. The deposited layers present very good bond properties. The resulting microstructur…
MoSi2 laser cladding—elaboration, characterisation and addition of non-stabilized ZrO2 powder particles
2003
International audience; The cladding process using laser beam radiation comprises different operational regimes, depending on the involved lasers (usually CO2 or Nd:YAG) and materials. A series of experiments has been carried out to investigate Nd:YAG laser cladding using MoSi2 powder. Procedures and operating parameters for producing clad layers has been developed and their properties evaluated. The feasibility of the laser cladding technique, using a high power Nd:YAG laser, by projecting MoSi2 powder on steel substrate was demonstrated. The results indicate a low density of cracks, elevated powder catchment efficiency (between 65 and 90%) and hardness values around 1200–1300 HV. Our goal…