Search results for "Aluminium"
showing 10 items of 548 documents
Mechanical properties of aluminum, zirconium, hafnium and tantalum oxides and their nanolaminates grown by atomic layer deposition
2015
ABSTRACT The mechanical properties of two different metal oxide nanolaminates comprised of Ta 2 O 5 and Al 2 O 3 , HfO 2 or ZrO 2 , grown on soda–lime glass substrate by atomic layer deposition, were investigated. Ta 2 O 5 and Al 2 O 3 layers were amorphous, whereas ZrO 2 and HfO 2 possessed crystalline structure. Thickness of single oxide layers was varied between 2.5 and 15 nm. The total thickness of the laminate structures was in the range of 160–170 nm. The hardness values of single layer oxides on glass ranged from 6.7 GPa (Ta 2 O 5 ) to 9.5 GPa (Al 2 O 3 ). Corresponding elastic moduli were 96 GPa and 101 GPa. The hardnesses of laminates were in the range of 6.8–7.8 GPa and elastic mo…
An empirical method to determine the free surface energy of solids at different deformations and temperatures regimes : An application to Al.
2005
Abstract We have performed molecular dynamics (MD) simulations using the three low index surfaces of Al to determine the variation of the surface energy as a function of deformation and temperature. We have also developed an empirical formulation for the surface free energy as a function of deformation. The observed difference between the numerical and analytical results has led us to divide the deformation into a mechanical and a thermal contribution. From this observation, we have obtained an expression for the surface free energy placing the temperature dependence on the bulk and surface elastic constants. Our simulations permitted us to analyze the multilayer relaxation for the particul…
Ceramique/metal component elaborated by flash sintering for ballistic protection
2012
This dissertation describes the synthesis of new components for ballistic protection with the assistance of flash sintering. Indeed, the objective is to associate two compounds showing very different sintering temperatures – such as alumina and aluminum, two reference materials for ballistic protection applications.The first synthesis method tested was the elaboration of a bi-material via the sintering of aluminump owder on alumina bulks. This study permitted to observe the formation of the alumina/aluminum bonding by scanning and transmission electron microscopy and to optimize the assembly parameters in order to obtain a bimaterials howing a strong interfacial cohesion. Adapted characteri…
Study of parameters endogeneous and exogeneous to ordinary Portland ciment influencing hydration of its main phase : tricalcium silicate
2012
This work devoted to study various parameters influencing hydration of silicate phase main Ordinary Portland Cement (OPC) was performed at the Laboratoire Interdisciplinaire Carnot de Bourgogne (ICB). This study is part of the project "Crystal Growth Control" initiated by BASF in order to monitor and provide the best as possible the hydration of Ordinary Portland Cement. The dissolution of alite, like the pure C3S one, is fast in pure water. Speed decreases with deviation from equilibrium and the concentration of aluminates ions in solution. There is also an adsorption on the surface of the aluminum which is into the alite and released by dissolution. Germination and growth of C-S-H has bee…
Etude expérimentale et modélisation thermodynamique du système CaO-SiO2-(Al2O3)-H2O
2012
The aim of this work is to build a thermodynamic model at 25°C to describe the main hydrates of ordinary Portland cement with or without supplementary cementitious materials (SCM) : calcium hydrosilicates. With high aluminium content, SCM in blended cements modify the nature and the composition of the hydrates of cement paste.The simplified model system CaO-SiO2-H2O was studied by synthesising of C-S-H with identical protocol and analysis. We distinguished, hydration solutions undersaturated and supersaturated from Portlandite.This last system has been extended to CaO-Al2O3-SiO2-H2O system. Then, we determined the most suitable protocol to synthesize pure C-A-S-H.The nanoparticular nature a…
Effect of fertilisation on the changes of soil pH and exchangeable aluminium content in soil
2015
W pracy oceniono stopień zakwaszenia gleby oraz zawartość glinu wymiennego w zależności od rodzaju zastosowanego nawozu mineralnego oraz jego dawki. Badania prowadzono w oparciu o doświadczenie wazonowe z jęczmieniem jarym odmiany browarniczej Propino. Uzyskane wyniki wskazują, że największe zakwaszenie oraz największe zawartości glinu wymiennego stwierdza się w warunkach stosowania nawożenia w kombinacji NPK wraz z saletrą amonową. Zastosowany w różnych dawkach siarczan wapnia dwuwodny nie wpłynął na zmianę odczynu gleby, a odnotowana zawartość glinu wymiennego była niższa niż w kombinacji NPK wraz z saletrą amonową.
Innovation by co-evolution in natural resource industries: The Norwegian experience
2011
Author's version of an article published in the journal: Geoforum. Also avaliable from the publisher at: http://dx.doi.org/10.1016/j.geoforum.2011.01.008 Some resource-based economies become wealthy while others stay poor and Norway belongs to the first category. This paper argues that part of the answer to why Norway has managed to benefit from its rich natural resources is found in the formation of a well-functioning national innovation system. The paper integrates the innovation system approach with a historical approach through the concept of co-evolution. The empirical study investigates how innovation systems evolve in natural resource industries through analysing the co-evolution bet…
Arene C‐H activation at aluminium(I) : meta selectivity driven by the electronics of SNAr chemistry
2020
The reactivity of the electron-rich anionic Al(I) (‘aluminyl’) compound K 2 [(NON)Al] 2 (NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di- tert -butyl-9,9-dimethylxanthene) towards mono- and disubstituted arenes is reported. C-H activation chemistry with n -butylbenzene gives exclusively the product of activation at the arene meta position. Mechanistically, this transformation proceeds in a single step via a concerted Meisenheimer-type transition state. Selectivity is therefore based on similar electronic factors to classical S N Ar chemistry, which implies the destabilization of transition states featuring electron-donating groups in either the ortho or the para positions. In the cases of tolu…
Cardiovascular, ventilatory and haematological responses of brown trout (Salmo trutta L.), to the combined effects of acidity and aluminium in humic …
1995
Two year old brown trout (Salmo trutta L.) were exposed for 7 days to pH 4.7 alone and with aluminium at concentrations of 0.28 and 0.45 mg l−1, respectively, in the water of River Rutajoki, Central Finland. The labile aluminium accounted for less than 30% of the total added amount in the humic water. During the exposures the fish were monitored by a non-contact bioelectronic monitoring system which records heart and ventilation rates of the fish. Terminal blood samples were obtained to evaluate the degree of stress. No mortality occurred during any of the exposures. Acid stress alone and with aluminium caused an immediate acute response in heart and ventilation rates, which remained higher…
Controlling the spatial distribution of aluminum in ZSM-5 crystals
1993
Abstract The spatial distribution of aluminum over ZSM-5 crystals was systematically studied using electron microprobing on polished crystals. Crystals synthesized with TPABr as template exhibit a pronounced enrichment of aluminum in the crystal rim, essentially irrespective of the aluminum source employed, although aluminum sources with organic anions are favoring less inhomogeneous profiles. With 1,6-hexanediol or from totally inorganic reaction gels, crystals with completely homogeneous aluminum profiles are obtained, even if the crystals grow larger than 50 μm. In the 1,6-hexanediol system the homogeneous profiles could be changed to profiles similar to the TPABr system by addition of K…