Search results for "Analytical"
showing 10 items of 9586 documents
Structure−Dynamics Coupling between Protein and External Matrix in Sucrose-Coated and in Trehalose-Coated MbCO: An FTIR Study
2004
We performed FTIR measurements on carboxy-myoglobin (MbCO) embedded in a sucrose−water matrix to study the degrees of freedom coupling between protein and external matrix in such a system. The work was undertaken on the light of recent results by Giuffrida et al. (J. Phys. Chem. B 2003, 107, 13211−13217), who evidenced, in trehalose-coated MbCO, a structured water−sugar environment of the protein, tightly coupled to the heme pocket structure. Such information was obtained through a suitable analysis of the temperature dependence of the CO stretching and of the water association bands in samples of different content of residual water. We applied here the same analysis to sucrose-coated MbCO.…
Recovery of aliphatic low-molecular-mass carboxylic acids from hardwood kraft black liquor
2015
Abstract During alkaline pulping of wood, substantial amounts of carbohydrates-derived aliphatic carboxylic acids (formic and acetic acids together with various hydroxy acids) are formed and dissolved into the cooking liquor (“black liquor”). These acids with low heating values are considered to be potential feedstocks for the chemical industry but, due to many factors, their straightforward recovery as free acids from black liquor (pH 13–14) is difficult. In this paper, we outlined the partial recovery of volatile formic and acetic acids from the acidified birch ( Betula pendula ) kraft black liquor (pH approximately 2.5) by distillation, and the partial recovery of significant low-molecul…
Dog behaviour classification with movement sensors placed on the harness and the collar
2021
Dog owners’ understanding of the daily behaviour of their dogs may be enhanced by movement measurements that can detect repeatable dog behaviour, such as levels of daily activity and rest as well as their changes. The aim of this study was to evaluate the performance of supervised machine learning methods utilising accelerometer and gyroscope data provided by wearable movement sensors in classification of seven typical dog activities in a semi-controlled test situation. Forty-five middle to large sized dogs participated in the study. Two sensor devices were attached to each dog, one on the back of the dog in a harness and one on the neck collar. Altogether 54 features were extracted from th…
Psychological and behavioural factors of unintentional doping: A preliminary systematic review
2018
In some cases, doping in sport is an intentional goal-directed behaviour, but research suggests that it might also occur accidentally when athletes inadvertently or unintentionally consume banned performance-enhancing drugs via food, supplements, or medication. Because research into the psychological factors of unintentional doping is still emerging, this paper aims to conduct a preliminary systematic review of all the existing literature concerning the psychology of unintentional doping in sport. The systematic review was carried out via an extensive search of Medline, PsycINFO, PsycTESTS, PsycARTICLES, and Web of Science, and reports from World Anti-Doping Agency. Among the 2110 articles …
Propulsion Calculated by Force and Displacement of Center of Mass in Treadmill Cross-Country Skiing
2022
This study evaluated two approaches for estimating the total propulsive force on a skier’s center of mass (COM) with double-poling (DP) and V2-skating (V2) skiing techniques. We also assessed the accuracy and the stability of each approach by changing the speed and the incline of the treadmill. A total of 10 cross-country skiers participated in this study. Force measurement bindings, pole force sensors, and an eight-camera Vicon system were used for data collection. The coefficient of multiple correlation (CMC) was calculated to evaluate the similarity between the force curves. Mean absolute force differences between the estimated values and the reference value were computed to evalua…
Thermal and Mechanical Characterization of Yarn Samples from Flemish Tapestry of the Sixteenth Century
2022
We propose a physico-chemical approach for theharacterization of the conservation condition of yarns from a Flemish tapestry of the sixteenth century. The aging effect on the yarns’ performance was evaluated by comparison with commercial materials. Water uptake experiments highlighted the aptitude of yarns toward water sorption and their increased hydrophilicity upon aging. Thermogravimetric analysis can be considered a fast approach for the fiber identification and assessment on the material life-time. The dynamic mechanical analysis provided direct evidence on the yarns, conservation state and their performance under different mechanical stresses. The proposed characterization path can be…
The dynamics of aroma release during consumption of candies of different structures, and relationship with temporal perception
2011
; We investigated the role of both candy texture and eating technique (melting or chewing) on the dynamics of aroma release. One novelty of this type of analysis was the simultaneous application of instrumental and sensory analysis. Four candy textures were established based on their storage modulus at 1 Hz by varying the gelatine content between 0 and 15% w/w. The in vivo release of three aroma compounds was monitored using Proton Transfer Reaction Mass Spectrometry and with a trained panel of testers. The gelatine content had no significant effect on the headspace/product partition and diffusion properties of the aroma compounds. The highest in vivo release for all aroma compounds was ob…
Minimal information for studies of extracellular vesicles 2018 (MISEV2018):a position statement of the International Society for Extracellular Vesicl…
2018
The last decade has seen a sharp increase in the number of scientific publications describing physiological and pathological functions of extracellular vesicles (EVs), a collective term covering various subtypes of cell-released, membranous structures, called exosomes, microvesicles, microparticles, ectosomes, oncosomes, apoptotic bodies, and many other names. However, specific issues arise when working with these entities, whose size and amount often make them difficult to obtain as relatively pure preparations, and to characterize properly. The International Society for Extracellular Vesicles (ISEV) proposed Minimal Information for Studies of Extracellular Vesicles ("MISEV") guidelines fo…
The determination of haemoglobin as cyanhaemiglobin or as alkaline haematin D-575. Comparison of method-related errors.
1989
In order to compare the accuracy of haemoglobin (Hb) determination methods, the commonly used cyanhaemiglobin (HiCN) method and the recently developed alkaline haematin D-575 (AHD) method (R. Zander, W. Lang & H. U. Wolf (1984) Clin. Chim. Acta 136, 83-93; H. U. Wolf, W. Lang & R. Zander (1984) Clin. Chim. Acta 136, 95-104) were tested with respect to method-related errors such as plasma, cell, and Hb errors. Both methods yield a series of more or less significant errors which generally lead to an overestimation of the Hb concentration in the order of 1%. However, in all three cases of plasma errors, i.e. normal plasma error, plasma error in lipaemic blood, and plasma error in bilirubinaemi…
Special Issue: Improvements for Resveratrol Efficacy
2017
International audience; Resveratrol is a well-known phenolic stilbene because of its presence in several edible plants and its proposed properties that are beneficial to human health [...].