Search results for "Andit"
showing 10 items of 89 documents
Enhanced Surface Ligands Reactivity of Metal Clusters by Bulky Ligands for Controlling Optical and Chiral Properties.
2021
Surface ligands play critical roles in determining the surface properties of metal clusters. However, modulating the properties and controlling the surface structure of clusters through surface‐capping agent displacement remain a challenge. In this work, a silver cluster, [Ag 14 (SPh(CF 3 ) 2 ) 12 (PPh 3 ) 4 (DMF) 4 ] ( Ag 14 ‐DMF , where HSPh(CF 3 ) 2 is 3,5‐bis(trifluoromethyl)benzenethiol, PPh 3 is triphenylphosphine and DMF is N,N‐Dimethylformamide), with weakly coordinated DMF ligands on the surface silver sites, was synthesized by using a mixed ligands strategy (bulky thiolates, phosphines and small solvents). The as‐prepared Ag 14 ‐DMF is a racemic mixture of chiral molecules. Owing …
Near surface seismostratigraphic modelling of the Bandita plain in Palermo town (Italy) from integra-ted analysis of HVSR and stratigraphic data
2016
The Horizontal to Vertical Spectral Ratio (HVSR) noise method (Nakamura, 1989) is nowadays widely used to estimate the resonance frequencies of geological structures (Bonnefoy-Claudet, 2006). However, often HVSR is also used to obtain information on the depth of the seismic bedrock and on thickness and seismic velocity of the process overburden deposits, using inversion techniques of the H/V curve (Fäh et al., 2003). This nevertheless produce results with large uncertainty intervals of parameters, and then must be necessarily constrained by detailed stratigraphic information. An application of HVSR inversion is presented in order to verify the effectiveness of this technique for purposes of…
Pliegos poéticos de bandoleros en la Cataluña del barroco. Un ejemplo de literatura propagandística
2018
En aquest estudi s’analitza la literatura popular de bandolers de la Catalunya del segle xvii. El bandolerisme sigué un fenomen important en les primeres dècades del barroc en el Principat i la seua repercussió arribà, de manera notable, a la literatura de cordell de l’època. Aquests plecs de cordell, que tenien la missió d’arribar a tots els públics, compten amb un nombre reduït d’estudis, si tenim en compte la seua importància. Per eixa raó, l’article analitza els dos principals moments històrics que propiciaren el major auge d’edició de plecs de bandolers en vers a Catalunya, com foren les signatures de les unions i dels agermanaments contra els bandolers (1606) i el sistema repressiu de…
An AI for dominion based on Monte-Carlo methods
2014
Masteroppgave i Informasjons- og kommunikasjonsteknologi IKT590 Universitetet i Agder 2014 To the best of our knowledge there exists no Arti_cial Intelligence (AI)for Dominion which uses Monte Carlo methods, that is competitive on ahuman level. This thesis presents such an AI, and tests it against someof the top Dominion strategies available. Although in a limited testingenvironment, the results show that our AI is capable of competing withhuman players, while keeping processing time per move at an acceptablelevel for human players. Although the approach for our AI is built onprevious knowledge about Upper Con_dence Bounds (UCB) and UCBapplied to Trees (UCT), an approach for handling the st…
Blocking Activin Receptor Ligands Is Not Sufficient to Rescue Cancer-Associated Gut Microbiota—A Role for Gut Microbial Flagellin in Colorectal Cance…
2019
Colorectal cancer (CRC) and cachexia are associated with the gut microbiota and microbial surface molecules. We characterized the CRC-associated microbiota and investigated whether cachexia affects the microbiota composition. Further, we examined the possible relationship between the microbial surface molecule flagellin and CRC. CRC cells (C26) were inoculated into mice. Activin receptor (ACVR) ligands were blocked, either before tumor formation or before and after, to increase muscle mass and prevent muscle loss. The effects of flagellin on C26-cells were studied in vitro. The occurrence of similar phenomena were studied in murine and human tumors. Cancer modulated the gut microbiota witho…
Toward Near-Infrared Emission in Pt(II)-Cyclometallated Compounds: From Excimers’ Formation to Aggregation-Induced Emission
2023
Two series of Pt(II)-cyclometallated compounds containing N^C^N tridentate and alkynyl-chromophore ligands have been synthesized and structurally characterized. The N^C^N ligands differ on the presence of R1 = H or F in the central aromatic ring, while six different chromophores have been introduced to the alkynyl moiety. Single-crystal X-ray structures for some of the compounds reveal the presence of weak intermolecular contacts responsible for the formation of some dimers or aggregates. The photophysical characterization shows the presence of two emission bands in solution assigned to the 3π–π* transition from the N^C^N ligands mixed with 3MLCT/3ILCT transitions (higher energy band) in de…
Utility of Three-Coordinate Silver Complexes Toward the Formation of Iodonium Ions
2021
The work herein describes the synthesis of five three-coordinate silver(I) complexes comprising a bidentate ligand L1, either bpy (2,2′-bipyridyl) or bpyMe2 (4,4′-dimethyl-2,2′-dipyridyl), and a monodentate ligand L2, either mtz (1-methyl-1H-1,2,3-triazole), 4-Etpy (4-ethylpyridine), or 4-DMAP (N,N-dimethylpyridin-4-amine). Upon reaction of the three-coordinate silver(I) complexes with 0.5 equiv of I2, the reactions quantitatively produce a 1:1 pair of complexes of a four-coordinate silver(I) complex [Ag(L1)2]PF6 and a two-coordinate iodonium complex [I(L2)2]PF6. The combination of [Ag(bpyMe2)2]PF6 and [I(4-DMAP)2]PF6 gave rise to an I+···Ag+ interaction where the I+ acts as a nucleophile, …
The influence of an ion-exchange resin on the kinetics of hydration of tricalcium silicate
2010
The addition of a finely-ground ion-exchange resin makes it possible to modify the hydration kinetics of C3S pastes. Analyses of the liquid phase in pastes and more dilute suspensions show that the resin exchanges calcium ions for sodium ions very rapidly during the early stage of hydration and therefore the concentration of silica in solution increases. The resin impacts the hydration of C3S by other mechanisms which depends on the resin quantity added. For a high resin quantity, the induction period is very short, but the longer-term hydration is enhanced compared to a reference sample without resin. We hypothesize that the surface of the resin can provide sites for the nucleation and gro…
Perfiles básicos del bandolerismo morisco valenciano: del desarme a la expulsión (1563-1609)
2009
espanolA la imagen del problema del bandolerismo morisco valenciano legada por Sebastian Garcia Martinez se contrapone en estas paginas una vision alternativa, basada en el empleo de dos fuentes principales: los libros de cuentas del Maestre Racional y las conclusiones criminales de la Real Audiencia. Dos son los aspectos fundamentales que se revisan: la geografia del fenomeno, a partir de la distincion entre los lugares de origen de los fuera de la ley y los escenarios donde perpetraron sus crimenes, y su evolucion desde 1563 hasta 1609, periodo a lo largo del cual pueden diferenciarse varias fases, tanto desde la perspectiva de la actividad delictiva, como desde la de la energia represiva…
Conformation and dynamics of the ligand shell of a water-soluble Au102 nanoparticle
2016
Inorganic nanoparticles, stabilized by a passivating layer of organic molecules, form a versatile class of nanostructured materials with potential applications in material chemistry, nanoscale physics, nanomedicine and structural biology. While the structure of the nanoparticle core is often known to atomic precision, gaining precise structural and dynamical information on the organic layer poses a major challenge. Here we report a full assignment of 1H and 13C NMR shifts to all ligands of a water-soluble, atomically precise, 102-atom gold nanoparticle stabilized by 44 para-mercaptobenzoic acid ligands in solution, by using a combination of multidimensional NMR methods, density functional t…