Search results for "Ang"
showing 10 items of 39486 documents
The Jäntti approach to adsorption with increasing gas pressure
2002
Jäntti introduced a method of calculating equilibrium adsorption from measurements where the pressure of the gas was varied in a stepwise manner. His aim was to shorten the time necessary for a given measurement. The method was applied to gas/solid systems in which simple adsorption processes occurred and where the number of adsorption sites was infinite. The present paper discusses the case where no adsorption is possible on an already occupied site (Langmuir isotherm) while the number of positions available for adsorption is considered limited. The advantages of using a gas pressure that increases linearly with time are evident for studies with this limitation. It is shown that such meas…
Assessing Transfer Entropy in cardiovascular and respiratory time series: A VARFI approach
2021
In the study of complex biomedical systems represented by multivariate stochastic processes, such as the cardiovascular and respiratory systems, an issue of great relevance is the description of the system dynamics spanning multiple temporal scales. Recently, the quantification of multiscale complexity based on linear parametric models, incorporating autoregressive coefficients and fractional integration, encompassing short term dynamics and long-range correlations, was extended to multivariate time series. Within this Vector AutoRegressive Fractionally Integrated (VARFI) framework formalized for Gaussian processes, in this work we propose to estimate the Transfer Entropy, or equivalently G…
Rotational collisional line broadening at high temperatures in the N2 fundamental Q-branch studied with stimulated Raman spectroscopy
1986
Self broadened N 2 Q-branch spectra are measured by high resolution stimulated Raman spectroscopy in the pressure region 0.25-1.9 atm. and in the temperature range 295-1310 K. Non additivity of the Q(J) components due to line overlap arising in the highest pressure range explored is carefully taken into account. Excellent fit of the whole spectra is thus obtained for each pressure with linearly density-dependent line widths. Semi-classical calculations of the line-broadening coefficients lead to consistent values with all the measured ones. These calculations are extended to higher J values and to higher temperatures (up to 2500 K). At last, a simple phenomenological model based on a polyno…
A Domain Imbedding Method with Distributed Lagrange Multipliers for Acoustic Scattering Problems
2003
The numerical computation of acoustic scattering by bounded twodimensional obstacles is considered. A domain imbedding method with Lagrange multipliers is introduced for the solution of the Helmholtz equation with a second-order absorbing boundary condition. Distributed Lagrange multipliers are used to enforce the Dirichlet boundary condition on the scatterer. The saddle-point problem arising from the conforming finite element discretization is iteratively solved by the GMRES method with a block triangular preconditioner. Numerical experiments are performed with a disc and a semi-open cavity as scatterers.
Beyond the spin model: exchange coupling in molecular magnets with unquenched orbital angular momenta.
2011
In this critical review we review the problem of exchange interactions in polynuclear metal complexes involving orbitally degenerate metal ions. The key feature of these systems is that, in general, they carry an unquenched orbital angular momentum that manifests itself in all their magnetic properties. Thus, interest in degenerate systems involves fundamental problems related to basic models in magnetism. In particular, the conventional Heisenberg-Dirac-Van Vleck model becomes inapplicable even as an approximation. In the first part we attempt to answer two key questions, namely which theoretical tools are to be used in the case of degeneracy, and how these tools can be employed. We demons…
Physics meets Bohemia Einstein in Bohemia Michael D. Gordin Princeton University Press, 2020. 360 pp.
2020
In Einstein in Bohemia, Michael Gordin seeks to illuminate the elusive significance of Einstein9s brief tenure in Prague, both for the biography of the famous physicist and for the cultural history of Bohemia. An expert in the history of modern physical sciences and of Russian, European, and American history, Gordin pulls together a wealth of information about the wider context of Einstein9s stay in Prague and of the cultural, scientific, and political history of Bohemia.
Modelling Systemic Cojumps with Hawkes Factor Models
2013
Instabilities in the price dynamics of a large number of financial assets are a clear sign of systemic events. By investigating a set of 20 high cap stocks traded at the Italian Stock Exchange, we find that there is a large number of high frequency cojumps. We show that the dynamics of these jumps is described neither by a multivariate Poisson nor by a multivariate Hawkes model. We introduce a Hawkes one factor model which is able to capture simultaneously the time clustering of jumps and the high synchronization of jumps across assets.
Stealth dicing with Bessel beams and beyond
2016
In the context of laser cutting of transparent materials, we investigate glass cleaving with Bessel beams and report that a modification of the beam with 3 main lobes drastically enhances cleavability and reduces defects.
Characteristics of Mesozoic fluvio-lacustrine formations of the western Central African Republic (Carnot Sandstones) by means of mineralogical and ex…
1990
Abstract The so-called Carnot Sandstones, Mesozoic fluvio-lacustrine detrital formation, which stretch over an area of more than 40 000 km 2 in the western part of the Central African Republic, are made of a succession of conglomerates, sandstones and argilites which can reach 300 m in thickness. Heavy mineral analyses and quartz exoscopic studies of this detrital material allow to understand the geology of these formations. The detrital material origin: heavy mineral distribution in the lower levels indicates mostly a meridional origin with a quantitatively poor peripheral supply. The importance of the transport: quartz exoscopic observations show that the main part of the detrital materia…
Second harmonic ac polarography of strongly adsorbed electroactive species
1981
Abstract The second harmonic ac current is calculated for the case of a quasi-reversible surface redox system: both species are strongly adsorbed according to a Langmuir isotherm and the kinetics of the process are controlled by the electron transfer. The current is measured with a phase-sensitive detector and the variation of the in-phase and quadrature components vs. the frequency leads to the surface rate constant ks. The experimental results obtained for benzo-(c)cinnoline are in good agreement with the theoretical predictions and with the results of impedance measurements. The advantages of the two methods are compared.