Search results for "Aramid"

Long-term moisture absorption and durability of FRP pultruded rebars

2021

Abstract Up to 15-years long moisture diffusion into carbon, glass, and aramid fiber reinforced plastic (FRP) rebars is studied. To eliminate uncertainties in identification of the radial and axial diffusivities, a successive methodology for determination of the diffusion coefficients is proposed. The concept of apparent diffusivity taking into account anisotropy and edge effects is extended to cylindrical samples. The ratio of the axial and radial diffusivities is the lowest for carbon (3) and the highest for glass (81) FRP rebars. Durability performance of the rebars is estimated by monitoring their interlaminar shear strength (ILSS). Long-term exposure of FRP rebars in a humid environmen…

Enantioselective synthesis of 4H-pyranonaphthoquinones via sequential squaramide and silver catalysis

2015

Chemical communications 52(8), 1669-1672(2016). doi:10.1039/C5CC09592A

Asymmetric Synthesis of Spiro β-Lactamsviaa Squaramide- Catalyzed Sulfa-Michael Addition/Desymmetrization Protocol

2016

An efficient asymmetric synthesis of spirocyclohexenone β-lactams bearing three contiguous stereocenters has been achieved in moderate to good yields and high stereoselectivities. The protocol involves the combination of a squaramide-catalyzed sulfa-Michael addition under desymmetrization via a dynamic kinetic resolution of racemic 2,5-cyclohexadienones.

Squaramide-Catalyzed Asymmetric aza-Friedel-Crafts/N,O-Acetalization Domino Reactions Between 2-Naphthols and Pyrazolinone Ketimines

2017

N-Boc ketimines derived from pyrazolin-5-ones were explored to develop an unprecedented domino aza-Friedel-Crafts/N,O-acetalization reaction with 2-naphthols. The novel method requires a catalyst loading of only 0.5 mol % of a bifunctional squaramide catalyst, is scalable to gram amounts, and provides a new series of furanonaphthopyrazolidinone derivatives bearing two vicinal tetra-substituted stereogenic centers in excellent yields (95-98 %) and stereoselectivity (>99:1 d.r. and 97-98 % ee). A different reactivity was observed in the case of 1-naphthols and other electron-rich phenols, which led to the aza-Friedel-Crafts adducts in 70-98 % yield and 47-98 % ee.

Water-Soluble Squaramide Dihydrates: N-Methylation Modulates the Occurrence of One- and Two-Dimensional Water Clusters through Hydrogen Bonding and D…

2018

Water confined in molecular size domains is distinct to bulk water. The altered interactions between adjacent water molecules, and between water molecules and molecular wall components of the confinement system, determine aspects of important phenomena in material science, biology, and nanotechnology. The structural determination of confined water, however, has proven to be challenging. Here, we describe the crystal structures of three related squaramides 1–3 whose molecular structures are modulated by the gradual incorporation of N-methyl groups to the squaramide moiety. The three squaramides differ in their hydrogen bonding capabilities due to the different degree of N-methylation of each…

Asymmetric Synthesis of Tetrahydrobenzofurans and Annulated Dihydropyrans via Cooperative One-Pot Organo- and Silver-Catalysis

2016

Synthesis : journal of synthetic organic chemistry 48(19), 3207-3216(2016). doi:10.1055/s-0035-1561468

ON THE EFFECTS OF A CRACK PROPAGATING TOWARD THE INTERFACE OF A BIMATERIAL SYSTEM

2006

This paper deals with the influence of matrix cracks on the failure mode of bimaterial systems and composite materials. In order to investigate such an influence, the stress field near a crack embedded into the more yielding material and propagating perpendicularly to the interface, has been analyzed by using systematic numerical simulations. Such analysis has shown that the crack propagation give rises to transversal stresses that can damage the reinforcing materials when this has low modulus, as glass fibers, or low transversal strength, such as carbon fibers. Moreover, the longitudinal stress concentration can damage the reinforcing material only if this has high stiffness, as in the cas…

Conformational Isomerism: Influence of the Z / E Isomerism on the Pathway Complexity of a Squaramide‐Based Macrocycle (Small 7/2021)

2021

Grafted squaramide monoamine nanoparticles as simple systems for sulfate recognition in pure water.

2012

New simple systems formed by a chain containing a squaramide function and a quaternised amine group attached to boehmite or silica-coated boehmite nanoparticles are able to discriminate anions in pure water.

One-Pot Synthesis and AFM Imaging of a Triangular Aramide Macrocycle

2014

Macrocyclizations in exceptionally good yields were observed during the self-condensation of N-benzylated phenyl p-aminobenzoates in the presence of LiHMDS to yield three-membered cyclic aramides that adopt a triangular shape. An ortho-alkyloxy side chain on the N-benzyl protecting group is necessary for the macrocyclization to occur. Linear polymers are formed exclusively in the absence of this Li-chelating group. A model that explains the lack of formation of other cyclic congeners and the demand for an N-(o-alkoxybenzyl) protecting group is providedon the basis of DFT calculations.High-resolution AFM imaging of the prepared molecular triangles on a calcite(10.4) surface shows individual …