Search results for "Arenes"

Calix[4]arene-functionalized naphthalene and perylene imide dyes.

2002

[reaction: see text] Calix[4]arenes bearing one, two, or four 1,8-naphthyl imide groups at the wide rim and bis-calix[4]arenes connected via perylene-bisimide dye spacers have been synthesized. The low-temperature NMR spectrum of the tetranaphthylimide suggests, in agreement with a crystal structure, a C2-symmetrical pinched cone conformation stabilized via face-to-face pi-pi interactions between opposite naphthylimide groups. UV-vis and fluorescence studies have been carried out for the perylene bis-calix[4]arene dyes.

Unusual conformations of 1,3-dialkoxythiacalix[4]arenes in the solid state

2006

The structures of three syn-1,3-dialkoxythiacalix[4]arenes with unusual conformations in the solid state are reported. The pinched cone conformation of syn-2 2 ,4 2 -dihydroxy-1 2 ,3 2 -bis-(prop-2-enyloxy)thiacalix[4]arene, C 30 H 24 O 4 S 4 , (3a), is stabilized by two intramolecular hydrogen bonds, remarkably formed from both OH groups to the same ether O atom. In syn-22,42-dihydroxy-1 5 ,2 5 ,3 5 ,4 5 -tetranitro-12,32-bis(prop-2-enyloxy)thiacalix[4]arene acetone disolvate, C 30 H 20 N 4 O 12 S 4 ·-2C 3 H 6 O, (3b1), the molecule is found in the 1,3-alternate conformation. The crystallographic C2 symmetry is due to a twofold rotation axis running through the centre of the calixarene rin…

Moral Conflicts as a Motor of Moral Identity Development at Work: Self-Awareness and Micro Processes in Weekly Experiences

2019

Based on the identity process model, we investigated developmental differences in moral identity between leaders by analyzing their personal experiences of and reactions to actual moral conflicts at work. Using a longitudinal (16-week) qualitative design, we collected weekly moral conflict stories from ten leaders. First, after an inductive exploratory analysis we found that the leaders showed different levels of awareness (descriptive, reflective, and evaluative) with regard to how far they were able to identify their own role, values, feelings, and behaviors in each moral conflict. Second, after a theory-driven analysis, the integrated model of the micro processes of identity development …

Convergence of voices: assimilation in linguistic therapy of evaluation.

2009

This paper shows the convergence of voices in psychotherapy in the context of the assimilation model. Convergence is the link between patients' voices within the community of voices. The main aim of the paper was to explore (a) how convergence (and divergence) is shown during sessions and the usefulness of convergence for the process of assimilation; (b) if a well-structured patient is able to track the sociohistorical antecedents of his/her main voices; and (c) if, at the end of the therapy, the self becomes richer and with more resources. For this aim to be realized, a case study of a patient, Maria, treated with linguistic therapy of evaluation for 14 sessions, was analysed by using the …

A possible approach for implementing self-awareness in JASON

2013

In Philosophy, the term awareness is often associated to theories of consciousness and self-referential behavior. In computer science, the awareness is a topic of increasing relevance in both Software Engineering and Artificial Intelligence, being closely related to autonomy and proactiveness.,We can distinguish two orders of awareness: the first order is the awareness of the environment also known as context-awareness; conversely, self-awareness is a higher order awareness (knowledge about one's own mental states).,Nowadays, many agent oriented languages offer native instruments to implement context-awareness. However, self-awareness is not adequately supported and it requires further cons…

Multihoming in the Market for Payment Media: Evidence from Young Finnish Consumers

2004

Tassa tutkimuksessa tarkastellaan sita, miksi jotkut kuluttajista kayttavat vain yhta maksuvalinetta ja toiset kuluttajat monia maksuvalineita maksaessaan paivittaisia ostoksiaan. Kayttamalla aineistoa nuorista suomalaisista kuluttajista loydamme, etta yksi tarkeimmista maksuvalineiden kayttoon vaikuttavista tekijoista on kuluttajien yleinen tietoisuus maksamiseen liittyvista kysymyksista. Instrumenttimuuttujaestimoinnit osoittavat, etta paremmin tietoiset kuluttajat kayttavat 1.2-1.3 kertaa useampaa maksuvalinetta kuin vahemman tietoiset kuluttajat. Koska monia uusia maksuvalineita kaytetaan usein aluksi olemassa olevien maksuvalineiden rinnalla, tuloksemme tukevat nakemysta, etta kuluttaj…

El terrorismo de la seguridad

2003

FFC-NMR Relaxometric Characterization of Nanosponges for Rationalizing their Adsorption and Release abilities

A circular economy: an analysis of the businesses awareness level in the Baltic Sea Region countries

2018

Circular economy is a model of production and consumption, which involves sharing, leasing, reusing, repairing, refurbishing and recycling existing materials and products as long as possible. In this way, the life cycle of products is extended. Unlike the traditional linear economic model based on a ‘take-make-consume-throw away’ pattern, a circular economy is based on the notion that all wastes can be considered as valuable resources in an almost closed loop, where products and the materials they contain are highly valued. In practice, it implies reducing waste to a minimum. Examination of the current knowledge and performance on resource efficiency and circular economy of industrial enter…

Shifting between cultural identities: The voice of preschool children

2018

 
 Aim. The purpose of this research is to capture the shift between two cultural identities, for a group of Romanian children enrolled in a German teaching preschool class, and to closely analyze the impact on cultural identity components.
 Methods. In this study 27 children, aged 3 to 6, were involved, together with their parents and two teachers. During one year of investigation, they were analyzed using participative observation, focus groups and in-depth interviews conducted in a public preschool.
 Results. The analysis reveals witch cultural identity components of this children undergo transformation, in what amount and with what impact considering the school environmen…