Search results for "Atmospheric temperature"
showing 10 items of 464 documents
Numerical Studies of the Diffusion Processes and First Step Oxidation in Nickel-Oxygen Systems by Variable Charge Molecular Dynamics
2010
Variable charge molecular dynamic simulations have been performed to study the diffusion mechanisms of oxygen atoms (O) in nickel (Ni) in the temperature range 950-1600 K and the very first steps of oxidation of monocrystalline nickel surfaces at 300 K and 950 K. The oxygen diffusivity can be well described by an Arrhenius law over the temperature range considered. The oxygen diffusion coefficient has been analysed and values of Ea = 1.99 eV for the activation energy and D0 = 39 cm2.s-1 for the pre-exponential factor were obtained. The first steps growth of the oxide layer show that after the dissociative chemisorption of the oxygen molecules on nickel surface, the oxidation leads to an isl…
Modeling polyethylene with the bond fluctuation model
1997
This work presents an application of recently developed ideas about how to map real polymer systems onto abstract models. In our case the abstract model is the bond fluctuation model with a Monte Carlo dynamics. We study the temperature dependence of chain dimensions and of the self-diffusion behavior in the melt from high temperatures down to 200 K. The chain conformations are equilibrated over the whole temperature range, which is possible for the abstract type of model we use. The size of the chains as measured by the characteristic ratio is within 25% of experimental data. The simulated values of the chain self-diffusion coefficient have to be matched to experimental information at one …
Cationic Mn12 Single-Molecule Magnets and Their Polyoxometalate Hybrid Salts
2003
A carboxy-substituted alkylammonium salt, namely, (4-carboxybenzyl)tributylammonium hexafluorophosphate, ZHPF(6), was prepared and used as incoming carboxylate ligand in a ligand-exchange reaction with [Mn(12)O(12)(O(2)CCH(3))(16)(H(2)O)(4)] (1) to afford a new Mn(12) single-molecule magnet (SMM), [Mn(12)O(12)(Z)(16)(H(2)O)(4)][PF(6)](16) (2), bearing 16 cationic units appended in the periphery. This compound behaves as a single-molecule magnet, exhibiting an out-of-phase ac magnetic susceptibility chi' '(M) signal that shows a single maximum in the 3.1-5.4 K temperature range. The frequency dependence of the maximum follows an Arrhenius law, with an effective energy barrier for reorientati…
Description of atmospheric conditions at the Pierre Auger Observatory using the Global Data Assimilation System (GDAS)
2012
Atmospheric conditions at the site of a cosmic ray observatory must be known for reconstructing observed extensive air showers. The Global Data Assimilation System (GDAS) is a global atmospheric model predicated on meteorological measurements and numerical weather predictions. GDAS provides altitude-dependent profiles of the main state variables of the atmosphere like temperature, pressure, and humidity. The original data and their application to the air shower reconstruction of the Pierre Auger Observatory are described. By comparisons with radiosonde and weather station measurements obtained on-site in Malargüe and averaged monthly models, the utility of the GDAS data is shown.
Canopy directional emissivity: Comparison between models
2005
Land surface temperature plays an important role in many environmental studies, as for example the estimation of heat fluxes and evapotranspiration. In order to obtain accurate values of land surface temperature, atmospheric, emissivity and angular effects should be corrected. This paper focuses on the analysis of the angular variation of canopy emissivity, which is an important variable that has to be known to correct surface radiances and obtain surface temperatures. Emissivity is also involved in the atmospheric corrections since it appears in the reflected downwelling atmospheric term. For this purpose, five different methods for simulating directional canopy emissivity have been analyz…
A comprehensive laboratory study on the immersion freezing behavior of illite NX particles: a comparison of 17 ice nucleation measurement techniques
2015
Immersion freezing is the most relevant heterogeneous ice nucleation mechanism through which ice crystals are formed in mixed-phase clouds. In recent years, an increasing number of laboratory experiments utilizing a variety of instruments have examined immersion freezing activity of atmospherically relevant ice-nucleating particles. However, an intercomparison of these laboratory results is a difficult task because investigators have used different ice nucleation (IN) measurement methods to produce these results. A remaining challenge is to explore the sensitivity and accuracy of these techniques and to understand how the IN results are potentially influenced or biased by experimental param…
Particle surface area dependence of mineral dust in immersion freezing mode: investigations with freely suspended drops in an acoustic levitator and …
2014
Abstract. The heterogeneous freezing temperatures of supercooled drops were measured using an acoustic levitator. This technique allows one to freely suspend single drops in the air without any wall contact. Heterogeneous nucleation by two types of illite (illite IMt1 and illite NX) and a montmorillonite sample was investigated in the immersion mode. Drops of 1 mm in radius were monitored by a video camera while cooled down to −28 °C to simulate freezing within the tropospheric temperature range. The surface temperature of the drops was contact-free, determined with an infrared thermometer; the onset of freezing was indicated by a sudden increase of the drop surface temperature. For compari…
Climatology of convective density currents in the southern foothills of the Atlas Mountains
2010
Density currents fed by evaporationally cooled air are an important dust storm generating feature and can constitute a source of moisture in arid regions. Recently, the existence of such systems has been demonstrated for the area between the High Atlas Mountains and the Sahara desert in southern Morocco on the basis of case studies. Here, a climatological analysis is presented that uses data from the dense climate station network of the IMPETUS project (An Integrated Approach to the Efficient Management of Scarce Water Resources in West Africa) for the 5 year period 20022006. Objective criteria mainly based upon abrupt changes in wind and dew point temperature are defined to identify possib…
Daily air temperature and electricity load in Spain
2001
Abstract Weather has a significant impact on different sectors of the economy. One of the most sensitive is the electricity market, because power demand is linked to several weather variables, mainly the air temperature. This work analyzes the relationship between electricity load and daily air temperature in Spain, using a population-weighted temperature index. The electricity demand shows a significant trend due to socioeconomic factors, in addition to daily and monthly seasonal effects that have been taken into account to isolate the weather influence on electricity load. The results indicate that the relationship is nonlinear, showing a “comfort interval” of ±3°C around 18°C and two sat…
A generalized single‐channel method for retrieving land surface temperature from remote sensing data
2003
[1] Many papers have developed algorithms to retrieve land surface temperature from at-sensor and land surface emissivity data. These algorithms have been specified for different thermal sensors on board satellites, i.e., the algorithm used for one thermal sensor (or a combination of thermal sensors) cannot be used for other thermal sensor. The main goal of this paper is to propose a generalized single-channel algorithm that only uses the total atmospheric water vapour content and the channel effective wavelength (assuming that emissivity is known), and can be applied to thermal sensors characterized with a FWHM (Full-Width Half-Maximum) of around 1 μm actually operative on board satellites…