Search results for "Autoionization"

showing 4 items of 14 documents

Rydberg and autoionizing states of tellurium studied by laser resonance ionization spectroscopy

2019

Multistep laser-resonance-ionization spectroscopy of tellurium (Te) has been performed at TRIUMF's off-line laser ion source test stand. Six clean and regular even-parity Rydberg series $5{p}^{3}$ $({^{4}S}_{3/2}^{\ensuremath{\circ}})$ $np\phantom{\rule{4pt}{0ex}}^{3}P_{0,1,2}$, $np\phantom{\rule{4pt}{0ex}}^{5}P_{1,2}$, and $nf\phantom{\rule{4pt}{0ex}}^{3}F_{2}/^{5}F_{1,2}$ were observed. The ionization potential of Te was extracted from the measured series as $72669.114{(56)}_{\mathrm{stat}}{(45)}_{\mathrm{sys}}\phantom{\rule{4pt}{0ex}}{\mathrm{cm}}^{\ensuremath{-}1}$. Excited from two different intermediate levels, seven odd-parity autoionization Rydberg series converging to the $5{s}^{2}…

Physicschemistry.chemical_element01 natural sciences3. Good health010305 fluids & plasmassymbols.namesakechemistryAutoionizationExcited stateIonization0103 physical sciencesRydberg formulasymbolsLaser resonanceAtomic physicsIonization energy010306 general physicsSpectroscopyTelluriumPhysical Review A
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Total angular momenta of even-parity autoionizing levels and odd-parity high-lying levels of atomic uranium

2002

Using three-step resonance ionization spectroscopy, over 200 even-parity autoionizing (AI) levels of atomic uranium, including Rydberg series converging to the second lowest ionic level (6L 11/2o), were observed in the 49 930–51 200 cm−1 energy range. Total angular momenta (J values) of these levels were determined by a polarization combination method as well as a method based on the J-momentum selection rule. Using the AI levels of which J values were determined unambiguously, unique J values were also assigned for about 70 high-lying odd-parity levels. The observed J-dependence on autoionization linewidth is interpreted as being due to a centrifugal potential barrier.

Physicschemistry.chemical_elementIonic bondingUraniumCondensed Matter PhysicsPolarization (waves)Atomic and Molecular Physics and OpticsLaser linewidthsymbols.namesakeAutoionizationchemistryRydberg formulasymbolsRectangular potential barrierPhysics::Atomic PhysicsAtomic physicsSpectroscopyJournal of Physics B: Atomic, Molecular and Optical Physics
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Quantum Control in Atomic Systems

1999

We review a series of recent experiments demonstrating quantum control of atomic processes and products induced by the interaction of the atom with coherent bichromatic electromagnetic fields. Since the effects under consideration are electromagnetically induced, control is established through the field parameters i.e. frequency, amplitude and phase. The controlled processes include resonant and non resonant multiphoton ionization, autoionization, radiative decay in multiple continua (ionization branching ratios) and third harmonic generation.

Quantum technologyElectromagnetic fieldPhysicsOpen quantum systemAutoionizationIonizationQuantum sensorPhysics::Atomic and Molecular ClustersQuantum simulatorHigh harmonic generationPhysics::Atomic PhysicsAtomic physics
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Interpretation of absorption edges by resonant electronic spectroscopy: experiment and theory

2004

Abstract Resonant electronic spectroscopy consists in measuring a non-radiative decay process (Auger or autoionization process) excited with photon energies around an absorption edge. The resonant spectra carry information both on the nature of the electronic transitions near the absorption edge by scanning the very first empty orbitals above the Fermi level (through the absorption process), and, on the other hand, on the atomic electronic configuration through the lineshape of the observed decay process. In this paper, after a quick review of the pioneering works in this field, we show that resonant measurements and their theoretical modeling can be used to precisely interpret complex abso…

RadiationAbsorption spectroscopyChemistryFermi levelCondensed Matter PhysicsElectron spectroscopyAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsResonant inelastic X-ray scatteringsymbols.namesakeAutoionizationAbsorption edgesymbolsPhysical and Theoretical ChemistryAtomic physicsSpectroscopyAbsorption (electromagnetic radiation)SpectroscopyJournal of Electron Spectroscopy and Related Phenomena
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