Search results for "BAND"
showing 10 items of 2610 documents
Electronic exchanges between adsorbed Ni atoms and TiO2(110) surface evidenced by resonant photoemission
2011
Abstract Nickel was deposited on stoichiometric TiO2(1 1 0) surface in the 0.02–2.1 equivalent monolayer (eqML) range and analyzed by means of photoemission and resonant photoemission. In the case of very low coverage (lower than 0.1 eqML), deposited nickel reacts with the surface through an electronic transfer from nickel atoms towards titanium ions. This exchange caused the filling of unoccupied Ti3d states leading to the increase of a peak in the TiO2 band gap. These states can be better characterized through resonant photoemission experiments at the Ti 3p → 3d absorption edge: for very low coverage, these states in the TiO2 band gap have resonant behavior of Ti3d electrons rather than N…
The CoSMOS L-band experiment in Southeast Australia
2007
The CoSMOS (Campaign for validating the Operation of the Soil Moisture and Ocean Salinity mission) campaign was conducted during November of 2005 in the Goulburn River Catchment, in SE Australia. The main objective of CoSMOS was to obtain a series of L-band measurements from the air in order to validate the L-band emission model that will be used by the SMOS (Soil Moisture and Ocean Salinity) ground segment processor. In addition, the campaign was designed to investigate open questions including the Sun-glint effect over land, the application of polarimetric measurements over land, and to clarify the importance of dew and interception for soil moisture retrievals. This paper summarises the …
Exploring single polarization X-band weather radar potentials for local meteorological and hydrological applications
2015
Summary The aim of this study is to evaluate the potential use of a low-cost single polarization X-band weather radar, verified by a disdrometer and a dense rain gauge network, installed as a supporting tool for hydrological applications and for monitoring the urban area of Palermo (Italy). Moreover, this study focuses on studying the temporal variability of the Z–R relation for Mediterranean areas. The radar device is provided with an automatic operational ground-clutter filter developed by the producer. Attention has been paid to the development of blending procedures between radar measurements and other auxiliary instruments and to their suitability for both meteorological and hydrologic…
Use of machine learning approaches to improve non-invasive skin melanoma diagnostic method in spectral range 450 - 950nm
2020
Non-invasive skin cancer diagnostic methods develop rapidly thanks to Deep Learning and Convolutional Neural Networks (CNN). Currently, two types of diagnostics are popular: (a) using single image taken under white illumination and (b) using multiple images taken in narrow spectral bands. The first method is easier to implement, but it is limited in accuracy. The second method is more sensitive, because it is possible to use illumination considering the absorption bands of the skin chromophores and the optical properties of the skin. Currently CNN use a single white light image, due to the availability of large datasets with lesion images. Since CNN processing and analysis requires a large …
Absorption band at 7.6 eV induced by γ-irradiation in silica glasses
2001
Optical absorption of defects induced by γ-irradiation in both natural and synthetic silica is experimentally investigated in the vacuum-ultraviolet (UV) range. Our results show that γ-rays, in a dose range of 1000 Mrad, induce an absorption band centered at 7.6 eV, the so-called E band, whose growth kinetics is not related to γ-activated precursors but to defects of the glassy matrix directly induced via the breaking of Si–O bonds occurring under γ-irradiation. Moreover, we observe that γ-rays do not bleach the E band present in some silica samples before irradiation, so ruling out that the associated defects can be precursors of the paramagnetic E′ centers, also induced by γ-irradiation.
First-principles simulations of the electronic density of states for superionic Ag2CdI4 crystals
2011
Abstract Energy band dispersion calculations have been performed for Ag 2 CdI 4 superionic within a framework of local density approximation (Perdew–Zunger parameterization) exploiting the first-principles CASTEP computer code. The ab-initio electronic structure simulations were performed for both ( I 4 and I 42 m ) types of e -Ag 2 CdI 4 crystalline structures. Principal optical functions as well as the density of electronic states in the spectral range of inter-band optical transitions (2.5 eV–20 eV) were determined. Theoretically calculated absorption coefficients derived from the obtained band structure are compared with appropriate experimental data.
The correlation of the 7.6 eV optical absorption band in pure fused silicon dioxide with twofold-coordinated silicon
1992
Abstract The optical absorption band at 7.6 eV, which appears in oxygen deficient pure silica, does not correlate with any ESR signal in non-irradiated samples. Longlasting illumination at 80 K in the range of its absorption leads to an increase of the absorption band at 5 eV. Subsequent heating to 290 K restores the initial absorption. These data can be explained as photodissociation and thermal recreation of a complex defect containing a twofold-coordinated silicon defect. This complex defect is responsible for the 7.6 eV absorption band.
Molecular dynamics in low-molar and polymeric ferroelectric liquid crystals
1991
Broadband dielectric spectroscopy covering the frequency range from 10−1 Hz to 109 Hz was employed to study the molecular dynamics in low-molar and polymeric ferrroelectric liquid crystals. At frequencies below 106 Hz the ferroelectric modes, soft and Goldstone mode are observed. In the frequency regime from 106 Hz to 109 Hz a fast relaxation process is found, which is assigned to the hindered rotation of the mesogens around their long molecular axis. It turns out that the molecular dynamics is not principally different between low-molar and polymeric systems.
Raman Spectroscopy and Low-Temperature Transport Measurements of Individual Single-Walled Carbon Nanotubes with Varying Thickness
2009
We have investigated two metallic and one semiconducting individual single-walled carbon nanotubes (SWNT) and one bundle of two semiconducting nanotubes with a diameter range 1.1−2.9 nm with Raman spectroscopy and low-temperature electric transport measurements. With these two methods, we obtain mutually independent measurements on the basic properties of a specific nanotube. In particular, we obtain data on metallic and semiconducting properties. Evidence of a small band gap for one metallic tube was obtained. For the semiconducting SWNTs with diameters of 2.7−2.9 nm, a special resonance condition was observed which causes an anomalous intensity ratio for the two components of the G-band. …
Luminescence of γ-radiation-induced defects in α-quartz
2004
Optical transitions associated with γ-radiation-induced defects in crystalline α-quartz were investigated by photoluminescence excited by both pulsed synchrotron radiation and steady-state light. After a 10 MGy γ-dose we observed two emissions at 4.9 eV (ultraviolet band) and 2.7 eV (blue band) excitable in the range of the induced absorption band at 7.6 eV. These two luminescence bands show a different temperature dependence: the ultraviolet band becomes bright below 80 K; the blue band increases below 180 K, but drops down below 80 K. Both emissions decay in a timescale of a few ns under pulsed excitation, however the blue band could also be observed in slow recombination processes and it…