Search results for "BAND"
showing 10 items of 2610 documents
Effects induced by 4.7 eV UV laser irradiation on pure silica core multimode optical fibers investigated by in situ optical absorption measurements
2011
We investigated by in situ optical absorption measurements the effects induced by 4.7 eV UV laser irradiation on pure silica core optical fibers. Laser irradiation with 100 MWcm−2 laser intensity generates in the fiber E′ centers which partially decay after irradiation due to their reaction with diffusing H2. An absorption band peaked at 5.3 eV is observed to grow in the post-irradiation stage with a kinetics anti-correlated to the decay of the 5.8 eV band of the E′ centers. The defect absorbing at 5.3 eV is proposed to be formed by trapping on pre-existing precursors of hydrogen atoms made available by breaking of H2 on E′.We also show by repeated irradiation experiments that the 5.3 eV-ab…
Pd–Pt alloys: correlation between electronic structure and hydrogenation properties
2001
Abstract Palladium and its alloys have been extensively studied because of their faculty to store reversibly hydrogen isotopes. Here, the substitution of palladium with platinum is investigated. Thermodynamical studies have shown an anomalous behaviour regarding to the classical models. This original behaviour is explained by the study of the electronic structure of the binary solid solutions. The drastic decrease of the hydrogen solubility in the Pd–Pt alloys is accounted for by the filling up of the palladium conduction band by the valence electrons of platinum. The anomalous decrease of the stability of the hydride is explained by the large broadening of the valence band due to the subst…
Application of 61Ni Mössbauer spectroscopy to chemical problems
1996
Using the possibility to produce 61Co sources at the MAinz MIcrotron, 61Ni Mossbauer spectroscopy was applied to different kinds of chemical problems. Measurements of isomer shifts and V zz values in some common compounds and compounds with unusual chemical bonding for comparison with band structure calculations, measurement of 61Ni Mossbauer parameters in model compounds for hydrogenase and dehydrogenase with an active [NiS4] centre, and study of novel binary NiF3 compounds at helium temperature are presented.
Mapping burns and natural reforestation using thematic Mapper data
1991
Abstract Remote sensing techniques are specially suitable to detect and to map areas affected by forest fires. In this work, Landsat 5 Thematic Mapper (TM) data has been used to study a number of forest fires that occurred in the province of Valencia (Spain) and to monitor the vegetation regeneration over burnt areas. A reference area (non‐burnt forest) was established to assess the change produced by fire. The radiance in the thermal band (10.4–12.5 μm) and the normalized difference in reflectance between near 1R (0.76–0.90 μm) and middle IR (2.08–2.35 μm) were the most suitable parameters to map burnt areas. This index can also be used for monitoring vegetation regeneration in burnt areas…
New Internal-Charge-Transfer Second-Order Nonlinear Optical Chromophores Based on the Donor Ferrocenylpyrazole Moiety
2016
A series of new N-arylated ferrocenepyrazole structures, carrying different donor or acceptor substituents in the para position of the aryl ring, has been synthesized by the Chan-Lam cross-coupling reaction. The nonplanar geometric molecular structure of some of these chromophores together with their crystal packing was determined by X-ray diffraction, and the HOMO and LUMO energy levels were evaluated by electrochemical and optical measurements and by density functional theoretical (DFT) calculations. By the investigation of solvent effects and time-dependent DFT (TD-DFT) calculations, the intense electronic absorption band around 270-310 nm was confirmed to be an internal-chargetransfer (…
Engineering the hypersonic phononic band gap of hybrid Bragg stacks.
2012
We report on the full control of phononic band diagrams for periodic stacks of alternating layers of poly(methyl methacrylate) and porous silica combining Brillouin light scattering spectroscopy and theoretical calculations. These structures exhibit large and robust on-axis band gaps determined by the longitudinal sound velocities, densities, and spacing ratio. A facile tuning of the gap width is realized at oblique incidence utilizing the vector nature of the elastic wave propagation. Off-axis propagation involves sagittal waves in the individual layers, allowing access to shear moduli at nanoscale. The full theoretical description discerns the most important features of the hypersonic one…
Scheduling solution for the IEEE 802.16 base station
2008
The IEEE 802.16 standard defines a wireless broadband access network technology called WiMAX. It introduces several advantages, one of which is the support for QoS at the MAC level. To ensure meeting the QoS requirements, the 802.16 base station must run some algorithm to allocate slots between connections. This algorithm is not defined in the 802.16 specification but rather is open for alternative implementations. We propose a simple, yet efficient, solution that is capable of allocating slots based on the QoS requirements, bandwidth request sizes, and the 802.16 network parameters. To test the proposed solution, we have implemented the 802.16 MAC and PHY layers in the NS-2 simulator. Seve…
Analysis of duplexing modes in the IEEE 802.16 wireless system
2010
The IEEE 802.16 standard defines two main duplexing modes: Time Division Duplexing (TDD) and Frequency Division Duplexing (FDD). The FDD can be divided further into Full-FDD (F-FDD) and Half-FDD (H-FDD). F-FDD requires full duplexing support from subscriber stations and works with two frequency bands. TDD operates a single frequency band, but it does not need full-duplexing support. H-FDD is a combination of these: it works with two frequency bands and does not require full-duplexing support. The cost of this is a more complicated scheduling and added overhead. Still, H-FDD might be the only possible duplexing mode in some occasions. In this paper, these duplexing modes are compared and the…
Adaptive Contention Resolution for VoIP Services in the IEEE 802.16 Networks
2007
In the IEEE 802.16 networks, a subscriber station can use the contention slots to send bandwidth requests to the base station. The contention resolution mechanism is controlled by the backoff start/end values and a number of the request transmission opportunities. These parameters are set by the base station and are announced to subscriber stations in the management messages. In the case of the VoIP services, it is critical that the contention resolution occurs within the specified time interval to meet the VoIP QoS requirements. Thus, it is the responsibility of the base station to set correct contention resolution parameters to ensure the QoS requirements. This paper presents analytical c…
Adaptive contention resolution parameters for the IEEE 802.16 networks
2007
In the IEEE 802.16 networks, the base station allocates resources to subscriber stations based on their QoS requirements and bandwidth request sizes. A subscriber station can send a bandwidth request when it has an uplink grant allocated by the base station or by taking part in the contention resolution mechanism. This paper presents analytical calculations for parameters that control the contention resolution process in the IEEE 802.16 networks. In particular, the backoff start/end values and the number of request transmission opportunities are considered. The simulation results confirm the correctness of theoretical calculations. They also reveal that the adaptive parameter tuning results…