Search results for "BUBBLE"
showing 10 items of 167 documents
ChemInform Abstract: Bubble Fractionation of Enantiomers from Solution Using Molecularly Imprinted Polymers as Collectors.
2010
Adsorptive bubble separation methods have been used to enrich components from both heterogeneous and homogeneous solutions. These methods are particularly effective for processing large solution volumes at low cost. Previous work demonstrated that chiral, surface-active collectors could be used to enrich enantiomers from homogeneous solution in a foam fractionation process. In a significant extension of this work, the use of highly selective molecularly imprinted polymers (MIPs) and heterogeneous solutions for the bubble flotation of enantiomers was evaluated. The high selectivity and ease of recycling of the MIP make this a potentially powerful approach for process-scale separations from l…
Bubble fractionation of enantiomers from solution using molecularly imprinted polymers as collectors.
1998
Adsorptive bubble separation methods have been used to enrich components from both heterogeneous and homogeneous solutions. These methods are particularly effective for processing large solution volumes at low cost. Previous work demonstrated that chiral, surface-active collectors could be used to enrich enantiomers from homogeneous solution in a foam fractionation process. In a significant extension of this work, the use of highly selective molecularly imprinted polymers (MIPs) and heterogeneous solutions for the bubble flotation of enantiomers was evaluated. The high selectivity and ease of recycling of the MIP make this a potentially powerful approach for process-scale separations from l…
On the measurement of bubble size distribution in gas–liquid contactors via light sheet and image analysis
2010
Abstract Particle image velocimetry techniques coupled with advanced image processing tools are receiving an increasing interest for measuring flow quantities and local bubble-size distributions in gas–liquid mechanically agitated vessels. When trying to analyze image information the problem arises that bubble sizes are generally underestimated, due to the fact that the laser sheet used for lighting the system randomly cuts bubbles over non-diametrical planes, leading to an apparent bubble size distribution even in the ideal case of single sized bubbles. Clearly in the case of bubbles with a size distribution the experimental information obtained is affected by the superposition of effects.…
Post-fragmentation vesiculation timescales in hydrous rhyolitic bombs from Chaitén volcano
2020
Abstract Bubble nucleation and growth dynamics exert a primary control on the explosivity of volcanic eruptions. Numerous theoretical and experimental studies aim to capture the complex process of melt vesiculation, whereas textural studies use vesicle populations to reconstruct magma behaviour. However, post-fragmentation vesiculation in rhyolitic bombs can create final quenched bubble (vesicle) textures that are not representative of the nature of fragmenting magma within the conduit. To examine bubble growth in hydrous rhyolitic bombs, we have used heated stage microscopy to directly observe vesiculation of a Chaiten rhyolite melt (with an initial dissolved water content of ~0.95 wt %) a…
Experimental analysis of bubble size distributions in 2D gas fluidized beds
2010
Abstract The present work focuses on the development of a novel statistical approach for the analysis of the behavior of a 2D fluidized bed operating under bubbling and slugging conditions. Experimental data were collected by means of a purposely built lab-scale 2D fluidized bed and an original digital image analysis technique (DIAT), allowing the acquisition of a number of data sufficient to perform a statistical analysis of bubble dynamics. In particular, measurements of bubble size distributions (BSD) along the bed were performed. The analysis allowed to characterize the shape of BSD for different particle systems and fluidization gas velocities; interestingly a bimodal shape of BSD is o…
An expansion–coalescence model to track gas bubble populations in magmas
2016
Abstract We propose a kinetic model that statistically describes the growth by decompression, exsolution and coalescence of a polydisperse population of gas bubbles in a silicate melt. The model is homogeneous in space and its main variable is a distribution function representing the probability to find a bubble of volume v and mass m at time t. The volume and mass growth rates are described by a simplification of the classical monodisperse bubble growth model. This simplification, which shortens computational time, removes the coupling between mass evolution and an advection–diffusion equation describing the behavior of the volatile concentration in the melt. We formulate three coalescence…
2017
Strombolian volcanism is a ubiquitous form of activity, driven by the ascent and bursting of bubbles of slug morphology. Whilst considerable attention has been devoted to understanding the behaviour of individual slugs in this regime, relatively little is known about how inter-slug interactions modify flow conditions. Recently, we reported on high temporal frequency strombolian activity on Etna, in which the larger erupted slug masses were followed by longer intervals before the following explosion than the smaller bursts (Pering et al., 2015). We hypothesised that this behaviour arose from the coalescence of ascending slugs causing a prolonged lag before arrival of the next distinct bubble…
Probing Physical Properties of Confined Fluids within Individual Nanobubbles
2008
Spatially resolved electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM) has been used to investigate as fluidic phase in nanoubbles embedded in a metallic Pd90Pt10 matrix. Using the 1s->2p excitation of the He atoms, maps of the He distribution, in particular of its density an pressure in bubbles of different diameter have been realized, thus providing an indication of the involved bubble formation mechanism. However, the short-range Pauli repulsion mechanism between electrons on neighboring atoms seems insufficient to interpret minute variations of the local local measurements performed at the interface between the metal and the He bubble. Simul…
Theory of warm ionized gases: Equation of state and kinetic Schottky anomaly
2013
Based on accurate Lennard-Jones type interaction potentials, we derive a closed set of state equations for the description of warm atomic gases in the presence of ionization processes. The specific heat is predicted to exhibit peaks in correspondence to single and multiple ionizations. Such kinetic analogue in atomic gases of the Schottky anomaly in solids is enhanced at intermediate and low atomic densities. The case of adiabatic compression of noble gases is analyzed in detail and the implications on sonoluminescence are discussed. In particular, the predicted plasma electron density in a sonoluminescent bubble turns out to be in good agreement with the value measured in recent experiment…
Direct measurement of forces between particles and bubbles
1999
One of the elementary stages of the flotation process is the formation of an aggregate between the particle and a bubble. This aggregate formation is governed by hydrodynamic, capillary and interparticle forces. During the last four years, techniques have been developed to measure directly the force between a colloidal particle and a bubble. These techniques are closely related to the development of atomic force microscopy. Advantages and possibilities, as well as limits and drawbacks are described.