Search results for "Biomassa"

Simultaneous production of furfural and levulinic acid from pine sawdust via acid-catalysed mechanical depolymerization and microwave irradiation

2019

In this work pine sawdust was converted into levulinic acid (LA) and furfural. Sawdust was first pre-treated with sulfuric acid-catalysed mechanical depolymerization. The conversion reactions were then performed with microwave heating at 180 °C. To enhance the furfural yield and the efficient separation of furfural and LA, a biphasic water-toluene reaction system was used. The effect of an additional catalyst, AlCl3, on the yield of LA and furfural was also studied. According to the results the pre-treatment method enhanced the yields of LA. In addition, due to the microwave heating the reaction times were short. Additional AlCl3 catalyst enhanced the LA yield, however excellent furfural yi…

Study of Ni, Pt, and Ru Catalysts on Wood-based Activated Carbon Supports and their Activity in Furfural Conversion to 2-Methylfuran

2018

Bio‐based chemicals can be produced from furfural through hydrotreatment. In this study, 2‐methylfuran (MF), a potential biofuel component, was produced with Pt, Ru, and Ni catalysts supported on wood‐based activated carbons. The catalytic hydrotreatment experiments were conducted in a batch reactor at 210–240 °C with 2‐propanol as solvent and 40 bar H2 pressure. Two types of activated carbon supports were prepared by carbonization and activation of lignocellulosic biomass (forest‐residue‐based birch and spruce from Finland). Both types of activated carbons were suitable as catalyst supports, giving up to 100 % furfural conversions. The most important factors affecting the MF yield were the…

Carbons from second generation biomass as sustainable supports for catalytic systems

2018

In this study activated carbons were produced from the wood of three different wood species (pine, birch, spruce). The resulting activated carbons were characterized in bulk for ash content, carbon content (elemental analyses), specific surface area, and pore size distribution, and at the surface by measuring the autogenerated pH and studying their structure by XPS. All the samples presented high surface areas and appeared to be mesoporous materials (mesopores >80%). The carbons were then used as support for AuPt nanoparticles and tested in the liquid phase oxidation of glycerol (GLY) and in the hydrogenation of levulinic acid (LA), two important chemicals from cellulose-based biomass. The …

Toxicological and bioactivity evaluation of blackcurrant press cake, sea buckthorn leaves and bark from Scots pine and Norway spruce extracts under a…

2021

Aqueous extracts from blackcurrant press cake (BC), Norway spruce bark (NS), Scots pine bark (SP), and sea buckthorn leaves (SB) were obtained using maceration and pressurized hot water and tested for their bioactivities. Maceration provided the extraction of higher dry matter contents, including total phenolics (TPC), anthocyanins, and condensed tannins, which also impacted higher antioxidant activity. NS and SB extracts presented the highest mean values of TPC and antioxidant activity. Individually, NS extract presented high contents of proanthocyanidins, resveratrol, and some phenolic acids. In contrast, SB contained a high concentration of ellagitannins, ellagic acid, and quercetin, exp…

Recupero energetico delle biomasse in vitivinicoltura: valutazione di un caso aziendale

2010

Solar PAR and UVR modify the community composition and photosynthetic activity of sea ice algae

2015

The effects of increased photosynthetically active radiation (PAR) and ultraviolet radiation (UVR) on species diversity, biomass and photosynthetic activity were studied in fast ice algal communities. The experimental set-up consisted of nine 1.44 m(2) squares with three treatments: untreated with natural snow cover (UNT), snow-free (PAR + UVR) and snow-free ice covered with a UV screen (PAR). The total algal biomass, dominated by diatoms and dinoflagellates, increased in all treatments during the experiment. However, the smaller biomass growth in the top 10-cm layer of the PAR + UVR treatment compared with the PAR treatment indicated the negative effect of UVR. Scrippsiella complex (mainly…

Usi energetici dei residui agricoli della coltivazione cerealicola in associazione con colture no food di rotazione: un caso studio nel Comprensorio …

2008

Gestione sostenibile delle foreste Mediterranee e uso energetico delle biomasse forestali residuali

2014

he book describes the reasons that led the Regional Department of Rural and Territorial Development to take part in the PROFORBIOMED Project. They can be summarized by the need to dispose of a tool for the sustainable management of all the state-owned forests of the Region. As a matter of fact, the Project aims at developing a model of sustainable forest management, through the recovery and reuse of wood scraps from ordinary silvicultural operations, to be used for the production of power and heat inside of a process adopting natural renewable energy sources. The main actions taken and the methodologies adopted are described, as well as the principles and instruments required for the settin…

Caratterizzazione bio-agronomica ed energetica di alcune specie presenti nella flora spontanea siciliana

2009

La biomassa ligno-cellulosica, proveniente da numerosi arbusti della macchia mediterranea, grazie alla loro diffusa disponibilità sul territorio, rappresenta sicuramente una fonte rinnovabile di energia facilmente reperibile. Il crescente interesse verso tali fonti ha sollecitato la ricerca ad approfondire le conoscenze su quelle specie che, da un lato possano fornire una notevole quantità di biomassa, dotata di un elevato rendimento energetico, e che, dall’altro, richiedono bassi input energetici (concimazioni, lavorazioni, apporti irrigui, ecc.) per la loro coltivazione. In quest’ottica, è stato svolto uno studio per individuare specie arbustive della macchia mediterranea, contribuendo co…

Brønsted and Lewis acid catalyzed conversion of pulp industry waste biomass to levulinic acid

2019

Enormous amounts of fiber sludge are generated annually by the pulp industry as a by-product. As a cellulose-rich material, its current usage, mainly as fuel, is inefficient from a material efficiency point of view. This work studied the utilization of fiber sludge from a Finnish and a Swedish pulp mill as a potential feedstock to produce levulinic acid, a valuable platform chemical. The conversion experiments of fiber sludge to levulinic acid were performed in a microwave reactor with a mixture of H2SO4 and Lewis acid as the catalyst. The reaction conditions, which included reaction time and temperature as well as the H2SO4 and Lewis acid concentrations, were studied in detail. The highest…