Search results for "Bismuth"
showing 10 items of 151 documents
Experimental and Theoretical Study of Bi2O2Se Under Compression
2018
[EN] We report a joint experimental and theoretical study of the structural, vibrational, elastic, optical, and electronic properties of the layered high-mobility semiconductor Bi2O2Se at high pressure. A good agreement between experiments and ab initio calculations is observed for the equation of state, the pressure coefficients of the Raman-active modes and the bandgap of the material. In particular, a detailed description of the vibrational properties is provided. Unlike other Sillen-type compounds which undergo a tetragonal to collapsed tetragonal pressure-induced phase transition at relatively low pressures, Bi2O2Se shows a remarkable structural stability up to 30 GPa; however, our res…
Quantum size effects in solitary wires of bismuth
2007
We have performed four-probe electrical transport measurements on solitary highly crystalline wires of semimetallic bismuth with aspect ratios up to 60 at room and at cryogenic temperatures. By proper choice of the substrate material and the film deposition parameters, lithographic wires with lateral dimensions of down to one single grain, $\sim 250$ nm, were fabricated. The electrical resistance of each wire was measured against its thickness through successive reactive ion etching of the self-same wire. Quantum size effects revealed themselves as regular oscillations in the electrical resistance. Some evidence for the semimetal-to-semiconductor phase transition has been detected. The meas…
Thermo-Optical Investigation of Sodium-Bismuth Titanate Single Crystal and PLZT Ceramics
2005
Thermal lensing in relaxor type ferroelectrics as a function of temperature has been investigated by using pulse/probe method. Enhanced thermo-optical (TO) properties had been observed in 3d elements (Cu, Co) doped PLZT ceramics and in sodium-bismuth titanate single crystals near phase transitions (PT). Comparison of TO signals for several doped PLZT materials reveals that 0.5 wt.% Cu doping is responsible for improved thermal lensing parameters interpreted by optimal light absorption, heat transfer and possible PT adjustment. TO experiments in sodium-bismuth titanate single crystals ([001] cut) show enhancement of TO properties in the region of PT and coexisting phases (rhombohedral and te…
Investigations of Low Temperature Phase Transitions in BiFeO3Ceramic by Infrared Spectroscopy
2011
In this paper, results of new infrared FIR-MIR measurements (wavenumber range of 4000–100 cm−1) in the range of the temperature 300 ÷ 8 K of the BiFeO3 ceramic are presented. Below 200 K only one symmetric band at ca. 800 cm−1 is visible. The full width at half maximum of this band decreases exponentially on cooling. The shape of the band at ca. 545 cm−1connected with A1 (TO) mode also changes between 60–40 K, this is in the vicinity of the phase transition at 50 K. Initially a broad band reveals its components as shoulder bands. Theirs FWHM decrease with cooling.
Low-dimensional non-toxic A 3 Bi 2 X 9 compounds synthesized by a dry mechanochemical route with tunable visible photoluminescence at room temperature
2019
We have synthesized fifteen inorganic and hybrid organic-inorganic non-toxic A3Bi2X9 compounds (A = K+, Rb+, Cs+, CH3NH3+ and HC(NH2)2+; X = I−, Br−, Cl−) through dry mechanochemistry. We demonstrate that this synthetic method is very well suited to prepare compounds from poorly soluble precursors, allowing thus the preparation of so far unreported compounds. X-ray diffraction analysis demonstrates the high crystallinity of the so-formed ternary bismuth halides. Furthermore, we show that, through substitution of the A-cation and X-anion, the bandgap of these compounds can be tuned to absorb throughout the whole visible spectrum. As-prepared powders of Cs3Bi2Br9 and Cs3Bi2I9 without any pass…
Impact of fluorine admixture, hydrogen loading, and exposure to ArF excimer laser on photoluminescence of bismuth defects in amorphous silica
2013
Abstract Photoluminescence (PL) excited by ArF (193 nm), KrF (248 nm) and N 2 (337 nm) pulsed lasers is studied in bismuth doped unfused silicon dioxide synthesized on silica substrates by surface-plasma chemical vapor deposition (SPCVD). Additive free and fluorinated (F content ~ 0.4 wt.%) amorphous silica are examined as host materials for bismuth. Three typical PL bands peaking at wavelengths of 650 nm (orange), 800 nm and 1400 nm (near infrared, NIR) were observed. It is found that fluorine additive weakly affects PL detail of as deposited samples. However, hydrogen loading completely deactivates NIR PL in the case of fluorine free sample, but only slightly suppresses the NIR band in fl…
Intra-center and recombination luminescence of bismuth defects in fused and unfused amorphous silica fabricated by SPCVD
2013
Abstract Photoluminescence (PL) of bismuth doped silicon dioxide excited by UV excimer lasers (ArF — 193 nm, KrF — 248 nm) and a green light laser diode (532 nm) is studied in a wide spectral band at temperatures ranging from 12 to 750 K. Two types of samples are investigated: unfused, 100 μm in thickness amorphous layer immediately deposited on the inner surface of silica substrate tube, and the same material after profusion resulted from tube collapsing to a rod by external heating. PL bands centered at 620–650 nm, 820 nm and 1400 nm wavelengths are observed in both fused and unfused samples. Under excitation by the green laser diode decay time constants for 650 nm (orange) and 1400 nm (N…
New Nuclear Magnetic Moment of Bi209 : Resolving the Bismuth Hyperfine Puzzle
2018
A recent measurement of the hyperfine splitting in the ground state of Li-like ${^{208}\mathrm{Bi}}^{80+}$ has established a ``hyperfine puzzle''---the experimental result exhibits a $7\ensuremath{\sigma}$ deviation from the theoretical prediction [J. Ullmann et al., Nat. Commun. 8, 15484 (2017); J. P. Karr, Nat. Phys. 13, 533 (2017)]. We provide evidence that the discrepancy is caused by an inaccurate value of the tabulated nuclear magnetic moment (${\ensuremath{\mu}}_{I}$) of $^{209}\mathrm{Bi}$. We perform relativistic density functional theory and relativistic coupled cluster calculations of the shielding constant that should be used to extract the value of ${\ensuremath{\mu}}_{I}(^{209…
First observation of the ground-state hyperfine transition in 209Bi80+
2013
The long sought after ground-state hyperfine transition in lithium-like bismuth 209Bi80+ was observed for the first time using laser spectroscopy on relativistic ions in the experimental storage ring at the GSI Helmholtz Centre in Darmstadt. Combined with the transition in the corresponding hydrogen-like ion 209Bi82+, it will allow extraction of the specific difference between the two transitions that is unaffected by the magnetic moment distribution in the nucleus and can therefore provide a better test of bound-state QED in extremely strong magnetic fields.
Very long nuclear relaxation times of spin polarized helium 3 in metal coated cells
1995
Abstract We obtained very long relaxation times T 1 of up to 120 h for the nuclear polarization of an optically pumped helium 3 gas. The glass containers were internally coated with metallic films such as bismuth or cesium. These findings will have applications in the field of helium magnetometers and polarized targets.