Search results for "Bisphenol"
showing 10 items of 84 documents
Determination of phenolic compounds in surface waters using high-performance liquid chromatography and molecularly imprinted solid-phase extraction
2021
An effective and reliable analytical method based on molecularly imprinted solid-phase extraction (MI-SPE) and high-performance liquid chromatography with photodiode array detector was developed to simultaneously determine four phenolic compounds: bisphenol A, 2-phenylphenol, tert-octylphenol and nonylphenol. A molecularly imprinted polymer that can selectively recognize bisphenol A and alkylphenols was developed. A bulk polymerization method using bisphenol A as a template, acrylamide as functional monomer, ethylene glycol dimethacrylate as the cross-linking agent, acetonitrile as porogenic solvent and 1,1’-azobis(cyclohexanecarbonitrile) as initiator was applied. This polymer was applied …
CCDC 636958: Experimental Crystal Structure Determination
2010
Related Article: A.Ray, G.M.Rosair, R.Rajeev, R.B.Sunoj, E.Rentschler, S.Mitra|2009|Dalton Trans.||9510|doi:10.1039/b911938h
Genotoxic and endocrine activities of bis(hydroxyphenyl)methane (bisphenol F) and its derivatives in the HepG2 cell line
2008
International audience; Human can be exposed to bis(hydroxyphenyl)methane (bisphenol F or BPF) and its derivatives as environment and food's contaminants. This study was investigated to identify and to compare toxic potency of BPF, BFDGE, and two of BPF metabolites using in vitro methods. BPF did not induce any genic mutation in bacteria when the Ames test was performed according to the OECD guideline. In contrast, using Human cell lines and Comet assay, we demonstrated that BPF and Bisphenol F Diglycidyl Ether (BFDGE) were effective on HepG2 cell DNA fragmentation at non-cytotoxic concentrations. DHB was also positive but at higher concentrations, near its limit of solubility. Neither BPF,…
Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes
2018
International audience; Origins of stereoselectivity in ROP of racemic chiral cyclic esters promoted by achiral yttrium complexes, resulting in the formation of highly heterotactic polylactide, and highly syndiotactic or, more uniquely, highly isotactic poly(3-hydroxybutyrate)s, are discussed. A close interplay between the nature of the cyclic ester, most particularly of the exocyclic functional chain installed on the chiral center of β-lactones, and the ortho-substituents installed on the phenolate rings of the ligand, results in various determining secondary interactions of steric and also electronic nature.
Polyether-bridged cyclophanes incorporating bisphenol A units as neutral receptors for quats: synthesis, molecular structure and binding properties
2001
Two novel neutral polyoxyethylene bridged cyclophanes (2a and 2b) incorporating bisphenol A units were synthesized and characterized by means of x-ray crystal structure determination. The binding properties of 2a and 2b toward tetramethylammonium, N-methylpyridinium, and acetylcholine cations were evaluated by means of 1H NMR spectroscopy. Consistent with indications provided by the molecular structure, the cavity in the basket-like cyclophanes is large enough to accommodate the given guest cations conveniently. Circumstantial evidence was obtained that 1,1,2,2-tetrachloroethane is too large to enter the cavity of the smaller cyclophane 2a, but can be included in the cavity of the larger cy…
Biomass-based composite catalysts for catalytic wet peroxide oxidation of bisphenol A : preparation and characterization studies
2019
Abstract The wet granulation process was used to prepare new, efficient, and cost-effective granular biomass-based composite catalysts for catalytic wet peroxide oxidation (CWPO) of bisphenol A (BPA). The most stable composite granules was prepared by mixing biomass-based carbon residue (CR) with metakaolin (MK) combined with calcium oxide (CaO) or cement and a solvent (NaOH or KOH). For all the prepared composite granules, the optimized binding agents to carbon ratio was 0.3, the solvent to carbon ratio 1.2, and the agitation rate 1200 rpm. The specific surface area of the prepared catalysts was 152–205 m2/g. The composite granular catalyst (CR + MK + CaO + NaOH) had the most durable and s…
Cariostatic effect of a light-cured, resin-reinforced glass-ionomer for bonding orthodontic brackets in vivo
1998
The aim of this study was to evaluate in vivo the cariostatic potential of the resin-reinforced glass-ionomer (Vitremer core build-up restorative; 3M Dental Product Division) when used as a bonding agent for orthodontic brackets. The mineral distribution and topography of the enamel surface adjacent to the bracket base was determined by quantitative microradiography (TMR) and confocal laser scanning microscopy (CLSM). The study was designed in split-mouth technique using 9 pairs of premolars to be extracted for orthodontic reasons. One tooth of each pair was bonded with the resin-reinforced glass-ionomer, and the control contralateral premolar with the non-fluoridated composite (Concise, 3M…
Abnormal peripubertal development of the rat mammary gland following exposure in utero and during lactation to a mixture of genistein and the food co…
2011
The impact of early exposure to endocrine disruptor mixtures on mammary gland development is poorly known. Here, we identify the effects of a conception to weaning exposure of rats to the phytoestrogen genistein (G) and/or the antiandrogen vinclozolin (V) at 1 mg/kg-d, alone or in association. Using several approaches, we found that G- and GV-exposed rats displayed significantly greater epithelial branching and proliferation, wider terminal end buds than controls at PND35, as well as ductal hyperplasia and periductal fibrosis. Focal branching defects were present in V-exposed rats. An increased ER and AR expression was observed in G- and CV- as compared to V-exposed rats at PND35. Surprisin…
Effect of three endocrine disruptors, bisphenol a, vinclozolin and genistein, on kallikrein 4 expression. – CIME project
2012
Effect of three endocrine disruptors, bisphenol a, vinclozolin and genistein, on kallikrein 4 expression. – CIME project. Colloque PNR-PE
Environmental levels of bisphenol A, genistein and vinclozolin feminize digit length ratios in male rats: towards a new sensitive indicator of prenat…
2012
Environmental levels of bisphenol A, genistein and vinclozolin feminize digit length ratios in male rats: towards a new sensitive indicator of prenatal endocrine disruption and its impact in the progeny. – CIME project. Colloque PNR-PE