Search results for "Bond formation"

showing 2 items of 42 documents

ChemInform Abstract: Unique Reactivity of Fluorinated Molecules with Transition Metals

2015

Organofluorine and organometallic chemistry by themselves constitute two potent areas in organic synthesis. Thus, the combination of both offers many chemical possibilities and represents a powerful tool for the design and development of new synthetic methodologies leading to diverse molecular structures in an efficient manner. Given the importance of the selective introduction of fluorine atoms into organic molecules and the effectiveness of transition metals in C-C and C-heteroatom bond formation, this review represents an interesting read for this aim.

chemistry.chemical_elementGeneral MedicineBond formationCombinatorial chemistryOrganic moleculeschemistry.chemical_compoundchemistryTransition metalFluorineMoleculeOrganic chemistryReactivity (chemistry)Organic synthesisOrganometallic chemistryChemInform
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Thieme Chemistry Journals Awardees – Where Are They Now? Molybdenum(V)-Mediated Synthesis of Nonsymmetric Diaryl and Aryl Alkyl Chalcogenides

2017

Oxidative chalcogenation reaction using molybdenum(V) reagents provides fast access to a wide range of nonsymmetric aryl sulfides and selenides. The established protocol is tolerated by a variety of labile functions, protecting groups, and aromatic heterocycles. In particular, when labile moieties are present, the use of molybdenum(V) reagents provides superior yields compared to other oxidants.

inorganic chemicalschemistry.chemical_classificationmolybdenum pentachloridedisulfides010405 organic chemistryArylOrganic Chemistrychemistry.chemical_elementMolybdenum pentachloride010402 general chemistryoxidative coupling01 natural sciences0104 chemical scienceschemistry.chemical_compoundchemistryMolybdenumReagentcross-couplingOrganic chemistryOxidative coupling of methaneC–S bond formationAlkylSynlett
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