Search results for "Borane"

showing 10 items of 278 documents

CCDC 156982: Experimental Crystal Structure Determination

2002

Related Article: S.Kiviniemi, M.Nissinen, T.Alaviuhkola, K.Rissanen, J.Pursiainen|2001|J.Chem.Soc.,Perkin Trans.2||2364|doi:10.1039/b100775k

Pyrazole-triphenylboraneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Organoboron Polymers for Photovoltaic Bulk Heterojunctions

2010

SOLAR-CELLSphotovoltaic bulk heterojunctionORGANIC PHOTOVOLTAICSn-type polymerthin filmsSOLAR-CELLS; ORGANIC PHOTOVOLTAICS; CONJUGATED POLYMERSCONJUGATED POLYMERSboranehigh performance polymer
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Adsorptive Separation of CO2 by a Hydrophobic Carborane-Based Metal-Organic Framework under Humid Conditions

2023

We report that the carborane-based metal-organic framework (MOF) mCB-MOF-1 can achieve high adsorptive selectivity for CO2:N2 mixtures. This hydrophobic MOF presenting open metal sites shows high CO2 adsorption capacity and remarkable selectivity values that are maintained even under extremely humid conditions. The comparison of mCB-MOF-1' with MOF-74(Ni) demonstrates the superior performance of the former under challenging moisture operation conditions.

Selective gas separationGeneral Materials ScienceHumid conditionsQuímicaMetal−organic frameworksCO2 adsorptionCarboranesHydrophobicBreakthrough
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Organic Monolayers by B(C6F5)3-Catalyzed Siloxanation of Oxidized Silicon Surfaces

2017

Inspired by the homogeneous catalyst tris(pentafluorophenyl) borane [B(C6F5)3], which acts as a promotor of Si-H bond activation, we developed and studied a method of modifying silicon oxide surfaces using hydrosilanes with B(C6F5)3 as the catalyst. This dedihydrosiloxanation reaction yields complete surface coverage within 10 min at room temperature. Organic monolayers derived from hydrosilanes with varying carbon chain lengths (C8-C18) were prepared on oxidized Si(111) surfaces, and the thermal and hydrolytic stabilities of the obtained monolayers were investigated in acidic (pH 3) medium, basic (pH 11) medium, phosphate-buffered saline (PBS), and deionized water (neutral conditions) for …

SiliconInorganic chemistrySilici Compostoschemistry.chemical_elementHomogeneous catalysis02 engineering and technologyBorane010402 general chemistry01 natural sciencesQuímica de superfíciesCatalysischemistry.chemical_compoundHydrolysisMonolayerElectrochemistryLife ScienceGeneral Materials ScienceSilicon oxideSpectroscopyVLAGOrganic ChemistrySurfaces and Interfaces021001 nanoscience & nanotechnologyCondensed Matter PhysicsOrganische ChemieSilane0104 chemical scienceschemistry0210 nano-technologyQuímica orgànicaLangmuir
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Design of carborane molecular architectures with electronic structure computations: From endohedral and polyradical systems to multidimensional netwo…

2009

11 pags, 6 figs. -- 19th International Conference on Physical Organic Chemistry (ICPOC-19) 13–18 July 2008, Santiago de Compostela, Spain

SingletComputational chemistryIcosahedral symmetryChemistryCASPT2General Chemical EngineeringComputationQuantum chemical computationsMolecular architectureGeneral ChemistryElectronic structureCASSCFDFTElectronic structuresTripletBiradicalsDianionsComputational chemistryAtomCarboraneSinglet stateDimersCarboranes
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CCDC 1824868: Experimental Crystal Structure Determination

2018

Related Article: María Frutos, Mar Gómez-Gallego, Elena A. Giner, Miguel A. Sierra, Carmen Ramírez de Arellano|2018|Dalton Trans.|47|9975|doi:10.1039/C8DT02296H

Space GroupCrystallography(2-(4-ferrocenyl-123-triazol-1-ylmethyl)-12-dicarba-closo-dodecaborane)-chloro-(pentamethyl-cyclopentadienyl)-iridiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 937833: Experimental Crystal Structure Determination

2013

Related Article: J.Bayardon, H. Laureano, V. Diemer, M. Dutartre, U. Das, Y.Rousselin, J.-C. Henry, F. Colobert, F. R. Leroux, S. Jugé|2012|J.Org.Chem.|77|5759|doi:10.1021/jo300910w

Space GroupCrystallography(Borane)(2-bromophenyl)dicyclohexylphosphineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 937835: Experimental Crystal Structure Determination

2013

Related Article: J.Bayardon, H. Laureano, V. Diemer, M. Dutartre, U. Das, Y.Rousselin, J.-C. Henry, F. Colobert, F. R. Leroux, S. Jugé|2012|J.Org.Chem.|77|5759|doi:10.1021/jo300910w

Space GroupCrystallography(Borane)(ferrocenyl)(2-bromophenyl)phenylphosphineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 768724: Experimental Crystal Structure Determination

2011

Related Article: F.Chaux, S.Frynas, H.Laureano, C.Salomon, G.Morata, M.-L.Auclair, M.Stephan, R.Merdes, P.Richard, M.-J.Ondel-Eymin, J.-C.Henry, J.Bayardon, C.Darcel, S.Juge|2010|Comptes Rendus Chimie|13|1213|doi:10.1016/j.crci.2010.06.001

Space GroupCrystallography(Borane)(phenyl)(2-methoxyphenyl)(ferrocenyl)phosphineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 762078: Experimental Crystal Structure Determination

2010

Related Article: Duc Hanh Nguyen, H.Laureano, S.Juge, P.Kalck, J.-C.Daran, Y.Coppel, M.Urrutigoity, M.Gouygou|2009|Organometallics|28|6288|doi:10.1021/om900684w

Space GroupCrystallography(Borane)-diphenyl-((5H-benzo[b]phosphindol-5-yl)methyl)phosphineCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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