Search results for "Brine"
showing 10 items of 92 documents
The REAPower Project: Power Production From Saline Waters and Concentrated Brines
2019
Aim of this chapter is that of describing in detail the REAPower project from the very beginning up to the testing of the pilot plant built at the end of the project.
REAPOWER – USE OF DESALINATION BRINE FOR POWER PRODUCTION THROUGH REVERSE ELECTRODIALYSIS
2015
Salinity gradient power (SGP) represents a viable renewable energy source associated with the mixing of two solutions of different salinities. Reverse electrodialysis (SGP-RE or RED) is a promising technology to exploit this energy source and directly generate electricity. However, although the principle of this technology is well known since several years, further R&D efforts are still necessary in order to explore the real potential of the SGP-RE process. With this regard, the aim of the REAPower project ( [GRAPHICS] ) is the development of an innovative system for power production by SGP-RE process, using sea (or brackish) water as a diluted solution and brine as a concentrate. The use o…
Reverse Electrodialysis Process: Analysis of Optimal Conditions for Process Scale-up
2014
Reverse Electrodialysis (SGP-RE or RED) process has been widely accepted as a viable and promising technology to produce electric energy from salinity difference (i.e salinity gradient power - e.g. using river water/seawater, or seawater and concentrated brines). Recent R&D efforts demonstrated how an appropriate design of the SGP-RE unit and a suitable selection of process conditions may crucially enhance the process performance. With this regard, a process simulator was developed and validated with experimental data collected on a lab-scale unit, providing a new modelling tool for process optimisation. In this work, performed within the REAPower project (www.reapower.eu), the process simu…
Techno-economic analysis of a novel hybrid system for the valorisation of SWRO brines in a minor Sicilian island
2021
In small remote islands, freshwater scarcity is an issue to which several viable solutions have already been found employing constantly evolving desalination technologies. The several RO plants in the Canary and minor Sicilian Islands are just an example . However, the beneficial application of seawater desalination is accompanied by a problematic matter: the production of high salinity brines. Not only do they compromise the aquatic ecosystem but their treatment in order to respect environmental regulations is costly too. Worth noting how these so-called “wastewater streams” present a high concentration of valuable raw materials, such as magnesium and calcium or sodium chloride, that are e…
Development of a pilot plant for the recovery of magnesium hydroxide from waste brines
Waste brines from various industrial processes, mainly from saltworks, are an important source of minerals, such as magnesium, table salt and potable water.
Diffusion dialysis for the treatment of H2SO4-CuSO4 solutions from electroplating plants: Ions membrane transport characterization and modelling
2021
Diffusion dialysis (DD) is proposed to separate and recover mineral acids and transition metals from electroplating industry process waters promoting a circular approach of resources recovery. In this work, a DD module with two anionic membranes (Fumasep FAD and Neosepta AFN) are used for the separation of H2SO4 from Cu2+ containing solutions. The membrane performances with sole H2SO4 solutions (0.2–2 M) and sole CuSO4 solutions (0.8–1.1 M Cu2+) and with mixtures of H2SO4 (0.6 M) and CuSO4 (0.2–1.1 M Cu2+) as feed are studied. H2SO4 recovery efficiency decreases as the concentration of acid increases. For H2SO4 solutions, the water drag flux from the retentate to the diffusate prevails agai…
A Novel Ionic Exchange Membrane Crystallizer to Recover Magnesium Hydroxide from Seawater and Industrial Brines
2020
A novel technology, the ion exchange membrane crystallizer (CrIEM), that combines reactive and membrane crystallization, was investigated in order to recover high purity magnesium hydroxide from multi-component artificial and natural solutions. In particular, in a CrIEM reactor, the presence of an anion exchange membrane (AEM), which separates two-compartment containing a saline solution and an alkaline solution, allows the passage of hydroxyl ions from the alkaline to the saline solution compartment, where crystallization of magnesium hydroxide occurs, yet avoiding a direct mixing between the solutions feeding the reactor. This enables the use of low-cost reactants (e.g., Ca(OH)2) without …
Reactive crystallisation process for magnesium recovery from concentrated brines
2014
Seawater brines, generated either by natural or anthropic processes, often cause significant environmental issues related to their disposal. A clear example is the case of brines from desalination plants, which can have severe environmental impacts on the receiving water body. On the other side, brines can represent a rich and appealing source of raw materials, especially when they are very concentrated, as it happens with bitterns (i.e. exhausted brines) produced in saltworks. In particular, magnesium concentration can reach values up to 30-40 kg/m3 of brine, which is 20-30 times that of typical seawater. An experimental campaign has been carried out in the present work for assessing the p…
Electrodialysis Applications in Wastewater Treatment for Environmental Protection and Resources Recovery: A Systematic Review on Progress and Perspec…
2020
This paper presents a comprehensive review of studies on electrodialysis (ED) applications in wastewater treatment, outlining the current status and the future prospect. ED is a membrane process of separation under the action of an electric field, where ions are selectively transported across ion-exchange membranes. ED of both conventional or unconventional fashion has been tested to treat several waste or spent aqueous solutions, including effluents from various industrial processes, municipal wastewater or salt water treatment plants, and animal farms. Properties such as selectivity, high separation efficiency, and chemical-free treatment make ED methods adequate for desalination and othe…
Energetic Valorisation of Saltworks Bitterns via Reverse Electrodialysis: A Laboratory Experimental Campaign
2023
Concentrated bitterns discharged from saltworks have extremely high salinity, often up to 300 g/L, thus their direct disposal not only has a harmful effect on the environment, but also generates a depletion of a potential resource of renewable energy. Here, reverse electrodialysis (RED), an emerging electrochemical membrane process, is proposed to capture and convert the salinity gradient power (SGP) intrinsically conveyed by these bitterns also aiming at the reduction of concentrated salty water disposal. A laboratory-scale RED unit has been adopted to study the SGP potential of such brines, testing ion exchange membranes from different suppliers and under different operating conditions. M…