Search results for "Bromine"
showing 10 items of 102 documents
Overlappingβdecay and resonance neutron spectroscopy of levels inKr87
1983
Energy levels in $^{87}\mathrm{Kr}$ have been studied, with special emphasis on the unbound region, using two different methods. The first method comprises neutron capture and transmission measurements on an enriched gas target of $^{86}\mathrm{Kr}$ using neutron time-of-flight techniques. In this way, neutron widths were determined for 39 resonances below 400 keV and capture areas for 14 resonances below 90 keV. The second method is a decay study of 56-s $^{87}\mathrm{Br}$ in which a level scheme for $^{87}\mathrm{Kr}$ has been established that shows 126 levels in the bound and 12 levels in the unbound region. A detailed comparison amongst the neutron resonance, the $\ensuremath{\gamma}$-r…
Dicopper(II) Metallacyclophanes with Electroswitchable Polymethyl-Substitutedpara-Phenylene Spacers
2013
Double-stranded anionic dinuclear copper(II) metallacyclic complexes of the paracyclophane type [Cu2L2]4- have been prepared by the CuII-mediated self-assembly of different para-phenylenebis(oxamato) bridging ligands with either zero-, one-, or four-electron-donating methyl substituents (L=N,N′-para- phenylenebis(oxamate) (ppba; 1), 2-methyl- N,N′-para-phenylenebis(oxamate) (Meppba; 2), and 2,3,5,6-tetramethyl- N,N′-para-phenylenebis(oxamate) (Me4ppba; 3)). These complexes have been isolated as their tetra-n-butylammonium (1 a-3 a), lithium(I) (1 b-3 b), and tetraphenylphosphonium salts (1 c-3 c). The X-ray crystal structures of 1 a and 3 c show a parallel-displaced π-stacked conformation w…
Elemental Bromine Production by TiO2 Photocatalysis and/or Ozonation
2016
Significant production of elemental bromine (Br2 ) was observed for the first time when treating bromide containing solutions at acidic pH, with TiO2 photocatalyst, ozone, or a combination thereof. Br2 selectivities up to approximately 85 % were obtained and the corresponding bromine mass balance values satisfied. The process is general and may be applied at a laboratory scale for green bromination reactions, or industrially as a cheap, safe, and environmentally sustainable alternative to the currently applied bromine production methods.
Die Wirkung von Theophyllin, Coffein und Theobromin auf Kontraktionskraft, Erregbarkeit, Refrakt�rzeit und Spontanfrequenz des isolierten Herzmuskels…
1956
In the electrically driven papillary muscle of the cat's right ventricle theophylline, caffeine and theobromine exerted a positive inotropic action. Log. dose-effect regression lines for the three drugs were parallel; the effect of theophylline was significantly greater than those of caffeine and theobromine. The range of concentrations used was 1/32–1/2 mM/1.
Total absorption γ -ray spectroscopy of the β -delayed neutron emitters Br87 , Br88 , and Rb94
2017
We investigate the decay of 87,88Br and 94Rb using total absorption γ -ray spectroscopy. These important fission products are β-delayed neutron emitters. Our data show considerable βγ intensity, so far unobserved in high-resolution γ -ray spectroscopy, from states at high excitation energy. We also find significant differences with the β intensity that can be deduced from existing measurements of the β spectrum. We evaluate the impact of the present data on reactor decay heat using summation calculations. Although the effect is relatively small it helps to reduce the discrepancy between calculations and integral measurements of the photon component for 235U fission at cooling times in the r…
Intense mass-separated beams of halogens and beta-delayed neutron emission from heavy bromine isotopes
1984
Improved production yields of short-lived halogens were obtained from a ThO2 target, irradiated with 600 MeV protons, in combination with a negative surface ionization source. Mass-separated samples were studied by decay spectroscopy. Production yields of radioactive isotopes of chlorine, bromine, iodine and astatine are presented. Half-lives and relative neutron emission probabilities were measured for the heavy bromine isotopes89−92Br. Normalizing to earlier publishedPn values for89Br, the results are:89Br (4.30±0.14s,P n =13.6±0.8%),90Br (1.92±0.06s,P n =24.8±1.5%),91Br (0.53 ±0.03 s,P n =30.1 ±2.1%), and92Br (0.31 ±0.02 s,P n =34.6±2.5%). Energy spectra ofβ-delayed neutrons were measure…
rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene
2020
In the title compound, a cyclooctene ring in a twist-boat conformation and a dioxolane ring with a distorted envelope conformation are annulated in a trans configuration. Alternating strands of single enantiomers build up the crystal. Within the strands, the molecules are connected by weak C—H...O hydrogen bonds.
Transition probabilities for BrII lines emitted from a wall-stabilized cascade arc
2000
Abstract Absolute transition probabilities of the eleven Br II lines were measured in emission. A plasma created in a wall-stabilized arc at atmospheric pressure in the mixture of argon and bromine vapors was used as the excitation source. The relative transition probabilities were converted to an absolute scale based on a lifetime value measured by the electron impact method. The results were compared with experimental data. Discrepancies have been found to be outside the experimental uncertainties.
Stark effect in some lines of neutral bromine
2002
Abstract This work presents experimental results of profile parameters for prominent lines of neutral bromine, for which serious discrepancies between experimental values of different authors as well as between experimental and calculated values were observed. The observed discrepancies between shock tube and earlier arc experiments are very large. Our results of profile parameters, obtained also in a wall-stabilized arc, show acceptable agreement with the earlier arc measurements. It is obvious, that the shock tube experimental result is out of the range of acceptable inaccuracy and should be remeasured. The theoretical calculations based on different assumptions give also strongly diverge…