Search results for "Bromonitromethane"

showing 2 items of 2 documents

ChemInform Abstract: A Catalytic Highly Enantioselective Direct Synthesis of 2-Bromo-2-nitroalkan-1-ols Through a Henry Reaction.

2009

Highly enantiomerically enriched 2-bromo-2-nitroalkan-1-ols are prepared by direct condensation of aliphatic and aromatic aldehydes with bromonitromethane in the presence of a catalytic amount of copper(II) acetate and a C1-symmetric camphor-derived amino pyridine ligand.

Addition reactionNitroaldol reactionChemistryBromonitromethaneCondensationEnantioselective synthesisOrganic chemistrychemistry.chemical_elementGeneral MedicineCopperPyridine ligandCatalysisChemInform
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A catalytic highly enantioselective direct synthesis of 2-bromo-2-nitroalkan-1-ols through a Henry reaction.

2008

Highly enantiomerically enriched 2-bromo-2-nitroalkan-1-ols are prepared by direct condensation of aliphatic and aromatic aldehydes with bromonitromethane in the presence of a catalytic amount of copper(II) acetate and a C1-symmetric camphorderived amino pyridine ligand. Blay Llinares, Gonzalo, Gonzalo.Blay@uv.es ; Hernandez Olmos, Victor, Victor.Hernandez@uv.es ; Pedro Llinares, Jose Ramon, Jose.R.Pedro@uv.es

Nitroaldol reactionEnrichedCondensationPyridinesBromonitromethaneUNESCO::QUÍMICACatalytic ; Synthesis ; Henry reaction ; Enriched ; CondensationMolecular Conformationchemistry.chemical_elementAcetatesLigands:QUÍMICA [UNESCO]CatalysisCatalysisSynthesisMaterials ChemistryOrganic chemistryCatalyticAldehydesEthaneChemistryUNESCO::QUÍMICA::Química inorgánicaCondensationMetals and AlloysEnantioselective synthesisStereoisomerismGeneral Chemistry:QUÍMICA::Química inorgánica [UNESCO]Nitro CompoundsCopperPyridine ligandSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsAlcoholsCeramics and CompositesHenry reactionCopperChemical communications (Cambridge, England)
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