Search results for "CARBONATE"
showing 10 items of 920 documents
Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy
2018
Limonene epoxide (1,2 limonene oxide) readily reacts with carbon dioxide in a ring opening copolymerization reaction with insertion of CO2 and formation of polycarbonates of exceptional chemical and physical properties. Both poly(limonene carbonate) and poly(limonene dicarbonate) can be synthesized using low cost Zn or Al homogeneous catalysts. This study addresses selected relevant questions concerning the technical and economic feasibility of limonene and carbon dioxide polymers en route to the bioeconomy.
Carbon isotope geochemistry and geochronological constraints of the Neoproterozoic Sirohi Group from northwest India
2012
a b s t r a c t The early Neoproterozoic carbonates of the Sirohi Group, northwestern India, were studied for geochronology as well as for oxygen and carbon isotopes across three different sections to understand their relationship with contemporaneous global events. New single zircon Pb-Pb evaporation data con- strain the age of the Sirohi Group between ca. 920 and ca. 820 Ma, though actual span for deposition of the carbonates may be little shorter taking into allowance the time for peneplanation. Narrow range in variation of 18O values is generally observed in the carbonate which is consistent with generally well-preserved original compositions. Two sections (SA and SS) out of the three t…
Petrography and high-resolution geochemical records of Lower Jurassic manganese-rich deposits from Monte Mangart, Julian Alps
2016
Deposits with unusually high Mn contents sampled at Monte Mangart in the Julian Alps include organic-rich marlstone and black shale with interbedded manganoan and siliceous limestone, which were deposited during the early Toarcian Oceanic Anoxic Event. Mn enrichment during that period has been related to global sea-level change coincident with increasing subsidence rate. The formation of Fe-Mn nodules, marking a hardground at the base of the Monte Mangart section, seems to be triggered by release of Mn from remote hydrothermal vents into a region of relatively elevated submarine topography where oxidizing conditions prevailed. However, very high Mn contents in carbonate phases above the har…
Weathering Products of a Dismantled Variscan Basement. Minero-Chemical Proxies to Insight on Cretaceous Palaeogeography and Late Neogene Palaeoclimat…
2020
This study compares, for the first time, the mineralogy and geochemistry of two residual-clay deposits in NW Sardinia (Nurra district) that formed at different times in tropical and sub-tropical climates. Both deposits represent palaeosols with deep-weathered residual profiles and overlie Mesozoic carbonate rocks that were deposited on the south European palaeomargin. The older alterite is Cenomanian–Turonian in age and grades upward into a horizon of karstic bauxite, whereas the younger unit occurs within alluvial deposits of Late Neogene age. The Cretaceous palaeosol represents the precursor of the overlying bauxite and formed from unknown sedimentary parent rocks. In contrast, the Messin…
The Potential Geosite of the “Libeccio Antico” Quarries: a Sedimentological and Stratigraphic Characterisation of Ornamental Stone from Mt Cocuccio, …
2018
The Custonaci marble district of western Sicily is known for the production of a valuable ornamental stone that has been, and nowadays is exploited due to its suitable properties and aesthetic qualities. The “Libeccio Antico” was, among the “marbles”, the most appreciated ornamental stone during the Baroque Age (the XVII–XVIII centuries), due to its strong polychrome contrasts from ivory to yellow, green or dark red. This polychrome pattern is the result of dissolution processes that involved an Upper Triassic peritidal limestone. The varicoloured sediments in paleocavities, collapse breccias, paleosols and neptunian dykes that occur in the “Libeccio Antico” represent the peculiar character…
A diagenetic control on the Early Triassic Smithian-Spathian carbon isotopic excursions recorded in the marine settings of the Thaynes Group (Utah, U…
2016
17 pages; International audience; n the aftermath of the end-Permian mass extinction, Early Triassic sediments record some of the largest Phanerozoic carbon isotopic excursions. Among them, a global Smithian-negative carbonate carbon isotope excursion has been identified, followed by an abrupt increase across the Smithian–Spathian boundary (SSB; ~250.8 Myr ago). This chemostratigraphic evolution is associated with palaeontological evidence that indicate a major collapse of terrestrial and marine ecosystems during the Late Smithian. It is commonly assumed that Smithian and Spathian isotopic variations are intimately linked to major perturbations in the exogenic carbon reservoir. We present p…
Onset of the Messinian Salinity Crisis: Sedimentological, petrographic and geochemical characterization of the pre-salt sediments from a new core (Ca…
2022
The present study aims to reconstruct the environmental changes leading to the Messinian Salinity Crisis during the transition from the Tortonian-Messinian marine conditions to the Messinian evaporitic environments. The core 3AGN2S04, recently drilled in the Caltanissetta Basin (Sicily), was analyzed to reveal the petrographic, mineralogical and geochemical characteristics of the late Tortonian – early Messinian pre-salt sediments. In particular, the facies characterization of the carbonates and organic-rich shales of the Calcare di Base (CdB) member allowed to understand its significance in the paleoenvironmental evolution towards salt deposition and to the reconstruct the brecciation proc…
Geoconservation in Sicily (Italy): the Example of the Isola delle Femmine (Palermo)
2022
Abstract The Regional Administration of Sicily recently erected Isola delle Femmine—a small island of the Tyrrhenian Sea, close to Palermo—as a geosite. A detailed geological survey has been carried out in order to define the most important geological features of the island together with the development of a new geological map based on topographic data and a digital model at 1:2.000 scale specially processed. Finally, a geological pathway through the island has been traced and illustrated. The geological substrate of Isola delle Femmine consists of a Mesozoic carbonate succession belonging to the Panormide Carbonate Platform. Two lithostratigraphic units have been differentiated. The lowest…
Multidisciplinary characterization and modelling of the medium enthalpy geothermal reservoir of the Western Sicily: results from the VIGOR Project
2013
The school nutrition environment and its association with soft drink intakes in seven countries across Europe - the ENERGY project
2014
The school is an important setting for promoting healthy eating especially at the transition from childhood to adolescence. This study contributes to the literature by describing practices within physical, political and sociocultural aspects of the school nutrition environment in seven countries across Europe based on questionnaires to the school management, and exploring their associations with soft drink consumption reported on questionnaires by 10-12 year olds. Several of the commonly self-reported practices could be supportive of a healthy diet (time to eat, access to water, restriction on marketing), but some practices were underutilized (i.e. discussion with stakeholders, healthy food…