Search results for "CATA"
showing 10 items of 13753 documents
Absolute quantification of noncoding RNA by microscale thermophoresis
2019
Abstract Accurate quantification of the copy numbers of noncoding RNA has recently emerged as an urgent problem, with impact on fields such as RNA modification research, tissue differentiation, and others. Herein, we present a hybridization‐based approach that uses microscale thermophoresis (MST) as a very fast and highly precise readout to quantify, for example, single tRNA species with a turnaround time of about one hour. We developed MST to quantify the effect of tRNA toxins and of heat stress and RNA modification on single tRNA species. A comparative analysis also revealed significant differences to RNA‐Seq‐based quantification approaches, strongly suggesting a bias due to tRNA modifica…
Total Structure and Electronic Structure Analysis of Doped Thiolated Silver [MAg24(SR)18]2– (M = Pd, Pt) Clusters
2015
With the incorporation of Pd or Pt atoms, thiolated Ag-rich 25-metal-atom nanoclusters were successfully prepared and structurally characterized for the first time. With a composition of [PdAg24(SR)18](2-) or [PtAg24(SR)18](2-), the obtained 25-metal-atom nanoclusters have a metal framework structure similar to that of widely investigated Au25(SR)18. In both clusters, a M@Ag12 (M = Pd, Pt) core is capped by six distorted dimeric -RS-Ag-SR-Ag-SR- units. However, the silver-thiolate overlayer gives rise to a geometric chirality at variance to Au25(SR)18. The effect of doping on the electronic structure was studied through measured optical absorption spectra and ab initio analysis. This work d…
Structural Evolution of Atomically Precise Thiolated Bimetallic [Au12+nCu32(SR)30+n]4– (n = 0, 2, 4, 6) Nanoclusters
2014
A series of all-thiol stabilized bimetallic Au-Cu nanoclusters, [Au(12+n)Cu32(SR)(30+n)](4-) (n = 0, 2, 4, 6 and SR = SPhCF3), are successfully synthesized and characterized by X-ray single-crystal analysis and density functional theory (DFT) calculations. Each cluster consists of a Keplerate two-shell Au12@Cu20 core protected by (6 - n) units of Cu2(SR)5 and n units of Cu2Au(SR)6 (n = 0, 2, 4, 6) motifs on its surface. The size and structural evolution of the clusters is atomically controlled by the Au precursors and countercations used in the syntheses. The clusters exhibit similar optical absorption properties that are not dependent on the number of surface Cu2Au(SR)6 units. Although DFT…
Adsorption and Activation of Water on Cuboctahedral Rhodium and Platinum Nanoparticles
2017
Rh and Pt are widely used as the components in heterogeneous catalysts for multiple industrial applications. Because the metals are typically in the form of nanoparticles in real catalysts, it is important to carefully select models for the computational prediction of the catalytic properties. Here we report a first-principles study on the water activation, an important step in numerous catalytic reactions, using the finite-size Rh and Pt nanoparticle models and compare them to the extended surface models. We show that regardless of the model, adsorption and activation of water is practically identical for both metals, whereas the dissociation is energetically more favorable on Rh. The expe…
How news affect the trading behavior of different categories of investors in a financial market
2015
We investigate the trading behavior of a large set of single investors trading the highly liquid Nokia stock over the period 2003-2008 with the aim of determining the relative role of endogenous and exogenous factors that may affect their behavior. As endogenous factors we consider returns and volatility, whereas the exogenous factors we use are the total daily number of news and a semantic variable based on a sentiment analysis of news. Linear regression and partial correlation analysis of data show that different categories of investors are differently correlated to these factors. Governmental and non profit organizations are weakly sensitive to news and returns or volatility, and, typica…
Industrial Citizenship, Cosmopolitanism and European Integration
2014
Abstract. There has been an explosion of interest in the idea of European Union citizenship in recent years, as a defining example of postnational cosmopolitan citizenship potentially replacing, or at least layered on top of national citizenships. We argue this form of EU citizenship undermines industrial citizenship, which is a crucial support for the egalitarianism and social solidarity on which other types of citizenship are based. Because industrial citizenship arises from collectivities based in class identities and national institutions, it depends on the nation state erritorial order and the social closure inherent in this. EU citizenship in its current ‘postnational’ form is realize…
Valutazione della resistenza allo stress salino di Puccinellia distans (Jacq.) Parl. trattata con applicazioni fogliari dell'osmoregolatore glicinbet…
2009
Task-Specific Organic Salts and Ionic Liquids Binary Mixtures: A Combination to Obtain 5-Hydroxymethylfurfural From Carbohydrates
2019
The increase in energy demand and depletion of fossil fuels are among major issues of modern society. Valorization and transformation of raw materials in products of industrial value represents a challenge. This justifies the growing interest of scientific research towards the identification of suitable media and methodologies able to pursue above goals, paying attention to matter of sustainability. On this subject, we studied sulfonic-acid functionalized diimidazolium salts as catalysts for the conversion of fructose and sucrose to 5-hydroxymethylfurfural (5-HMF) in an ionic liquid mixture. In general, using these salts allowed us to obtain 5-HMF in good yields from both substrates in mild…
A new species of Silene sect. Dipterosperma (Caryophyllaceae) from Sicily
2012
Silene kemoniana, a new species of the section Dipterosperma from NW Sicily, is described and illustrated. It is a therophyte that occurs in mountains near Palermo, where it grows on Mesozoic limestones in xerophilous garigues. Its relationships with S. colorata and allied species are also examined. A key of the species belonging to sect. Dipterosperma is provided. Se describe e ilustra Silene kemoniana, una nueva especie del NW de Sicilia perteneciente a la sección Dipterosperma. Se trata de un terófito que habita en algunas montañas próximas a Palermo, donde crece sobre calizas mesozoicas entre matorrales mediterráneos xerófilos. Se estudian sus relaciones con S. colorata y otras especies…
Additions to terrestrial flora of Tunisia: occurrence and taxonomic notes
2020
We document new records of 11 vascular taxa. Some were found in the wild for the first time and, therefore, are new reports to terrestrial flora of Tunisia. One species, Ranunculus acris L., is reported for the first time for North Africa. Parietaria cretica L. is confirmed for North Africa. Details about the distribution and habitats of the 11 species are provided, and comments on their status and taxonomy are included.