Search results for "CERAMICS"
showing 10 items of 1599 documents
Formation of layered titania and zirconia catalysed by surface-bound silicatein
2005
Silicatein immobilised on self-assembled polymer layers using a histidine-tag chelating anchor group retains its hydrolytical activity for the formation of biosilica, and catalyses the formation of layered arrangements of biotitania and biozirconia.
Highly enantioselective aza-Henry reaction with isatin N-Boc ketimines.
2014
A highly enantioselective aza-Henry reaction with isatin N-Boc ketimines using a Cu(II)–BOX complex as a catalyst is described. The reaction, which does not require protection of the N1 atom, provides the corresponding nitroamines bearing a quaternary stereocentre with high yields and enantiomeric excesses (up to 99.9%).
A catalytic highly enantioselective direct synthesis of 2-bromo-2-nitroalkan-1-ols through a Henry reaction.
2008
Highly enantiomerically enriched 2-bromo-2-nitroalkan-1-ols are prepared by direct condensation of aliphatic and aromatic aldehydes with bromonitromethane in the presence of a catalytic amount of copper(II) acetate and a C1-symmetric camphorderived amino pyridine ligand. Blay Llinares, Gonzalo, Gonzalo.Blay@uv.es ; Hernandez Olmos, Victor, Victor.Hernandez@uv.es ; Pedro Llinares, Jose Ramon, Jose.R.Pedro@uv.es
Indentation of rigidly supported sandwich beams with foam cores exhibiting non-linear compressive behaviour.
2011
A generalized analytical approach to investigate the indentation of sandwich beams under concentrated loads is presented, based on the Winkler foundation theory. A segment-wise model is implemented to the case of fully backed sandwich beams with polymeric foam cores exhibiting generic non-linear compressive behaviours. Closed-form analytical solutions of the indentation curve are obtained for simplified foam compression behaviours: elastic-perfectly-plastic, bilinear and bilinear-perfectly-plastic. Analytical predictions are compared with experimental data from sandwiches employing foam cores with peculiar non-linear behaviours. The proposed models are found to give a better match of the e…
Time-resolved luminescence of YAG:Ce and YAGG:Ce ceramics prepared by electron beam assisted synthesis
2020
Abstract The luminescence characteristics of YAG:Ce and YAGG:Ce ceramic phosphors produced by electron beam assisted synthesis have been investigated. The obtained emission and decay kinetics characteristics have been compared with those for commercial phosphors synthesized by conventional methods and showed good qualitative and quantitative correspondence. In our opinion, the used electron-beam-assisted synthesis method could be considered as a perspective production method of high refractory multicomponent oxide ceramics.
Cathodoluminescence and IR absorption of oxygen deficient silica – influence of hydrogen treatment
1999
Abstract The cathodoluminescence (CL) and IR absorption of silica samples with normal stoichiometry as well as with an extremely high level of oxygen deficit were studied. Additionally, some samples have been treated in hydrogen at 800°C. Crystalline quartz was used for reference measurements and the CL data have been compared with those of X-ray excited luminescence (XL). The luminescence spectra of silica have a band at 1.85 eV due to non-bridging oxygens and the two bands at 2.7 and 4.4 eV due to twofold-coordinated silicons. The energetic yield for CL is about 0.1%, for XL it approaches 0.15%. Cathodoluminescence of quartz at temperatures >130 K exhibits the self-trapped exciton lumines…
Nucleation kinetics in deionized charged colloidal suspension
2011
A systematic experimental study on the nucleation, crystallization and crystal-growth of one-componentcharged colloidal particles (122 nm diluted in pure water with densities between 0.5 μm−3bnpb5 ...
The structural properties of soda–silicate sols and of the lime–soda–silicate gel formation
1999
Abstract Alkaline silicate solutions were prepared with varying SiO 2 –Na 2 O ratios, Rm=[SiO 2 ]/[Na 2 O]=2 or 3, with a constant silica concentration equal to 1.5 M. The structure and the number fraction of different silicate molecular species present in the solutions were classically determined for molar ratio Rm=2 using 29 Si nuclear magnetic resonance ( 29 Si NMR). In the case of the sample with Rm=3, for which no NMR data was available, we used small-angle X-ray scattering (SAXS) experiments to get this information. The SAXS model was previously tested with Rm=2 silicate solution. When Ca ++ is added to alkaline silicate solutions, a gel is obtained under well-defined conditions. The …
Phénomène, culture et tradition : statuts et r̂oles du Campaniforme au IIIe millénaire dans le Sud-Est de la France
1998
Abstract The "Bell Beaker " complex should not be globally perceived, because it seems to include several different entities, as shown by its variations in space and time. A regional approach, in south-eastern France, outlines the existence of a first " Bell Beaker Phenomenon " and its spread in Late Neolithic societies. This relatively marginal phenomenon quickly becomes an actual independent "Bell Beaker Culture ", with different geographical fades. These may have been in contact with surviving local cultures. In the Early Bronze Age, a "Bell Beaker Tradition " integrates some new elements brought in from outside, and seems to extend the Bell Beaker culture. The role of this " Bell Beaker…
Les Campaniformes dans le sud-est de la France
2004
The term "Bell Beaker", in the strict sense, designates a ceramic beaker form with an S-shaped profile that gives it the shape of an inverted bell. This type of drinking-vessel is characterized by both its very particular pattern of decoration and by the generally skilled execution of that decoration. By extension, the decoration characteristic of these beakers bas allowed the expansion of the category "Bell-Beaker" to include other pottery forms and even other types of decoration showing the same tradition, vvhich probably represent an evolution or reproduction of the original Bell Beaker pattern, The recognition of these objects and their definition as a class date to the nineteenth centu…