Search results for "CERAMICS"
showing 10 items of 1599 documents
Isoelectronic series of twofold coordinated Si, Ge, and Sn atoms in glassy SiO2: a luminescence study
1992
Abstract Luminescence centers causing optical absorption bands in the 5 eV region in oxygen-deficient pure (‘Si-doped’), as well as in Ge- and Sn-doped glassy SiO2 were studied. The spectral and particularly kinetic data show that in all cases luminescence centers with closely similar properties exist which constitute an isoelectronic series. They are attributed to defects, formed by electrically neutral twofold coordinated Si, Ge, and Sn atoms (T20 centers) in glassy SiO2. Twofold coordinated Si causes the characteristic ‘B2’ optical absorption band at 5.03 eV. Upon reaction with atomic hydrogen, T20 centers convert to the well known ‘H(I)’, ‘H(II)’ and ‘H(III)’ ESR-active defects. The alt…
Influence of the Substituent on Selective Photocatalytic Oxidation of Aromatic Compounds in Aqueous TiO2 Suspensions.
2006
Experimental results are reported showing that the photocatalytic oxidation of aromatic compounds containing an electron-donor group (EDG) gives rise mainly to ortho- and para-monohydroxy derivatives while in the presence of an electron-withdrawing group (EWG) all the monohydroxy derivatives are obtained.
Analysys and optimization of an end double-lap bonded joint for GFRP composite sandwich panels
2022
Although the best configuration of the joints used to connect a common GFRP sandwich panel with the main structures is the adhesively bonded one, that permit high static and fatigue performances as well as to avoid stress concentrations, mechanical or hybrid joints are still widely used in the industrial field. After a preliminary theoretical design, the optimal configuration of an end adhesively bonded double-lap joint constituted by a simple insert as internal adherent and the same face sheets as external adherent, has been researched. In detail, several experimental tests and successive numerical simulations under tensile and bending loading, performed by varying the main influence para…
Wet electrospinning-aided self-assembly of multifunctional GO-CNT@PCL core-shell nanocomposites with spider leg bioinspired hierarchical architectures
2022
We report a fast route enabling the multiscale design of nanohybrid structures comprising a 3D fibrous network of polycaprolactone (PCL) wrapped by graphene oxide (GO) sheets onto which carbon nanotube (CNT) brushes are anchored. The method relies on electrospinning PCL solutions onto a suspension of GO and CNTs in ethanol. Self-assembly is due to electrostatic wrapping of GO sheets around PCL fibers and 7C-7C stacking between GO and CNTs. Hierarchical architecture and nanopatterned surface allow gathering the starting properties of PCL, GO and CNTs into lightweight (99% porosity) yet robust (1575% stiffness improvement), amphiphilic monoliths that can remove methylene blue and/or methyl or…
An innovative route to prepare in situ graded crosslinked PVA graphene electrospun mats for drug release
2022
We present a fast, one step method to obtain PVA/graphene/chlorhexidine nanofibrous membranes, with a crosslinking gradient along their cross-section. Briefly, polymeric solutions were electrospun onto a heated plate, enabling the in situ crosslinking of PVA macromolecules. Of course, the crosslinking degree of such structures was found to decrease upon the distance from the plate during deposition. The outcomes reveal the crucial role of graphene, capable of promoting heat transfer throughout the entire structure, thus leading to 70-80% crosslinking degrees and preventing delamination issues. Such membranes were compared to untreated and oven thermally treated ones, and a robust relationsh…
Opuntia Ficus Indica based green composites for NPK fertilizer controlled release produced by compression molding and fused deposition modeling
2022
Excessive fertilization causes ecological problems due to leaching issues. To solve this problem and promote agriculture sustainability an innovative green composite for controlled release fertilizers was produced by adding NPK fertilizer flour to a biodegradable polymer with or without Opuntia Ficus Indica (OFI) particles. Six for- mulations were produced and employed for the fabrication of devices both for compression molding and fused deposition modeling (FDM). Both fillers displayed a good dispersion in the composites, excellent adhesion with the polymeric matrix and effectively acted as reinforcement. The decrease of NPK release rate (up to 30 days) was achieved using whole composites …
Assessment of performance degradation of hybrid flax-glass fiber reinforced epoxy composites during a salt spray fog/dry aging cycle
2022
The main goal of this paper is the evaluation of the performances reversibility of hybrid composites when they are dried after being aged in salt-fog environment. To this aim, epoxy composites reinforced with flax and glass fabrics respectively in the internal and external laminae were at first exposed to salt-fog (i.e., identified as wet phase) and then stored in controlled conditions (i.e., identified as dry phase). The flexural properties evolution of these composites as well as their water uptake and contact angle were monitored at varying time of both phases. The flexural strength and modulus of hybrid composites is 23.4% (17.9%) and 15.5% (12.9%) lower than unaged ones after 30 (15) d…
Modelling the structure-property relationships of high performance PBAT-based biocomposites with natural fibers obtained from Chamaerops humilis dwar…
2022
Two fibrous fillers were achieved from stalks and leaves of Chamaerops humilis dwarf palm and tested as reinforcing agents for poly(butylene adipate co-terephthalate) (PBAT)-based composites. The influence of filler type and content on the morphomechanical properties of the green composites was assessed. The outcomes of tensile tests pointed out that both fillers are strong candidates to overcome the two main limiting aspects of PBAT, that is, the lack of both stiffness and cost-effectiveness, while preserving its stretchability and environmental sustainability. The remarkable stiffness increments (up to 300%), combined with fair retention of stretchability (33%) and doubled resistance, led…
Advances in selective conversions by heterogeneous photocatalysis
2010
Selective photocatalytic conversions are offering an alternative green route for replacing environmentally hazardous processes with safe and energy efficient routes. This paper reports the most recent advances in the application of heterogeneous photocatalysis to synthesize valuable compounds by selective oxidation and reduction.
Vibration-based identification of mechanical properties of orthotropic arbitrarily shaped plates: Numerical and experimental assessment
2018
Abstract An innovative procedure is introduced for the identification of the mechanical parameters of orthotropic plates of arbitrary shape, under various boundary conditions, based on vibration data. The method employs a combination of a convenient Rayleigh-Ritz approach and Particle-Swarm Optimization to estimate elastic constants of the orthotropic material in a straightforward manner, without requiring computationally demanding iterative Finite Element analyses. Specifically, the pb-2 Rayleigh-Ritz procedure is extended and applied to deal with orthotropic plates, simplifying the approach to more easily treat generic plate shapes, taking advantage of the Green's theorem. The method is t…