Search results for "CLU"
showing 10 items of 14395 documents
La Self-Efficacy degli insegnanti di sostegno in formazione iniziale
2021
Nell’ultimo ventennio gli studi sulla Self-Efficacy hanno sempre più indagato le percezioni degli insegnanti e come queste influenzano, non solo il loro modo di lavorare, ma soprattutto gli esiti di apprendimento e il senso di autoefficacia degli allievi. La percezione di autoefficacia degli insegnanti nel costruire ambienti di apprendimento inclusivi assume un ruolo ancora più importante. Il presente contributo indaga tale costrutto in un campione di 1591 studenti iscritti al V ciclo del corso per il conseguimento della specializzazione per le attività di sostegno didattico per gli alunni con disabilità dell’Università degli Studi di Palermo. In the last twenty years, studies on Self-Effic…
Individual Approach to Studies during Covid-19 Quarantine
2021
Anitas Vaivodes diplomdarbs “Individuāla pieeja mācībām Covid-19 karantīnas laikā” izstrādāts Latvijas Universitātes Pedagoģijas, psiholoģijas un mākslas fakultātes Skolotāju izglītības nodaļā. Diplomdarba mērķis ir raksturot sociālā pedagoga mācību atbalsta darbu skolēniem, lai izstrādātu sociālpedagoģiskās darbības programmu nesekmīgo skolēnu atbalstam attālinātā mācību procesa laikā vispārizglītojošajā skolā. Teorētiskajā daļā tiek raksturoti iekļaujošās izglītības un atbalsta sistēmas jēdzieni, kā arī aprakstīta Latvijas izglītības sistēmas pāreja uz karantīnas periodu 2019./2020. m.g. otrajā pusgadā. Praktiskā daļa ietver aptauju par pētījumu par atbalsta sistēmas procesu Rīgas sociālā…
[Ag67(SPhMe2)32(PPh3)8]3+: Synthesis, Total Structure, and Optical Properties of a Large Box-Shaped Silver Nanocluster
2016
Engineering the surface ligands of metal nanoparticles is critical in designing unique arrangements of metal atoms. Here, we report the synthesis and total structure determination of a large box-shaped Ag67 nanocluster (NC) protected by a mixed shell of thiolate (2,4-dimethylbenzenethiolate, SPhMe2) and phosphine (triphenylphosphine, PPh3) ligands. Single crystal X-ray diffraction (SCXRD) and electrospray ionization mass spectrometry (ESI-MS) revealed the cluster formula to be [Ag67(SPhMe2)32(PPh3)8]3+. The crystal structure shows an Ag23 metal core covered by a layer of Ag44S32P8 arranged in the shape of a box. The Ag23 core was formed through an unprecedented centered cuboctahedron, i.e.,…
Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)40]3+ (X=Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles
2017
Surface ligands play important roles in controlling the size and shape of metal nanoparticles and their surface properties. In this work, we demonstrate that the use of bulky thiolate ligands, along with halides, as the surface capping agent promotes the formation of plasmonic multiple-twinned Ag nanoparticles with high surface reactivities. The title nanocluster [Ag141X12(S-Adm)40]3+ (where X = Cl, Br, I; S-Adm = 1-adamantanethiolate) has a multiple-shell structure with an Ag71 core protected by a shell of Ag70X12(S-Adm)40. The Ag71 core can be considered as 20 frequency-two Ag10 tetrahedra fused together with a dislocation that resembles multiple-twinning in nanoparticles. The nanocluster…
Анализ проблем развития лесопромышленного комплекса при формировании модели экономики замкнутого цикла на примере Томской области
2019
The main objective of the paper is the conduction of the timber industry complex problems analysis from the circular economy and sustainable development point of view. The problem of waste is considered in conjunction with other environmental, economic and social problems. A modeling of the value chain process and the formation of threats along the whole chain «nature (forest) – economy – society (consumer)» is being conducted. A classification of the development problems in the timber industry complex on the basis of «created values» and «production factors» has been developed. Planned growth in logging volume and wood processing, expansion of unused waste require the development of a spec…
Theoretical investigation of the electronic structure of fullerenes
1994
Summary form only given. Research in the growing family of fullerene compounds are in continuous expansion. Much theoretical and experimental effort has been devoted to the study of the electronic properties these carbon cages present. However, although significant work has been done, the purpose of this paper is to provide a detailed theoretical analysis of the electronic properties of several fullerenes. We have calculated the electronic structure of these carbon cages within the valence effective Hamiltonian (VEH) approach. The calculated one-electron energy levels are correlated with experimental UPS spectra. The good correlation between calculated and experimental values shows VEH appr…
Modelling Systemic Cojumps with Hawkes Factor Models
2013
Instabilities in the price dynamics of a large number of financial assets are a clear sign of systemic events. By investigating a set of 20 high cap stocks traded at the Italian Stock Exchange, we find that there is a large number of high frequency cojumps. We show that the dynamics of these jumps is described neither by a multivariate Poisson nor by a multivariate Hawkes model. We introduce a Hawkes one factor model which is able to capture simultaneously the time clustering of jumps and the high synchronization of jumps across assets.
Spin-lattice relaxation of deuterated methyl groups: Implications of the pauli principle
1999
The high-field spin-lattice relaxation of deuterated methyl groups undergoing rotational tunneling is investigated theoretically. It is found that for systems showing a tunneling frequency comparable to accessible Larmor frequencies the relaxation to equilibrium of the Zeeman energy does not follow a simple exponential time dependence even in powdered samples due to a finite coupling to the relaxation of the tunneling system. This finding contrasts to the high-temperature behavior of reorienting methyl groups which undergo simple exponential relaxation. The nonexponentiality has its origin in the statistical coupling of the three deuteron spins due to the Pauli principle.
Towards Controlled Synthesis of Water-Soluble Gold Nanoclusters : Synthesis and Analysis
2019
Water-soluble gold nanoclusters with well-defined molecular structures and stability possess particular biophysical properties making them excellent candidates for biological applications as well as for fundamental spectroscopic studies. The currently existing synthetic protocols for atomically monodisperse thiolate-protected gold nanoclusters (AuMPCs) have been widely expanded with organothiolates, yet the direct synthesis reports for water-soluble AuMPCs are still deficient. Here, we demonstrate a wet-chemistry pH-controlled synthesis of two large water-soluble nanoclusters utilizing p-mercaptobenzoic acid (pMBA), affording different sizes of plasmonic AuMPCs on the preparative scale (∼7 …