Search results for "CNT"

Chemical modification of carbon nanomaterials (SWCNTs, DWCNTs, MWCNTs and SWCNHs) with diphenyl dichalcogenides

2015

Control over chemical functionalization is a crucial point in the field of nanotechnology. Herein, we present the covalent functionalization of several carbon nanoforms (single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes and carbon nanohorns) by means of diphenyl dichalcogenides. These ones show different reactivity to the nanomaterials and are able to modify their electronic properties depending on the electronegativity of the functionalizing heteroatom. Theoretical calculations were also performed to support the experimental results. All the modified structured nanocarbons were thoroughly characterized by TGA Raman, XPS, UV/Vis/nIR, IR and TEM te…

M13_Microfluidics_for_CNT

2018

Compared to pure water, the CNT dispersion has much lower interfacial tension at the dispersion – glass interface due to the presence of SDBS surfactant. Since the behavior of microfluidic system in the confined regime is driven by liquid – solid interfacial tension, the droplet formation and droplet propagation are unstable and unpredictable.

Reactive melt blending of functionalized-MW/CNTs with polyolefin

2012

Adding nanotube adding into a polymeric matrix leads to the formulation of nanocomposites with enhanced macroscopical performances, and, moreover, the use of functionalized MW-CNTs leads to the nanocomposite formulation with even better properties. Furthermore, the reactive melt blending can be considered as a powerful processing method, i.e. reasonably simple and ecologically friendly, in order to formulate polymer based nanocomposite with good performance. In this work, the reactive melt blending between an ethylene-acrylic acid co-polymer, bis-oxazoline and functionalized MW-CNTs was performed and the rheological properties of the formulated systems were investigated.

Preparation of functionalized-MW-CNTs/Polyolefin nanocomposites and analysis of their physical properties

2010

Centrality and rapidity dependence of inclusive pion and prompt photon production in p+Pb collisions at the LHC with EPS09s nPDFs

2014

The centrality dependencies of the inclusive neutral pion and prompt photon nuclear modification factors for p+Pb collisions at the LHC are studied using a spatially dependent set of nuclear PDFs, EPS09s. The calculations are performed at mid- and forward rapidities searching for an observable which would optimally probe the spatial dependence of the nuclear PDFs. In addition, we discuss to which $x$ values of the nucleus the different observables are sensitive.

Resistance simulations for junctions of SW and MW carbon nanotubes with various metal substrates

2011

Abstract This theoretical study focuses on junctions between the carbon nanotubes (CNTs) and contacting metallic elements of a nanocircuit. Numerical simulations on the conductance and resistance of these contacts have been performed using the multiple scattering theory and the effective media cluster approach. Two models for CNT-metal contacts have been considered in this paper: a) first principles “liquid metal” model and b) semi-empirical model of “effective bonds” based on Landauer notions on ballistic conductivity. Within the latter, which is a more adequate description of chirality effects, we have simulated both single-wall (SW) and multi-wall (MW) CNTs with different morphology. Res…

Using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry for the characterization of functionalized carbon nanotubes

2013

RATIONALE: Functionalization of carbon nanotubes (CNTs) generates complex systems that require the development of suitable characterization protocols. New techniques have been explored, and existing analytical and spectroscopic methods to characterize functionalized CNTs have been adapted. Presently, chemical characterization of functionalized CNTs (f-CNTs) remains a difficult task. METHODS: Matrix-assisted laser desorption/ionization (MALDI) analysis is performed on f-MWCNT samples prepared via grafting or absorption of anti-oxidant (AO) molecules on both MWCNT-COOH and MWCNT-OH. Covalently functionalized MWCNTs were subjected to thermal degradation and/or hydrolysis reaction before analys…

Kondensaation vaikutus hiilinanoputkidepositioon hydrofiilisellä piioksidipinnalla

2017

Tutkielmassa käsittelen kondensaatiota ja sen muodostumista hydrofiilisellä piioksidipinnalla olevaan moniseinäisten nanoputkien depositioon. Kondensaation depositioon muodostamia aukkoja analysoimalla pyritään saamaan kuva siitä miten kondensaatio vaikuttaa depositioon ja miten nanoputket vaikuttavat kondensaatioon. Näytteinä käytettiin happiplasmalla hydrofiiliseksi käsiteltyä piioksidisirua, johon tehtiin nanoputkidepositio pudottamalla nanoputkia sisältävää liuosta suurella nopeudella pyörivälle näytteelle. Näytteillä tehtiin kolmea erilaista koetta. Kontaktikokeissa pisara tuotiin kontaktiin näytteen kanssa, kondensaatiokokeissa pisara pidettiin näytepinnan läheisyydessä ja jäähdytysko…

The STAT3 Inhibitor Galiellalactone Reduces IL6-Mediated AR Activity in Benign and Malignant Prostate Models

2018

IL6/STAT3 signaling is associated with endocrine therapy resistance in prostate cancer, but therapies targeting this pathway in prostate cancer were unsuccessful in clinical trials so far. The mechanistic explanation for this phenomenon is currently unclear; however, IL6 has pleiotropic effects on a number of signaling pathways, including the androgen receptor (AR). Therefore, we investigated IL6-mediated AR activation in prostate cancer cell lines and ex vivo primary prostate tissue cultures in order to gain a better understanding on how to inhibit this process for future clinical trials. IL6 significantly increased androgen-dependent AR activity in LNCaP cells but importantly did not infl…

Interleukin-10 and interleukin-18 promoter polymorphisms in an Italian cohort of patients with undifferentiated carcinoma of nasopharyngeal type.

2004

Purpose: Cytokines such as IL-10 and IL-18 seem to be involved in the inflammatory response of undifferentiated carcinoma of nasopharyngeal type (UCNT). The aim of this study was to evaluate the correlation between functional single nucleotide polymorphisms (SNPs) in the promoter region of IL-10 and IL-18 genes and the virological and clinical characteristics in a large case series of Caucasian patients suffering from UCNT, a tumor regularly associated with the Epstein Barr Virus (EBV). Methods: Eighty-nine patients with histologically confirmed UCNT and 130 healthy donors were included in our study. DNA was examined for the polymorphisms of IL-10 gene at positions –1082, −819, −592 by dire…